Binder composition comprising poly(amino acid)s for fiber composite articles

Patent metadata

Field	Value
Publication number	US-11976168-B2
Application number	US-202118269028-A
Country	US
Kind code	B2
Filing date	Dec 22, 2021
Priority date	Dec 23, 2020
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

The present invention relates to a binder composition comprising component A comprising polymer(s) A1 and optionally component B comprising component B1 which is selected from the group consisting of a mono-saccharide s, disaccharides, hydroxyacetone, glycolaldehyde and mixtures thereof, wherein polymer(s) A1 comprises at least 70 wt.-% poly(amino acid)s based on the total weight of the polymers) A1 and has (have) a total weight average molecular weight M w,total of 800 g/mol to 10.000 g/mol, wherein the binder composition comprises 60 to 100 wt.-% polymer(s) A1, and 0 to 40 wt.-% component B1, based on the total weight of the sum of polymer(s) A1 and component B1, wherein the weight amounts of the polymer(s) A1 and component B1 are selected such that the total weight of the sum of polymer(s) A1 and component B1 is 100 wt.-%.

First claim

The invention claimed is:

1. Use of a binder composition comprising
component A comprising polymer(s) A1 and
optionally component B comprising component B1 which is selected from the group consisting of monosaccharides, 5 disaccharides, hydroxyacetone, glycolaldehyde and mixtures thereof,
wherein polymer(s) A1 consist(s) of polylysine(s) and has(have) a total weight average molecular weight M w, total of 800 g/mol to 10,000 g/mol,
wherein the binder composition comprises 80 to 100 wt.-% polymer(s) A1, and 0 to 20 wt.-% component B1, based on the total weight of the sum of polymer(s) A1 and component B1, wherein the weight amounts of the polymer(s) A1 and component B1 are selected such that the total weight of the sum of polymer(s) A1 and component B1 is 100 wt.-%,
for the preparation of a lignocellulosic fiber board, wherein 3 to 15 wt-% polymer(s) A1 and component B1 in total based on the total oven-dry weight of the lignocellulosic fibers are used for the preparation of the lignocellulosic composite article.

2. Use according to claim 1 , wherein component B1 is selected from the group consisting
of hydroxyacetone, 1,3-dihydroxyacetone, xylose, fructose, glucose, mannose, saccharose and mixtures thereof.

3. Use according to claim 1 , wherein no compound B is included.

4. Use of a reacted Binder composition obtainable or obtained by reacting the binder components A and B and lignocellulosic fibers or reacting component A and lignocellulosic fibers as defined in claim 1 , for the preparation of a lignocellulosic fiber board.

5. Use of a composition kit comprising the binder composition as defined in claim 1 , wherein component A and component B are stored separately, for the preparation of a lignocellulosic fiber board.

6. A lignocellulosic fiber board comprising a plurality of lignocellulosic fibers, and a binder composition as defined claim 1 , wherein 3 to 15 wt-% polymer(s) A1 and component B1 in total based on the total oven-dry weight of the lignocellulosic fibers are used for the preparation of the lignocellulosic composite article.

7. The lignocellulosic fiber board according to claim 6 , having a thickness of 1.5 to 5 mm.

8. The lignocellulosic fiber board according to claim 6 , having an internal bond strength of more than 0.8 N/mm 2 .

9. A process for the batchwise or continuous production of lignocellulosic fiber boards
which are multi-layered lignocellulose-based fiber boards with a core and with at least one upper and one lower surface layer, comprising the following steps:
a) mixing of the lignocellulosic fibers with a binder composition for each layer, wherein the mixture for at least one layer comprises the binder composition as defined in claim 1 ,
b) layer-by-layer scattering of the mixtures of the individual layers to form a mat,
c) pressing the mat to a board at a temperature of 80 to 300° C. and at a pressure of 1 to 100 bar
wherein 3 to 15 wt.-% polymer(s) A1 and component B1 in total based on the total 20 oven-dry weight of the lignocellulosic fibers, are used for the preparation of the lignocellulose-based fiber boards.

10. A process for the batchwise or continuous production of single layered lignocellulosic fiber boards comprising the following steps:
a) mixing of the lignocellulosic fibers with a binder composition, wherein the mixture comprises the binder composition as defined in claim 1 ,
b) scattering of the mixtures to form a mat,
c) pressing the mat to a board at a temperature of 80 to 300° C. and at a pressure of 1 to 100 bar or
c′) pressing the mat to a board at a temperature of 80 to 200° C. and at a pressure of 0.1 to 100 bar, wherein a high-frequency electrical field is applied during pressing until 80 to 200° C. is reached in the center of the mat
wherein 3 to 15 wt.-% polymer(s) A1 and component B1 in total based on the total oven-dry weight of the lignocellulosic fibers, are 5 used for the preparation of the lignocellulose-based fiber boards.

11. A process for the batchwise or continuous production of lignocellulosic fiber boards
which are multi-layered lignocellulose-based fiber boards with a core and with at least one upper and one lower surface layer, comprising the following steps:
a) mixing of the lignocellulosic fibers with a binder composition for each layer, wherein the mixture for at least one layer comprises the binder composition as defined in claim 1 ,
b) layer-by-layer scattering of the mixtures of the individual layers to form a mat,
c) pressing the mat to a board at a temperature of 80 to 300° C. and at a pressure of 1 to 100 bar
wherein 3 to 15 wt.-% polymer(s) A1 and component B1 in total based on the total 20 oven-dry weight of the lignocellulosic fibers, are used for the preparation of the lignocellulose-based fiber boards,
wherein both components A and B of the binder composition as defined in claim 1 are added to the lignocellulosic pieces in step a) either
a1) separately from one another or
a2) as a mixture.

12. The process according to claim 9 , wherein the lignocellulosic fibers are prepared from wood.

13. The process according to claim 10 , wherein the boards obtained in step c) or step c′) have an internal bond strength of more than 0.8 N/mm 2 .

Assignees

• Basf Se

Inventors

• Sommer Gereon Antonius
• Weinkoetz Stephan
• Tuerp David
• Scherr Guenter
• Hamann Jessica Nadine
• Teles Joaquim Henrique
• Lunkwitz Ralph
• Servay Thomas
• Lindner Jean-Pierre Berkan
• Kunsmann-Keitel Dagmar Pascale

Classifications

• C08G69/10 Primary

  Alpha-amino-carboxylic acids {(polysuccinimides C08G73/1092)} · CPC title

• B27N3/002

  characterised by the type of binder (compositions of macromolecular compounds C08L) · CPC title

• B27N3/04

  from fibres · CPC title

• C08K5/07

  Aldehydes; Ketones · CPC title

• C08K5/1545 Primary

  Six-membered rings · CPC title