Light-stimuli responsive coordination polymer, and preparation and use thereof

Patent metadata

Field	Value
Publication number	US-11976087-B2
Application number	US-202218026820-A
Country	US
Kind code	B2
Filing date	Feb 15, 2022
Priority date	Dec 30, 2021
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

The invention provides a light-stimuli responsive coordination polymer, and preparation method and use thereof. The coordination polymer has a chemical formula of [Zn(tkpvb) (Fb)2]n1, wherein Fb represents p-fluorobenzoate, tkpvb represents 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene, and n=3000-60000; and crystallographic parameters of: (1) crystal system: monoclinic system; (2) space group: C2/c; (3) a=28.577(3)Å, b=7.4084(6) Å, c=22.612(3) Å, β=126.771(2)°, and V=3834.8(7) Å3; (4) Z=4; and (5) F(000)=1720, R1=0.0440, wR2=0.1042, and GOF=1.047. The method is simple, and has mild reaction conditions, and fast light conversion rate. The means of light-stimuli responsiveness are non-contact and non-damage type, the volume adjustment is highly accurate, and the whole adjustment process does not require any chemical reagents, and is safe and reliable. Photoactuators can complete a variety of behaviors under the irradiation of ultraviolet light having a wavelength of 365 nm.

First claim

What is claimed is:

1. A light-stimuli responsive coordination polymer, wherein the coordination polymer is a bright yellow bulk crystal and has a chemical formula of [Zn(tkpvb)(Fb) 2 ] n1 , crystallographic parameters of:
(1) crystal system: monoclinic system;
(2) space group: C2/c;
(3) a=28.577(3) Å, b=7.4084(6) Å, c=22.612(3) Å, β=126.771(2)°, and V=3834.8(7) Å 3 ;
(4) Z=4; and
(5) F(000)=1720, R 1 =0.0440, wR 2 =0.1042, and GOF=1.047,
wherein Fb represents p-fluorobenzoate, tkpvb represents 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene, and n1=3000-60000.

2. A method for preparing a light-stimuli responsive coordination polymer according to claim 1 , comprising steps of:
dissolving zinc nitrate hexahydrate, p-fluorobenzoic acid or a water-soluble salt thereof, and 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene in a mixed solvent of N,N-dimethylformamide and water, adjusting the pH to 5-6, and reacting to obtain the light-stimuli responsive coordination polymer.

3. The preparation method according to claim 2 , wherein the molar ratio of zinc nitrate hexahydrate, p-fluorobenzoic acid or a water-soluble salt thereof and 1,2,4,5-tetrakis((E)-2-(4-pyridyl)vinyl)benzene is 1-2.5:1-2.5:1-2.5.

4. The preparation method according to claim 2 , wherein the reaction temperature is 120 to 125° C., and the time is 5-12 h.

5. A composite film, comprising a light-stimuli responsive coordination polymer according to claim 1 .

6. A method for preparing a composite film according to claim 5 , comprising steps of:
S 1 : grinding the light-stimuli responsive coordination polymer, dispersing in a solvent, and drying;
S 2 : adding a substrate, and stirring to obtain a uniform viscous liquid;
S 3 : adding the uniform viscous liquid into a mold, drying, and peeling to obtain the composite film.

7. The method for preparing a composite film according to claim 6 , wherein the substrate is selected from the group consisting of PVA, chitosan, polyvinylidene difluoride, polypropylene and any combination thereof.

8. A photoactuator, prepared with a composite film according to claim 5 .

Assignees

• Univ Soochow

Inventors

• Lang Jianping
• Yang Zhanyong
• Ni Chunyan

Classifications

• C07F3/06 Primary

  Zinc compounds · CPC title

• C08J5/18

  Manufacture of films or sheets · CPC title

• C08K5/0091

  Complexes with metal-heteroatom-bonds · CPC title

• F03G7/016

  Photosensitive actuators, e.g. using the principle of Crookes radiometer · CPC title

• F03G7/029 Primary

  characterised by the material or the manufacturing process, e.g. the assembly · CPC title