High pressure strippers for use in urea plants

Patent metadata

Field	Value
Publication number	US-11976027-B2
Application number	US-202017418512-A
Country	US
Kind code	B2
Filing date	Apr 30, 2020
Priority date	May 3, 2019
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

Shell-and-tube strippers for stripping a urea/carbamate mixture, related systems, methods, and uses. The stripper includes a shell, a plurality of tubes disposed within the shell, and a heating fluid distributor for homogenizing the flow of a heating fluid near a heating fluid inlet. The heating fluid distributor includes an edge wall and a laterally disposed heating fluid distribution plate. Related systems, methods, and uses are also provided.

First claim

The invention claimed is:

1. A shell-and-tube stripper for stripping a urea/carbamate mixture,
the stripper comprising a top end in fluid connection with a bottom end through a plurality of tubes disposed within a shell;
the top end comprising an inlet for a urea/carbamate mixture and an outlet for a gas mixture comprising a stripping gas and one or more stripped compounds;
the bottom end comprising an outlet for a urea/carbamate stream concentrated in urea;
the shell-and-tube stripper further comprising a heating fluid inlet and a heating fluid outlet in fluid connection with a shell-side space disposed between the plurality of tubes and the shell;
the shell-and-tube stripper having a longitudinal direction and lateral cross sections, the longitudinal direction being parallel to the tubes and the lateral cross sections being perpendicular to the longitudinal direction;
wherein the shell-and-tube stripper comprises a heating fluid distributor adjacent to the heating fluid inlet for homogenizing a flow of heating fluid in the stripper, the heating fluid distributor comprising an edge wall and a heating fluid distribution plate which is disposed parallel to the lateral cross sections;
the edge wall comprising two or more openings and/or a plurality of perforations, and the edge wall defining a belt-shaped space between the shell and the edge wall;
the heating fluid inlet being arranged for providing heating fluid to the belt-shaped space;
the belt-shaped space being arranged for providing heating fluid to an inner heating fluid distribution space;
the heating fluid distribution plate being arranged for providing heating fluid from the inner heating fluid distribution space to the shell-side space between the heating fluid distributor and the bottom end;
the heating fluid distribution plate comprising a plurality of perforations, the plurality of perforations comprising a plurality of tube holes and a plurality of heating fluid holes, wherein a size and/or a density of the heating fluid holes changes in a radial direction of the heating fluid distribution plate.

2. The shell-and-tube stripper according to claim 1 wherein the size of the heating fluid holes changes from a center of the heating fluid distribution plate towards an outer rim of the heating fluid distribution plate.

3. The shell-and-tube stripper according to claim 2 wherein the size of the heating fluid holes increases from the outer rim to the center of the heating fluid distribution plate; or
wherein the size of the heating fluid holes decreases from the outer rim to the center of the heating fluid distribution plate.

4. The shell-and-tube stripper according to claim 2 wherein the heating fluid distribution plate comprises one or more areas in which the size of the heating fluid holes strictly decreases from the outer rim to the center of the heating fluid distribution plate, and wherein the heating fluid distribution plate comprises one or more areas in which the size of the heating fluid holes strictly increases from the outer rim to the center of the heating fluid distribution plate.

5. The shell-and-tube stripper according to claim 1 wherein means for limiting vibrations of the tubes are provided between the heating fluid distribution plate and the bottom end.

6. The shell-and-tube stripper according to claim 5 , wherein the means for limiting vibrations of the tubes comprise a plurality of rod baffles.

7. The shell-and-tube stripper according to claim 1 wherein an angle between the longitudinal direction and the heating fluid distribution plate is from 85.0° to 90.0°; and/or
wherein an angle between the longitudinal direction and the edge wall is from 0.0° to 5.0°.

8. The shell-and-tube stripper according to claim 7 wherein the angle between the longitudinal direction and the heating fluid distribution plate is 90.0°; and/or
wherein the angle between the longitudinal direction and the edge wall is 0.0°.

9. The shell-and-tube stripper according to claim 1 wherein a diameter of each of the heating fluid holes is from at least 1 mm to at most 16 mm; and/or wherein a ratio of the diameter of a largest of the heating fluid holes to the diameter of a smallest of the heating fluid holes is from at least 1.1 to at most 16.

10. The shell-and-tube stripper according to claim 9 wherein the diameter of each of the heating fluid holes is from at least 5 mm to at most 7 mm.

11. The shell-and-tube stripper according to claim 1 wherein the heating fluid holes in the heating fluid distribution plate are evenly spaced at concentric circles around a center of the heating fluid distribution plate.

12. The shell-and-tube stripper according to claim 1 wherein the density of heating fluid holes is constant in the heating fluid distribution plate, wherein the size of the heating fluid holes changes from a center of the heating fluid distribution plate towards an outer rim of the heating fluid distribution plate, wherein the tube holes are arranged in a triangular geometry, and wherein each heating fluid hole is centrally disposed between three adjacent tube holes.

13. The shell-and-tube stripper according to claim 1 wherein the density of heating fluid holes is constant in the heating fluid distribution plate, wherein the size of the heating fluid holes changes from a center of the heating fluid distribution plate towards an outer rim of the heating fluid distribution plate, wherein the tube holes are arranged in a square geometry, and wherein each heating fluid hole is centrally disposed between four adjacent tube holes.

14. The shell-and-tube stripper according to claim 1 wherein the stripper comprises more than 3000 tubes.

15. The shell-and-tube stripper according to claim 14 , wherein the stripper comprises 5000 to 10000 tubes.

16. The shell-and-tube stripper according to claim 1 , wherein the bottom end comprises an inlet for the stripping gas.

17. A system for production of urea comprising a carbamate condenser, a urea reactor, and a shell-and-tube stripper according to claim 1 .

18. A heating fluid distributor for homogenizing a flow of steam adjacent to a heating fluid inlet of a shell-and-tube stripper for stripping a urea/carbamate mixture, the heating fluid distributor comprising an edge wall and a heating fluid distribution plate which is disposed parallel to lateral cross sections of the shell-and-tube stripper;
the edge wall comprising two or more openings and/or a plurality of perforations, the heating fluid distribution plate having an outer rim and a center, the heating fluid distribution plate comprising a plurality of perforations, the plurality of perforations comprising a plurality of tube holes and a plurality of heating fluid holes, wherein a size and/or a density of the heating fluid holes changes from the center of the heating fluid distribution plate towards the outer rim of the heating fluid distribution plate.

19. A method for stripping a urea/carbamate mixture, the method comprising steps of:
providing a shell-and-tube stripper according to claim 1 ;
providing the urea/carbamate mixture to the inlet for the urea/carbamate mixture;
providing a heating fluid to the shell-side space by means of the heating fluid inlet, wherein the heating fluid is saturated steam;
contacting the urea/carbamate mixture and the stripping gas in a tube-side space disposed within the tubes, and heating the urea/carbamate mixture by means of the heating fluid, thereby obtaining a urea/carbamate stream concentrated in urea;
extracting the urea/carbamate stream con

Assignees

• Yara Int Asa

Inventors

• Porro Lino Giovanni

Classifications

• C07C273/16 Primary

  Separation; Purification · CPC title

• B01J8/067

  Heating or cooling the reactor (B01J8/062 takes precedence) · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J19/006

  Baffles · CPC title

• B01J19/2425 Primary

  in parallel · CPC title