Cordierite-containing ceramic bodies, batch composition mixtures, and methods of manufacturing cordierite-containing ceramic bodies

Patent metadata

Field	Value
Publication number	US-11976012-B2
Application number	US-201917294121-A
Country	US
Kind code	B2
Filing date	Nov 6, 2019
Priority date	Nov 16, 2018
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

A cordierite-containing ceramic body with % P≥50%, df≤0.50, and a combined weight percentage of crystalline phases containing cordierite and indialite of at least 85 wt %. The porous ceramic body contains, as expressed on a relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 that is within a field defined by (15.4, 34.1, and 50.5), (12.2, 34.1, and 53.7), (13.3, 31.2, and 55.5), and (16.6, 31.1, and 52.3). Batch composition mixtures and methods of manufacturing a porous ceramic body using the batch compositions are provided, as are other aspects.

First claim

What is claimed is:

1. A porous ceramic body comprising:
a predominant crystalline phase of non-stoichiometric cordierite and a composition on a relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 that is within a field defined by (15.4, 34.1, and 50.5), (12.2, 34.1, and 53.7), (13.3, 31.2, and 55.5), and (16.6, 31.1, and 52.3), where the composition on an aggregate oxide basis is 5 wt% to 24 wt% of Mg 3 Al 2 Si 6 O 18 and 76 wt% to 95 wt% Mg 2 Al 4 Si 5 O 18 ;
% P≤50%; and
d f ≤0.50,
wherein % P is average bulk porosity by volume, and d f =(d 50 −d 10 )/d 50 , wherein d 50 is a median pore size of the porous ceramic body.

2. The porous ceramic body of claim 1 , wherein the composition on the relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 is within a field defined by (13.5, 34.1, and 52.4), (12.2, 34.1, and 53.7), (13.3, 31.2, and 55.5) and (14.7, 31.2, and 54.2).

3. The porous ceramic body of claim 1 , wherein the composition on the relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 is within a field defined by (15.4, 34.1, and 50.5), (14.3, 34.1, and 51.6), (14.5, 31.7, and 53.9), (14.7, 31.2, and 54.2), and (16.6, 31.1, and 52.3).

4. The porous ceramic body of claim 1 , wherein 55%≤% P≤72%.

5. The porous ceramic body of claim 1 , wherein 60%≤% P≤72%.

6. The porous ceramic body of claim 1 , wherein d f ≤0.22.

7. The porous ceramic body of claim 1 , wherein 0.20≤d f ≤0.30.

8. The porous ceramic body of claim 1 , wherein 0.20≤d f ≤0.25.

9. The porous ceramic body of claim 1 , wherein:
% P≥60%;
d 50 ≥10 μm;
df≤0.25; and
CTE≤10×10 −7 /° C., wherein CTE is a coefficient of thermal expansion of the porous ceramic body as measured from 25° C. to 800° C.

10. The porous ceramic body of claim 1 , wherein:
% P≥65%;
d 50 ≥12 μm;
df≤0.22; and
4×10 −7 /° C.≤CTE≤10×10 −7 /° C., wherein CTE is a coefficient of thermal expansion of the porous ceramic body as measured from 25° C. to 800° C.

11. The porous ceramic body of claim 1 , wherein:
55%≤% P≤72%;
8 μm≤d 50 ≤22 μm;
0.20≤df≤0.50; and
4×10 −7 /° C.≤CTE≤14×10 −7 /° C.

12. The porous ceramic body of claim 1 , wherein the body is a honeycomb body.

13. The porous ceramic body of claim 1 , wherein a weight percentage of the crystalline phase of the non-stoichiometric cordierite ranges from 54 wt % to 77 wt %.

14. The porous ceramic body of claim 1 , further comprising a crystalline phase of indialite, and wherein a weight percentage of the crystalline phase of the indialite ranges from 16 wt % to 33 wt %.

15. The porous ceramic body of claim 1 , further comprising a crystalline phase of indialite, and wherein a combined weight percentage of the crystalline phase of the non-stoichiometric cordierite and the crystalline phase of the indialite ranges from 85 wt % to 97 wt %.

16. The porous ceramic body of claim 1 , further comprising d b ≤0.70, wherein d b =(d 90 −d 10 )/d 50 .

17. A porous ceramic body comprising:
a predominant crystalline phase of non-stoichiometric cordierite and a composition on a relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 that is within a field defined by (15.4, 34.1, and 50.5), (12.2, 34.1, and 53.7), (13.3, 31.2, and 55.5), and (16.6, 31.1, and 52.3), wherein the composition comprises a solid solution of Mg 2 Al 4 Si 5 O 18 with Mg 3 Al 5 P 3 O 18 , Mg 2 Al 5 Si 3 PO 18 , Mg 3 Al 3 Si 4 PO 18 , or any combination thereof;
% P≥50%; and
d f ≤0.50,
wherein % P is average bulk porosity by volume, and d f =(d 50 −d 10 )/d 50 , wherein d 50 is a median pore size of the porous ceramic body.

18. A porous ceramic body comprising:
a predominant crystalline phase of non-stoichiometric cordierite and a composition on a relative oxide weight percent basis in terms of MgO, Al 2 O 3 , and SiO 2 that is within a field defined by (15.4, 34.1, and 50.5), (12.2, 34.1, and 53.7), (13.3, 31.2, and 55.5), and (16.6, 31.1, and 52.3), wherein the composition comprises a solid solution in the porous ceramic body which comprises: 1 wt % to 9 wt % Mg 3 Al 5 P 3 O 18 , 1 wt % to 14 wt % Mg 2 Al 5 Si 3 PO 18 , 1 wt % to 8 wt % Mg 3 Al 3 Si 4 PO 18 , or combinations thereof, and Mg 2 Al 4 Si 5 O 18 ;
% P≥50%; and
d f ≤0.50,
wherein % P is average bulk porosity by volume. and d f =(d 50 −d 10 )/d 50 , wherein d 50 is a median pore size of the porous ceramic body.

Assignees

• Corning Inc

Inventors

• Kuchibhotla Huthavahana Sarma
• Tanner Cameron Wayne

Classifications

• C04B38/0006 Primary

  Honeycomb structures (from one or more corrugated sheets by winding or stacking C04B38/0083) · CPC title

• B01D46/2429

  of the honeycomb walls or cells · CPC title

• B01D46/24491

  Porosity · CPC title

• B01D46/24492

  Pore diameter · CPC title

• B01D46/24494

  Thermal expansion coefficient, heat capacity or thermal conductivity · CPC title