Pulse current assisted uncanned rolling method for titanium-TiAl composite plates

Patent metadata

Field	Value
Publication number	US-11975370-B2
Application number	US-202017311241-A
Country	US
Kind code	B2
Filing date	Oct 23, 2020
Priority date	Oct 23, 2019
Publication date	May 7, 2024
Grant date	May 7, 2024

Abstract

The present disclosure provides a pulse current assisted uncanned rolling method for titanium-TiAl composite plates, including the following specific steps: 1. preparing titanium alloy sheets; 2. preparing TiAl alloy sheets; 3. uncanned lay-up; 4. pulse current assisted hot-rolling; 5. separation and subsequent processing, thus getting the titanium-TiAl composite plates. The composite plates are of good quality on the surface without oxide layer shedding, no cracks at the edges and the ends, with uniform and fine microstructures, good bonding interface and excellent mechanical properties.

First claim

What is claimed is:

1. A pulse current assisted uncanned rolling method for titanium-TiAl composite plates, comprising the following steps:
step 1, preparation of titanium alloy sheets:
a. melting a titanium alloy by a vacuum induction levitation melting process, to obtain cylindrical ingots, wherein the cylindrical ingots have a diameter of ≥100 mm and a height of ≥180 mm;
b. cutting off risers from the ingots and removing oxide skin from the surface by turn milling to obtain titanium alloy billets, then holding the titanium alloy billets in a box-type vacuum heat treatment furnace at 900° C.˜1100° C. for 30˜60 min, upsetting the titanium alloy billets with a hydraulic forging press at a strain rate of 0.01˜0.05 s −1 , for which the total deformation is 70˜80%; at the end of upsetting, holding the billets in the vacuum heat treatment furnace at 400° C.˜500° C. for 2 h, and furnace cooling the billets to obtain upset billets;
c. removing oxide skin from the upset billets, flattening the surface, cutting the cores of forging discs and processing into standard rectangular blocks, chamfering the deformation front ends of the upset billets, holding in the box-type vacuum heat treatment furnace at 900° C.˜1100° C. for 30˜60 min, and then rolling at a rolling speed of 0.5˜1.5 m/s, for which the pass reduction rate is 30%˜40%, holding the passes back in the furnace at a holding temperature of 900° C.˜1100° C. and for a period of 10˜15 min, the total rolling deformation is 70%˜80%, holding the rolled sheets in the vacuum heat treatment furnace at 400° C.˜500° C. for 2 h, and furnace cooling the rolled sheets to obtain titanium alloy sheets;
step 2, preparation of TiAl alloy sheets:
a. melting a TiAl alloy by a vacuum induction levitation melting process, to get cylindrical ingots, wherein the cylindrical ingots have a diameter of ≥100 mm and a height of ≥180 mm;
b. cutting off risers from the TiAl alloy ingots and then conducting hot isostatic pressing, then cutting off risers from the ingots and removing oxide skin from the surface by turn milling, and flattening the upper and lower end faces of the TiAl alloy ingots;
c. spraying high temperature anti-oxidation coating onto the circumferential face and the upper and lower end faces of cylindrical TiAl alloy billets, holding in the box-type vacuum heat treatment furnace at 1200° C.˜1250° C. for 30˜60 min, heating the upper and lower anvils of the press with a split cylindrical box-type resistance furnace to 600° C.˜700° C., conducting uncanned near-isothermal upsetting on the TiAl alloy billets at a strain rate of 0.01˜0.05 s −1 , for which the total deformation is 70˜80%; at the end of upsetting, holding the billets in the vacuum heat treatment furnace at 900° C.˜1000° C. for 2 h, furnace cooling;
d. removing oxide skin from the upset billets, flattening the surface, cutting the cores of forging discs and processing into standard rectangular blocks, to obtain the TiAl alloy sheets;
step 3, uncanned lay-up:
a. cutting off billets with certain dimensions from the titanium alloy and TiAl alloy sheets prepared in steps 1 and 2 by wire cut electrical discharge machining, in which the thickness ratio of titanium alloy to TiAl alloy is 1.2:1˜2:1; cutting the bottom titanium alloy concave billets from the cores of forging discs in step 1, chamfering the ends of the billets, then conducting surface treatment on the titanium alloy and TiAl alloy billets by means of mechanical polishing until the surface roughness reaches Ra1.6-Ra0.8, then ultrasonic cleaning in an acetone solution for 5˜10 min, and then taking out and drying;
b. laying-up the surface-treated titanium alloy and TiAl alloy billets in a symmetric stacking manner, with the titanium alloy on the outside, evacuating and then welding on by a tungsten argon arc welding process, to get the titanium-TiAl alloy slabs to be rolled;
step 4, pulse current assisted hot-rolling:
a. holding the titanium-TiAl alloy slabs to be rolled from step 3 in the vacuum box-type heat treatment furnace at 1050° C.˜1150° C. for 30˜60 min;
b. taking the titanium-TiAl alloy slabs to be rolled out of the furnace for electroplastic rolling, in which pulse current is fed into the slabs away from the rolling inlet through a copper conductive clamp equipped with a graphite gasket, the rolling speed is 0.5˜1.5 m/s, and the pass reduction rate is 15%˜25%; holding the passes back in the furnace at a holding temperature of 1050° C.˜1150° C. and for a period of 10˜15 min, the total rolling deformation is 50%˜60%;
c. holding the rolled sheets in the vacuum heat treatment furnace at 900° C.˜1000° C. for 2 h, furnace cooling, to get annealed titanium-TiAl composite plates; and
step 5, separation and subsequent processing:
a. trimming the annealed titanium-TiAl composite plates obtained from step 4 by means of mechanical processing, and separating the upper and lower composite plates;
b. conducting surface treatment on the composite plates mechanically, polishing until the surface roughness reaches Ra1.6˜Ra0.8, then ultrasonic cleaning in an acetone solution for 5˜10 min, and then taking out and drying, to get the titanium-TiAl composite plates.

2. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the titanium alloy types in step 1 comprise TC4 (Ti-6Al-4V) titanium alloy or BT16 (Ti-3Al-4.5V-5Mo) titanium alloy; the TiAl alloy types in step 2 comprise Ti-44Al-8Nb-(B,Y) alloy or Ti-43Al-4Nb-2Mo-2V alloy.

3. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the heat treating atmosphere in b and c of step 1 is argon atmosphere, of which the argon pressure is 0.95˜1 MPa and the mass purity of argon is 99.99%.

4. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the atmosphere of hot isostatic pressing and heat treatment in b and c of step 2 is argon atmosphere, of which the argon pressure is 0.95˜1 MPa and the mass purity of argon is 99.99%.

5. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the hot isostatic pressing process is: the hot isostatic pressing temperature is 1230° C.˜1260° C., the pressure is 100 MPa˜150 MPa, under the protection of an argon atmosphere, holding for a period of 3 h˜4 h, and tapping with the cooling of the furnace.

6. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the chamfered corner in a of step 3 is a round corner with an angle of 45° and a radius of 3˜6 mm; evacuating the air inside the lay-up through a vacuum pump.

7. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 1 , wherein, the heat treating atmosphere in a, b and c of step 4 is argon atmosphere, of which the argon pressure is 0.95˜1 MPa and the mass purity of argon is 99.99%; feeding a large flow of argon when opening and closing the furnace door to ensure an inert atmosphere environment; the pulse current in b of step 4 has a frequency of 300 Hz˜800 Hz, its wave form is rectangle, the voltage is 120 V, and the peak current is 100˜200 A·mm −2 ; the insulation of the rolling mill stand is realized by ceramic insulation gaskets for the bearing seat.

8. The pulse current assisted uncanned rolling method for titanium-TiAl composite plates according to claim 4 , wherein, the hot isostatic pressing process is: the hot isostatic pressing temperature is 1230° C.˜1260° C., the pressure is 100 MPa˜150 MPa, under the protection of an argon atmosphere, holding for a period of 3 h˜4 h, and tapping with the cooling of the furnace.

Assignees

• Univ Taiyuan Technology

Inventors

• Han Jianchao
• Jia Yi
• Wang Tao
• Ren Zhongkai
• Liu Yuanming
• He Dongping
• Li Sha
• Guo Miao

Classifications

• B21B1/38 Primary

  for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, {pack rolling}(B21B1/40 takes precedence; folding sheets before, or separating layers after, rolling B21B47/00) · CPC title

• B21B3/00

  Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences {; Rolling of aluminium, copper, zinc or other non-ferrous metals}(altering special metallurgical properties of alloys, other than structure consolidation or mechanical properties resulting therefrom C21D, C22F) · CPC title

• B21B15/0007

  Cutting or shearing the product · CPC title

• B21B15/0035

  Forging or pressing devices as units · CPC title

• B22D7/005

  from non-ferrous metals · CPC title