Electrode for membrane-electrode assembly and method of manufacturing same

Patent metadata

Field	Value
Publication number	US-11973230-B2
Application number	US-202017027142-A
Country	US
Kind code	B2
Filing date	Sep 21, 2020
Priority date	Apr 27, 2020
Publication date	Apr 30, 2024
Grant date	Apr 30, 2024

Abstract

Disclosed are an electrode including a porous substrate, a membrane-electrode assembly for a fuel cell including the same and a method of manufacturing the same. In the method of manufacturing the membrane-electrode assembly, the amount of a catalyst that is loaded depending on the position is applied in a gradational manner, thus efficiently using the catalyst, thereby reducing costs owing to the use of a decreased amount of the metal catalyst. Further, the membrane-electrode assembly includes the electrode including a porous substrate, thus making it easy to select hot-pressing conditions and increasing processing efficiency. The porous substrate is hydrophobic and the pore size in the electrode is not decreased compared to conventional electrodes, thus reducing flooding and generating various operation regions. The electrode including the porous substrate can minimize electrode loss, thus improving electrode durability.

First claim

What is claimed is:

1. An electrode for a membrane-electrode assembly, comprising:
a porous substrate having pores therein; and
an electrode material located in the pores of the porous substrate,
wherein a region of the porous substrate when viewed in a cross-section in a thickness direction has a different thickness than a remaining region of the porous substrate,
wherein the region of the porous substrate when viewed in the cross-section in the thickness direction has a different electrode density than the remaining region of the porous substrate,
wherein the porous substrate comprises one or more selected from the group consisting of polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene (ETFE), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-perfluoroalkylvinylether copolymer (PFA), polyimide, polyester, and polyethylene terephthalate (PET),
wherein the electrode material comprises a metal catalyst,
wherein the porous substrate comprises a first region and a second region, having different thicknesses when viewed in the cross-section in the thickness direction,
wherein a thickness of the first region is greater than a thickness of the second region,
wherein one surface of the porous substrate is flat and an opposite surface of the porous substrate is irregular depending on a shape of the first region and the second region,
wherein the thickness of the first region is 5 to 10 μm and the thickness of the second region is 2 to 5 μm, and
wherein a loaded amount (mg/cm 2 ) of the metal catalyst in the electrode material is applied in a gradational manner over the thickness of the first region.

2. The electrode of claim 1 , wherein the one surface of the porous substrate that is flat is configured to contact an electrolyte membrane of the membrane-electrode assembly.

3. The electrode of claim 1 , wherein the loaded amount of the metal catalyst that is loaded in the electrode material incorporated into the first region is greater than the loaded amount of the metal catalyst that is loaded in the electrode material incorporated into the second region.

4. The electrode of claim 1 , wherein the loaded amount of the metal catalyst that is loaded in the electrode material incorporated into the first region is 0.5 to 1.0 mg/cm 2 , and the loaded amount of the metal catalyst that is loaded in the electrode material incorporated into the second region is 0.05 to 0.5 mg/cm 2 .

5. The electrode of claim 1 , wherein a connecting portion connects the first region and the second region at a right angle or obliquely.

6. The electrode of claim 1 , wherein the pores have a size of 0.8 to 5.0 μm.

7. The electrode of claim 1 , wherein the first region has a porosity of 50 to 80% and the second region has a porosity of 10 to 50%.

8. The electrode of claim 1 , wherein an electrode density of the first region is greater than an electrode density of the second region.

9. The electrode of claim 8 , wherein the electrode density of the first region is 0.20 to 0.35 mg/cm2 and the electrode density of the second region is 0.05 to 0.20 mg/cm2.

10. A fuel cell, comprising:
a membrane-electrode assembly comprising an electrolyte membrane and an electrode disposed on each of opposite surfaces of the electrolyte membrane; and
a subgasket comprising a center portion contacting the membrane-electrode assembly and an edge portion excluding the center portion,
wherein the electrode comprises a porous substrate having pores therein, and an electrode material located in the pores of the porous substrate,
wherein a region of the porous substrate when viewed in a cross-section in a thickness direction has a different electrode density than a remaining region of the porous substrate,
wherein the porous substrate comprises one or more selected from the group consisting of polytetrafluoroethylene (PTFE), ethylene/tetrafluoroethylene (ETFE), tetrafluoroethylene-hexafluoropropylene copolymer (FEP), tetrafluoroethylene-perfluoroalkylvinylether copolymer (PFA), polyimide, polyester, and polyethylene terephthalate (PET),
wherein the electrode material comprises a metal catalyst,
wherein the edge portion comprises an air inlet and a hydrogen inlet,
wherein the porous substrate comprises a first region and a second region, the first region being thicker than the second region when viewed in the cross-section in the thickness direction,
wherein one surface of the porous substrate is flat and an opposite surface of the porous substrate is irregular depending on a shape of the first region and the second region,
wherein the thickness of the first region is 5 to 10 μm and the thickness of the second region is 2 to 5 μm, and
wherein a loaded amount (mg/cm 2 ) of the metal catalyst in the electrode material is applied in a gradational manner over the thickness of the first region.

11. The fuel cell of claim 10 , wherein the one surface of the porous substrate that is flat is configured to contact the electrolyte membrane of the membrane-electrode assembly.

Assignees

• Hyundai Motor Co Ltd
• Kia Motors Corp

Inventors

• Seol Su Won
• Yang Ji Hoon
• Cho Yoon Hwan

Classifications

• H01M4/8626 Primary

  characterised by the form · CPC title

• H01M4/8828

  Coating with slurry or ink · CPC title

• H01M8/1004 Primary

  characterised by membrane-electrode assemblies [MEA] (H01M8/12 takes precedence) · CPC title

• H01M4/8636 Primary

  with a gradient in another property than porosity (H01M4/861 takes precedence) · CPC title

• H01M8/0247 Primary

  characterised by the form (characterised by a channel configuration H01M8/0258) · CPC title