Ethylene/alpha-olefin interpolymer compositions with improved long term heat aging performance

US11970602B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11970602-B2
Application numberUS-201816969972-A
CountryUS
Kind codeB2
Filing dateFeb 14, 2018
Priority dateFeb 14, 2018
Publication dateApr 30, 2024
Grant dateApr 30, 2024

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  1. Title

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  2. Abstract

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  4. Key dates

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  5. First independent claim

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Abstract

Official abstract text for this publication.

A first composition comprising a first ethylene/α-olefin/diene interpolymer and a second ethylene/α-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 40 to 70 wt % ethylene, based on the weight of the first composition.

First claim

Opening claim text (preview).

What is claimed is: 1. A first composition comprising from 30 to 40 wt % of a first ethylene/α-olefin/diene interpolymer and from 60 to 70 wt % of a second ethylene/α-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 45 to 65 wt % ethylene, based on the weight of the first composition, and wherein the first ethylene/α-olefin/diene interpolymer has a weight average molecular weight (Mw) from 250,000 to 500,000 g/mole, and a diene content from 0.40 to 0.60 wt % and has a C2 (polymerized ethylene) content from 55 to 80 wt %, based on the weight of the first ethylene/α-olefin/diene interpolymer, and wherein the first composition has a weight average molecular weight (Mw) from 200,000 to 280,000 g/mole, a % crystallinity from 0.5% to 12% and has a “% Peak Area (21.3 to 22.0 ppm)” >5.0%, as determined by 13C NMR and the ratio of the C2 (polymerized ethylene) content of the first composition to the C2 (polymerized ethylene) content in the first ethylene/α-olefin/diene interpolymer is from 0.50 to 1.10; and wherein the ratio of the Mooney Viscosity (ML, 1+4, 125° C.) of the first composition to the Mooney Viscosity (ML, 1+4, 125° C.) of the first ethylene/α-olefin/diene interpolymer is from 0.75 to 1.05. 2. The first composition of claim 1 , wherein the first ethylene/α-olefin/diene interpolymer and the second ethylene/α-olefin interpolymer are each, independently, an EPDM. 3. The first composition of claim 1 , wherein the first composition has a molecular weight distribution (Mw/Mn) from 2.10 to 3.20. 4. The first composition of claim 1 , wherein the first interpolymer and the second interpolymer comprise ≥95 wt % of the total weight of the first composition. 5. A crosslinked composition comprising the first composition of claim 1 . 6. An article comprising at least one component formed from the first composition of claim 1 . 7. A composition comprising the first composition of claim 1 and an additive. 8. The composition of claim 7 , wherein the additive is MgO or ZnO. 9. The composition of claim 7 , wherein the first composition is present in an amount from 26 wt % to 42 wt %, based on the weight of the composition. 10. The composition of claim 7 , wherein the composition, after 1008 hours, at 150° C., in air, retains ≥50% of its original Tensile Strength, and retains ≥35% of its original Elongation at Break. 11. A crosslinked composition comprising the composition of claim 7 . 12. An article comprising at least one component formed from the composition of claim 7 . 13. The composition of claim 1 , wherein the composition, after 1008 hours, at 150° C., in air, retains ≥50% of its original Tensile Strength, and retains ≥35% of its original Elongation at Break.

Assignees

Inventors

Classifications

  • C08L23/16Primary

    Ethylene-propylene or ethylene-propylene-diene copolymers · CPC title

  • with non-conjugated dienes, e.g. EPT rubbers · CPC title

  • containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure · CPC title

  • Crosslinking · CPC title

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What does patent US11970602B2 cover?
A first composition comprising a first ethylene/α-olefin/diene interpolymer and a second ethylene/α-olefin interpolymer, and wherein the first composition comprises from 0.1 to 1.0 wt % diene, based on the weight of the first composition, and wherein the first composition comprises from 40 to 70 wt % ethylene, based on the weight of the first composition.
Who is the assignee on this patent?
Dow Global Technologies Llc
What technology area does this patent fall under?
Primary CPC classification C08L23/16. Mapped technology areas include Chemistry & Metallurgy.
When was this patent published?
Publication date Tue Apr 30 2024 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 6 related publications on this page (citations in our corpus or others sharing the same primary CPC).