Multilayer films that include at least five layers and methods of producing the same

Patent metadata

Field	Value
Publication number	US-11969976-B2
Application number	US-202017632468-A
Country	US
Kind code	B2
Filing date	Aug 4, 2020
Priority date	Aug 6, 2019
Publication date	Apr 30, 2024
Grant date	Apr 30, 2024

Abstract

Embodiments of the present disclosure are directed to multilayer films. Embodiments of the multilayer films may include a first layer comprising a first polyolefin, a second layer comprising a second polyolefin, a third layer comprising a third polyolefin, fourth layer comprising a fourth polyolefin, and a fifth layer comprising a fifth polyolefin. The second layer may be positioned between the first layer and the third layer; the third layer may be positioned between the second layer and the fourth layer; and the fourth layer may be positioned between the third layer and the fifth layer. Two or more of the first polyolefin, second polyolefin, third polyolefin, and fourth polyolefin may be the same or different. The third polyolefin may be a polyethylene composition having a density of 0.924 g/cm 3 to 0.936 g/cm 3 and a melt index (I 2 ) of 0.25 g/10 minutes to 2.0 g/10 minutes.

First claim

The invention claimed is:

1. A multilayer film comprising:
a first layer comprising a first polyolefin;
a second layer comprising a second polyolefin;
a third layer comprising a third polyolefin, wherein the second layer is positioned between the first layer and the third layer;
a fourth layer comprising a fourth polyolefin, wherein the third layer is positioned between the second layer and the fourth layer; and
a fifth layer comprising a fifth polyolefin, wherein the fourth layer is positioned between the third layer and the fifth layer;
wherein two or more of the first polyolefin, the second polyolefin, the third polyolefin, the fourth polyolefin, and the fifth polyolefin are the same or different in composition; and
wherein the third polyolefin is a polyethylene composition comprising:
(a) a first polyethylene fraction having a single peak in a temperature range of 45° C. to 87° C. in an elution profile via improved comonomer composition distribution (iCCD) analysis method, wherein a first polyethylene fraction area is an area in the elution profile beneath the single peak of the first polyethylene fraction between 45° C. and 87° C.; and
(b) a second polyethylene fraction having a single peak in a temperature range of 95° C. to 120° C. in the elution profile via iCCD analysis method and wherein a second polyethylene fraction area is an area in the elution profile beneath the single peak of the second polyethylene fraction between 95° C. and 120° C.;
wherein the polyethylene composition has a density of 0.924 g/cm 3 to 0.936 g/cm 3 and a melt index (I 2 ) of 0.25 g/10 minutes to 2.0 g/10 minutes, wherein the first polyethylene fraction area comprises at least 40% of the total area of the elution profile, wherein a ratio of the first polyethylene fraction area to the second polyethylene fraction area is 0.75 to 2.5, and wherein the width of the single peak of the second polyethylene fraction at 50 percent peak height is less than 5.0° C.

2. The multilayer film of claim 1 , wherein one or more of the first layer, the second layer, the third layer, the fourth layer, or the fifth layer are in direct contact with one another.

3. The multilayer film of claim 1 , wherein the first layer and the fifth layer are the outermost layers of the multilayer film.

4. The multilayer film of claim 1 , wherein:
the first layer is in direct contact with the second layer;
the second layer is in direct contact with the third layer;
the third layer is in direct contact with the fourth layer; and
the fourth layer is in direct contact with the fifth layer.

5. The multilayer film of claim 1 , wherein the polyethylene composition of the third layer has a zero shear viscosity ratio of less than 3.0.

6. The multilayer film of claim 1 , wherein the polyethylene composition of the third layer has a molecular weight distribution, expressed as the ratio of the weight average molecular weight to number average molecular weight (M w /M n ), in the range of from 2.5 to 8.0.

7. The multilayer film of claim 1 , wherein the multilayer film has a thickness of 15 microns to 250 microns.

8. The multilayer film of claim 1 , wherein one or both of the second polyolefin or the fourth polyolefin is a polyethylene having a density of greater than 0.940 g/cm 3 , when measured according to ASTM 742.

9. The multilayer film of claim 1 , wherein one or both of the first polyolefin or the fifth polyolefin is a linear low density polyethylene having a density from 0.905 g/cm 3 to 0.936 g/cm 3 .

10. The multilayer film of claim 1 , wherein the multilayer film has a dart drop impact of at least 700 grams when measured according to ASTM D1709 Method A.

11. The multilayer film of claim 1 , wherein the multilayer film has an average secant modulus in a machine direction of at least 60,000 psi, wherein the average secant modulus is measured in accordance with ASTM D882.

12. The multilayer film of claim 1 , wherein the multilayer film has an overall density of at least 0.925 g/cm 3 .

13. The multilayer film of claim 1 , wherein the multilayer film a tensile creep in a cross direction of less than 50%, when measured in accordance with ASTM D2990 at 1.7 kg, 15 hours, and 50° C.

14. A multilayer film comprising:
a first layer comprising a linear low density polyethylene having a density from 0.905 g/cm 3 to 0.936 g/cm 3 ;
a second layer comprising a polyethylene having a density of greater than 0.940 g/cm 3 , when measured according to ASTM 742:
a third layer comprising a third polyolefin, wherein the second layer is positioned between the first layer and the third layer;
a fourth layer comprising a polyethylene having a density of greater than 0.940 g/cm 3 , when measured according to ASTM 742, wherein the third layer is positioned between the second layer and the fourth layer; and
a fifth layer comprising a linear low density polyethylene having a density from 0.905 g/cm 3 to 0.936 g/cm 3 , wherein the fourth layer is positioned between the third layer and the fifth layer; and
wherein two or more of the first polyolefin, second polyolefin, third polyolefin, and fourth polyolefin have the same or different; and
wherein the third polyolefin is a polyethylene composition comprising:
(a) a first polyethylene fraction having a single peak in a temperature range of 45° C. to 87° C. in an elution profile via improved comonomer composition distribution (iCCD) analysis method, wherein a first polyethylene fraction area is an area in the elution profile beneath the single peak of the first polyethylene fraction between 45° C. and 87° C.; and
(b) a second polyethylene fraction having a single peak in a temperature range of 95° C. to 120° C. in the elution profile via iCCD analysis method and wherein a second polyethylene fraction area is an area in the elution profile beneath the single peak of the second polyethylene fraction between 95° C. and 120° C.;
wherein the polyethylene composition has a density of 0.924 g/cm 3 to 0.936 g/cm 3 and a melt index (I 2 ) of 0.25 g/10 minutes to 2.0 g/10 minutes, wherein the first polyethylene fraction area comprises at least 40% of the total area of the elution profile, wherein a ratio of the first polyethylene fraction area to the second polyethylene fraction area is 0.75 to 2.5, and wherein the width of the single peak of the second polyethylene fraction at 50 percent peak height is less than 5.0° C.

15. The multilayer film of claim 14 , wherein:
the first layer and the fifth layer are the outermost layers of the multilayer film;
the first layer is in direct contact with the second layer;
the second layer is in direct contact with the third layer;
the third layer is in direct contact with the fourth layer; and
the fourth layer is in direct contact with the fifth layer.

Assignees

• Dow Global Technologies Llc
• Dow Quim De Colombia S A

Inventors

• Camelo Jorge Mario Rodriguez
• De Oliveira Marlos Guintini
• Mazzola Nicolas Cardoso
• Biswas Sanjib
• Gaubert Joshua B
• Ginger Douglas S
• Kapur Mridula
• Oner-Deliormanli Didem
• Demirors Mehmet

Classifications

• B32B27/08 Primary

  of synthetic resin · CPC title

• B32B27/32 Primary

  comprising polyolefins {(comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30)} · CPC title

• B32B2250/05

  5 or more layers · CPC title

• B32B2250/242

  All polymers belonging to those covered by group B32B27/32 · CPC title

• B32B2307/558

  Impact strength, toughness · CPC title