Metal-carbon fiber reinforced resin material composite and method for manufacturing metal-carbon fiber reinforced resin material composite

Patent metadata

Field	Value
Publication number	US-11969969-B2
Application number	US-201917599914-A
Country	US
Kind code	B2
Filing date	Apr 2, 2019
Priority date	Apr 2, 2019
Publication date	Apr 30, 2024
Grant date	Apr 30, 2024

Abstract

What is provided is a new and improved metal-carbon fiber reinforced resin material composite in which the galvanic corrosion of dissimilar materials of a metal member is suppressed and electrodeposition coatability is excellent and a method for manufacturing the metal-carbon fiber reinforced resin material composite. A metal-carbon fiber reinforced resin material composite according to the present invention has a metal member, a resin coating layer disposed on at least a part of a surface of the metal member, and a carbon fiber reinforced resin material containing a matrix resin and a carbon fiber material present in the matrix resin, the resin coating layer contains any one or more kinds selected from the group consisting of metal particles, intermetallic compound particles, conductive oxide particles, and conductive non-oxide ceramic particles as conductive particles and further contains a binder resin, and the conductive particles have a powder resistivity at 23° C. to 27° C. of 7.0×10 7 Ω·cm or less and contain one or more selected from the group consisting of Zn, Si, Zr, V, Cr, Mo, Mn, and W.

First claim

The invention claimed is:

1. A metal-carbon fiber reinforced resin material composite comprising:
a metal member;
a resin coating layer disposed on at least a part of a surface of the metal member; and
a carbon fiber reinforced resin material that is disposed on at least a part of a surface of the resin coating layer and contains a matrix resin and a carbon fiber material present in the matrix resin,
wherein the resin coating layer contains one or a plurality of kinds of conductive particles selected from metal particles, intermetallic compound particles, conductive oxide particles, and conductive non-oxide ceramic particles and further contains a binder resin,
the conductive particles have a powder resistivity at 23° C. to 27° C. of 7.0 ×10 7 Ω·cm or less and contain one or more selected from the group including Zn, Si, Zr, V, Cr, Mo, Mn, and W as a configuration element, and
wherein at least one kind of said conductive particles is selected from one or more of Al-doped zinc oxide, ZrB 2 , MoSi 2 , CrB 2 , WSi 2 , VB 2 , ferrosilicon, and ferromanganese.

2. The metal-carbon fiber reinforced resin material composite according to claim 1 , wherein the conductive oxide particles are doped conductive oxide particles.

3. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein a volume rate of the conductive particles in the resin coating layer is 1.0% or more and 30.0% or less.

4. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein an average thickness of the resin coating layer is 1.0 μm or more and 200.0 μm or less.

5. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein an average particle size of the conductive particles is 50.0 μm or less.

6. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein, when an average thickness of the resin coating layer is represented by T (μm) and an average particle size of the conductive particles is represented by r (μm), a relationship of 0.5≤T/r≤300.0 is satisfied.

7. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein a glass transition temperature of the resin coating layer is 100° C. or lower.

8. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein the binder resin is an epoxy resin or a resin containing one or more kinds selected from the group including a urethane resin, an epoxy resin, a polyester resin, and a melamine resin and an epoxy resin.

9. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein the matrix resin contains a thermoplastic resin.

10. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein the matrix resin contains a phenoxy resin.

11. The metal-carbon fiber reinforced resin material composite according to claim 1 , further comprising:
an electrodeposition-coated coating formed on at least one selected from the group of the resin coating layer and the carbon fiber reinforced resin material.

12. The metal-carbon fiber reinforced resin material composite according to claim 1 ,
wherein the metal member is steel or plated steel.

13. A method for manufacturing a metal-carbon fiber reinforced resin material composite comprising:
a step of thermally compressing a metal member provided on at least a part of a surface of a resin coating layer containing conductive particles and a binder resin and a carbon fiber reinforced resin material through the resin coating layer,
wherein the conductive particles contain one or a plurality of kinds of metal particles, intermetallic compound particles, conductive oxide particles, and conductive non-oxide ceramic particles,
the conductive particles have a powder resistivity at 23° C. to 27° C. of 7.0 ×10 7 Ω·cm or less and contain one or more selected from the group including Zn, Si, Zr, V, Cr, Mo, Mn, and W as a configuration element, and
wherein at least one kind of said conductive particles is selected from one or more of Al-doped zinc oxide, ZrBz, MoSi, CrBz, WSi, VB, ferrosilicon, and ferromanganese.

14. The method for manufacturing a metal-carbon fiber reinforced resin material composite according to claim 13 , the method further comprising, before the step of thermal compression:
a step of forming the metal member.

15. The method for manufacturing a metal-carbon fiber reinforced resin material composite according to claim 13 , the method further comprising, after the step of thermal compression:
a step of forming a laminate in which the metal member and the carbon fiber reinforced resin material are laminated together.

16. The method for manufacturing a metal-carbon fiber reinforced resin material composite according to claim 13 , the method further comprising:
a step of forming an electrodeposition-coated coating on at least one selected from the group of the resin coating layer and on the carbon fiber reinforced resin material by electrodeposition coating.

17. The metal-carbon fiber reinforced resin material composite according to claim 2 ,
wherein a volume rate of the conductive particles in the resin coating layer is 1.0% or more and 30.0% or less.

Assignees

• Nippon Steel Corp

Inventors

• Ueda Kohei
• Kawamura Yasuaki
• Koori Masumi
• Ibaragi Masaharu

Classifications

• B32B15/14 Primary

  next to a fibrous or filamentary layer · CPC title

• B32B15/08

  of synthetic resin · CPC title

• C08J5/121

  by heating · CPC title

• C08J5/243

  using carbon fibres · CPC title

• C08J5/249

  characterised by the additives used in the prepolymer mixture · CPC title