Method for applying embossed structures to coating media while pre-treating the embossing tool used therefor

Patent metadata

Field	Value
Publication number	US-11969755-B2
Application number	US-202017615986-A
Country	US
Kind code	B2
Filing date	Jun 3, 2020
Priority date	Jun 3, 2019
Publication date	Apr 30, 2024
Grant date	Apr 30, 2024

Abstract

Described herein are a method for transferring an embossed structure, which includes at least the steps (1-i) and (2-i) or (1-ii) and (2-ii), where steps (1-i) and (2-i) or (1-ii) and (2-ii) are carried out using an embossing tool (P1) including at least one embossing die (p1), where the embossing die (p1) of the embossing tool (P1) is pretreated, before the implementation of step (2-i) or before the implementation of step (1-ii), with at least one organic solvent and/or at least one reactive diluent, and also a method of using a corresponding pretreated embossing tool (P1) including at least one embossing die (p1) for the purpose of transferring an embossed structure in such a way.

First claim

The invention claimed is:

1. A method for transferring an embossed structure using an embossing tool, which comprises at least the steps
( 1 - i ) applying a coating composition to at least a part of a surface of a substrate, to give a composite, and
( 2 - i ) at least partially embossing the coating composition, applied at least partially to the surface of the substrate, by means of at least one embossing tool comprising at least one embossing die,
or
( 1 - ii ) applying a coating composition to at least a part of an at least partially embossed surface of an embossing die of an embossing tool and
( 2 - ii ) applying a substrate to at least a part of the surface of the coating composition, applied to the embossing die, to give a composite on the embossing die,
which comprises pretreating the at least one embossing die of the embossing tool, before the implementation of step ( 2 - i ) and before the implementation of step ( 1 - ii ), with at least one organic solvent and/or at least one reactive diluent, and, through step ( 2 - i ) and step ( 1 - ii ), transferring microstructures having a structure depth >30 μm as embossed structure onto the coating composition;
wherein a solids content of the coating composition is ≥90 wt %, based on a total weight of the coating composition.

2. The method as claimed in claim 1 , wherein the pretreatment to be carried out before implementation of step ( 2 - i ) and step ( 1 - ii ) comprises wetting the at least one embossing die with at least one organic solvent and/or at least one reactive diluent.

3. The method as claimed in claim 1 , wherein the pretreatment to be carried out before implementation of step ( 2 - i ) and step ( 1 - ii ) takes place using at least one ultrasonic nozzle.

4. The method as claimed in claim 1 , wherein the at least one organic solvent used for the pretreatment is selected from the group consisting of C 1 -C 4 alcohols, and the at least one reactive diluent used for the pretreatment is selected from the group consisting of monofunctional, difunctional, trifunctional and polyfunctional (meth)acrylates and also mixtures thereof.

5. The method as claimed in claim 1 , wherein through step ( 2 - i ) and step ( 1 - ii ) microstructures and/or nanostructures are transferred as embossed structure onto the coating composition.

6. The method as claimed in claim 1 , wherein through step ( 2 - i ) and step ( 1 - ii ) microstructures having a structure depth >40 μm are transferred as embossed structure onto the coating composition.

7. The method as claimed in claim 1 , wherein an aspect ratio of the embossed structure transferred by step ( 2 - i ) and step ( 1 - ii ) onto the coating composition is >1.

8. The method as claimed in claim 1 , wherein a coating obtainable from the coating composition, and the at least one embossing die of the embossing tool, have embossed structures which are mirror images of one another.

9. The method as claimed in claim 1 , which comprises, after implementation of step ( 2 - i ) and of step ( 1 - ii ), at least one further step
( 3 ) at least partially curing the at least partially embossed coating composition, obtained after step ( 2 - i ) or step ( 1 - ii ), to give a composite composed of the substrate and of at least partially embossed and at least partially cured coating, wherein throughout a duration of the at least partial curing, the coating composition is in contact with the at least one embossing die of the at least one embossing tool, and
optionally comprises a step
( 4 ) removing the composite obtained after step ( 3 ) from the at least one embossing die of the embossing tool.

10. The method as claimed in claim 1 , wherein the coating composition is a coating composition which is curable by radiation.

11. The method as claimed in claim 1 , wherein the coating composition comprises at least one component which comprises at least one carbon double bond and which is present therein in an amount in a range from 40 to 95 wt %.

12. The method as claimed in claim 1 , wherein the coating composition comprises at least one monofunctional, difunctional, trifunctional and/or polyfunctional (meth)acrylate.

13. The method as claimed in claim 1 , wherein the substrate is a film web.

14. The method as claimed in claim 1 , wherein the substrate is a moving film web.

15. A method of using an embossing tool comprising at least one embossing die, the method comprising using the embossing tool for transferring an embossed structure to at least a part of a surface of a coating composition, wherein the at least one embossing die of the embossing tool has been pretreated, before the transfer, with at least one organic solvent and/or at least one reactive diluent, and the embossed structure transferred onto the coating composition comprises microstructures having a structure depth >30 μm, wherein a solids content of the coating composition is ≥90 wt %, based on a total weight of the coating composition.

16. A method for transferring an embossed structure using an embossing tool, which comprises at least the steps
( 1 - i ) applying a coating composition to at least a part of a surface of a substrate, to give a composite, and
( 2 - i ) at least partially embossing the coating composition, applied at least partially to the surface of the substrate, by means of at least one embossing tool comprising at least one embossing die,
or
( 1 - ii ) applying a coating composition to at least a part of an at least partially embossed surface of an embossing die of an embossing tool and
( 2 - ii ) applying a substrate to at least a part of the surface of the coating composition, applied to the embossing die, to give a composite on the embossing die,

which comprises pretreating the at least one embossing die of the embossing tool, before the implementation of step ( 2 - i ) and before the implementation of step ( 1 - ii ), with at least one organic solvent and/or at least one reactive diluent, and, through step ( 2 - i ) and step ( 1 - ii ), transferring microstructures having a structure depth >30 μm as embossed structure onto the coating composition;
wherein the at least one organic solvent used for the pretreatment is selected from the group consisting of C 1 -C 4 alcohols, and the at least one reactive diluent used for the pretreatment is selected from the group consisting of monofunctional, difunctional, trifunctional and polyfunctional (meth)acrylates and also mixtures thereof.

17. The method as claimed in claim 16 , wherein a solids content of the coating composition is ≥90 wt %, based on a total weight of the coating composition.

Assignees

• Basf Coatings Gmbh

Inventors

• Kues Jan-Bernd
• Piontek Susanne
• Exner Joerg
• Kleine-Bley Birgit
• Garcia Martin Alberto
• Noatschk Jens-Henning
• Lorenz Michael
• Von Der Aa Robert
• Bergmann Frank
• Schipper Wilfried

Classifications

• B05D3/12 Primary

  by mechanical means · CPC title

• B05D1/02

  performed by spraying · CPC title

• C09D133/04

  Homopolymers or copolymers of esters {(C09D143/04 takes precedence)} · CPC title

• B41F19/02 Primary

  with embossing · CPC title

• B29C59/046 Primary

  for layered or coated substantially flat surfaces · CPC title