High viscosity polyacrylate base fluids

Patent metadata

Field	Value
Publication number	US-11965140-B2
Application number	US-201917757031-A
Country	US
Kind code	B2
Filing date	Dec 12, 2019
Priority date	Dec 12, 2019
Publication date	Apr 23, 2024
Grant date	Apr 23, 2024

Abstract

Low molecular weight polyalkyl acrylate polymers can be used as high viscosity base fluids. A corresponding method can be used for their preparation. Lubricant compositions may contain such low molecular weight polyalkyl acrylate polymers and the compositions may be used as automatic transmission fluids, manual transmission fluids, continuously variable transmission fluids, gear oil formulations, industrial gear oil formulations, axle fluid formulations, dual clutch transmission fluids, dedicated hybrid transmission fluids, or hydraulic oils.

First claim

The invention claimed is:

1. A lubricant formulation, comprising:
a base oil comprising at least one polyalkyl acrylate, wherein the at least one polyalkyl acrylate comprises:
(a) 95 to 100% by weight of at least one branched C 8-10 -alkyl acrylate; and
(b) 0 to 5% by weight of at least one C 1-20 -alkyl (meth)acrylate,
wherein a weight-average molecular weight of the at least one polyalkyl acrylate is in the range of 7,000 to 25,000 g/mol and a residual monomer content is 0.1% by weight or lower.

2. The lubricant formulation according to claim 1 , wherein the at least one polyalkyl acrylate consists of 100% by weight of the at least one branched C 8-10 -to-alkyl acrylate.

3. The lubricant formulation according to claim 1 , wherein the at least one branched C 8-10 -alkyl acrylate is selected from the group consisting of 2-ethylhexyl acrylate and 2-propylheptyl acrylate.

4. A base oil composition, comprising:
(A) 70 to 95% by weight of at least one polyalkyl acrylate, comprising:
(a) 95 to 100% by weight of at least one branched C 8-10 -alkyl acrylate; and
(b) 0 to 5% by weight of at least one C 1-20 -alkyl (ineth)acrylate,
wherein a weight-average molecular weight of the at least one polyalkyl acrylate is in the range of 7,000 to 25,000 g/mol and a residual monomer content is 0.1% by weight or lower; and

(B) 5 to 30% by weight of a base oil selected from the group consisting of API Group oils, API Group III oils, API Group IV oils, and mixtures thereof,
based on a total weight of the base oil composition.

5. The base oil composition according to claim 4 , wherein the at least one polyalkyl acrylate consists of 100% by weight of the at least one branched C 8-10 -to-alkyl acrylate.

6. The base oil composition according to claim 4 , wherein the at least one branched C 8-10 -to-alkyl acrylate is selected from the group consisting of 2-ethylhexyl acrylate and 2-propylheptyl acrylate.

7. The base oil composition according to claim 4 , wherein the at least one branched C 8-10 -to-alkyl acrylate is ethylhexyl acrylate.

8. The base oil composition according to claim 4 , wherein the base oil composition is an industrial gear oil.

9. A polyalkyl acrylate, comprising:
(a) 95 to 100% by weight of at least one branched C 8-10 -alkyl acrylate; and
(b) 0 to 5% by weight of at least one C 1-20 -alkyl (meth)acrylate,
wherein a weight-average molecular weight of the polyalkyl acrylate is in the range of 7,000 to 25,000 g/mol and a residual monomer content is 0.1% by weight or lower.

10. The polyalkyl acrylate according to claim 9 , consisting of 100% by weight of the at least one branched C 8-10 -alkyl acrylate.

11. The polyalkyl acrylate according to claim 9 , wherein the at least one branched C 8-10 -alkyl acrylate is selected from the group consisting of 2-ethylhexyl acrylate and 2-propylheptyl acrylate.

12. The polyalkyl acrylate according to claim 9 , wherein the at least one branched C 8-10 -alkyl acrylate is ethylhexyl acrylate.

13. A lubricating composition, comprising:
(A) 20 to 60% by weight of at least one polyalkyl acrylate, comprising:
(a) 95 to 100% by weight of at least one branched Cs-to-alkyl acrylate; and
(b) 0 to 5% by weight of at least one C 1-20 -alkyl (meth)acrylate, based on a total weight of the at least one polyalkyl acrylate,
wherein a weight-average molecular weight of the at least one polyalkyl acrylate is in the range of 7,000 to 25,000 g/mol and a residual monomer content is 0.1% by weight or lower;

(B) 40 to 80% by weight of a base oil selected from the group consisting of API Group II oils, API Group III oils. API Group IV oils, and mixtures thereof, and
(C) 0 to 5% by weight of one or more additives,
based on a total weight of the lubricating composition.

14. The lubricating composition according to claim 8 , wherein the one or more additives are selected from the group consisting of pour point depressants, dispersants, defoamers, detergents, demulsifiers, antioxidants, antiwear additives, extreme pressure additives, friction modifiers, anticorrosion additives, dyes and mixtures thereof.

15. A process for preparing at least one polyalkyl acrylate, the process comprising:
(i)charging a reaction vessel with a base oil;
(ii) heating the base oil of (i) to a reaction temperature of 130° C. to 170° C.;
(ii) constantly feeding a mixture of at least one branched C 8-10 -alkyl acrylate and 0.1 to 1.2% of an initiator, based on an amount of the at least one branched C 8-10 -alkyl acrylate, to the reaction vessel over a time of 120 to 240 minutes, to obtain a reaction mixture;
(iv) optionally, stirring the reaction mixture obtained under (iii) for another 50 to 90 minutes, and
(v) cooling the reaction mixture obtained under (iv) to an ambient temperature and obtaining the at least one polyalkyl acrylate;
wherein the at least one polyalkyl acrylate comprises:
(a) 95 to 100% by weight of the at least one branched C 8-10 -alkyl acrylate, and
(b) 0 to 5% by weight of at least one C 1-20 -alkyl (meth)acrylate,
wherein a weight-average molecular weight of the at least one polyalkyl acrylate is in the range of 7,000 to 25,000 g/mol and a residual monomer content is 0.1% by weight or lower.

16. The lubricant formulation according to claim 1 , wherein the lubricant formulation is an industrial gear oil formulation.

17. The process of claim 15 , wherein the process optionally further comprises filtering the reaction mixture, and wherein the process does not comprise further purification, other than the optional filtering.

18. The polyalkyl acrylate according to claim 9 , consisting of 100% by weight of 2-ethylhexyl acrylate, 2-propylheptyl acrylate, or a combination thereof.

Assignees

• Evonik Operations Gmbh

Inventors

• Maier Stefan Karl
• Neusius Michael
• Xiao Qi
• Fedor Gabriela
• Hilf Stefan
• Mähling Frank-Olaf

Classifications

• C10M107/28 Primary

  containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate · CPC title

• C08F20/16

  of phenols or of alcohols containing two or more carbon atoms · CPC title

• C10M2203/003

  used as base material · CPC title

• C10M2209/0845

  used as base material · CPC title

• C10N2020/04

  Molecular weight; Molecular weight distribution · CPC title