Treatment of produced hydrocarbons

Patent metadata

Field	Value
Publication number	US-11965131-B2
Application number	US-201917415946-A
Country	US
Kind code	B2
Filing date	Dec 20, 2019
Priority date	Dec 21, 2018
Publication date	Apr 23, 2024
Grant date	Apr 23, 2024

Abstract

A method for managing metal naphthenates in produced hydrocarbons includes injecting acid and/or sour gas into produced hydrocarbons in a production well, flowline or riser, to thereby control the pH of fluids contained in the produced hydrocarbons.

First claim

The invention claimed is:

1. A method for preventing or mitigating the formation of, and/or removing, metal naphthenates in produced hydrocarbons during an artificial lift procedure, the method comprising:
injecting acid and sour gas simultaneously into produced hydrocarbons in a production well to facilitate lift of the produced hydrocarbons and to control the pH of fluids contained in the produced hydrocarbons to prevent an increase in the pH above a threshold pH value,
to thereby, as a result of said preventing an increase in the pH above the threshold pH value, prevent or mitigate the formation of, and/or remove, metal naphthenates in the produced hydrocarbons,
wherein the threshold pH value is the pH value at which metal naphthenates would otherwise form.

2. The method of claim 1 , wherein the produced hydrocarbons undergo a reduction in pressure during a processing stage that is performed after the acid and sour gas is injected, and the pH is controlled to prevent an increase in the pH above the threshold value during the reduction in pressure.

3. The method of claim 1 , wherein the pH is controlled to lower the pH of the fluids contained in the produced hydrocarbons, to thereby remove metal naphthenates formed in a reservoir from which the produced hydrocarbons are produced.

4. The method of claim 1 , wherein the metal naphthenates are oil-soluble metal naphthenates, precipitated metal naphthenates, and/or calcium naphthenates.

5. The method of claim 1 , wherein the fluids contained in the produced hydrocarbons are, or comprise, produced water.

6. The method of claim 1 , wherein the threshold pH value is between 7.5 and 3.

7. The method of claim 1 , wherein the acid and sour gas is injected into the produced hydrocarbons through one or more openings in production tubing located in the production well.

8. The method of claim 7 , wherein the one or more openings in the production tubing are provided with valves to control the inflow of acid and sour gas.

9. The method of claim 1 , wherein the produced hydrocarbons are contained in production tubing located in the production well, wherein the acid and sour gas is injected deep in the production well such that injection takes place close to a lower completion section.

10. The method of claim 1 , wherein the acid comprises an inorganic acid.

11. The method of claim 1 , wherein the acid comprises, or consists of, a carboxylic acid.

12. The method of claim 11 , wherein the carboxylic acid has an alkane chain comprising fewer than five carbons.

13. The method of claim 11 , wherein the carboxylic acid has a molecular weight of less than 400 g/mol.

14. The method of claim 1 , where the acid does not form ligands or precipitate in the presence of divalent metal ions.

15. The method of claim 1 , wherein the acid and sour gas has a higher temperature than fluids in a reservoir from which the produced hydrocarbons are produced.

16. The method of claim 1 , further comprising, before injecting the acid and sour gas:
simulating, using a computing device, pH conditions in a production train through which the produced hydrocarbons are conveyed; and
calculating, based on the results of the simulation, the concentration and amount of acid and sour gas to be injected.

Assignees

• Equinor Energy As

Inventors

• Haug Ingvild Johanne
• BØRRESEN Børre Tore
• Mediaas Heidi
• Kummernes Hege
• Larsen Ivar Øystein

Classifications

• C09K8/524 Primary

  organic depositions, e.g. paraffins or asphaltenes · CPC title

• C09K8/536

  characterised by their form or by the form of their components, e.g. encapsulated material · CPC title

• E21B37/06 Primary

  using chemical means for preventing or limiting {, e.g. eliminating,} the deposition of paraffins or like substances · CPC title

• E21B43/00 Primary

  Methods or apparatus for obtaining oil, gas, water, soluble or meltable materials or a slurry of minerals from wells (applicable only to water E03B) · CPC title

• C10G17/00 Primary

  Refining of hydrocarbon oils in the absence of hydrogen, with acids, acid-forming compounds or acid-containing liquids, e.g. acid sludge · CPC title