Long-branched polypropylene composition with increased melt strength stability
US-2018298174-A1 · Oct 18, 2018 · US
US11965084B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11965084-B2 |
| Application number | US-201817274530-A |
| Country | US |
| Kind code | B2 |
| Filing date | Sep 21, 2018 |
| Priority date | Sep 21, 2018 |
| Publication date | Apr 23, 2024 |
| Grant date | Apr 23, 2024 |
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A method for producing a polypropylene-based resin foamed molded article by blow molding a foamed parison formed of a base resin, in which: the base resin contains, in specific mixing proportions, a branched polypropylene-based resin (A), a linear polypropylene-based resin (B) and a recovered raw material (C) that is recovered in the course of production of the polypropylene-based resin foamed molded article. Each of the resin (A), resin (B) and the recovered raw material (C), has a specific range of a melt tension and a melt flow rate. A difference in melting point between the resin (A) and resin (B) is within a specific range. A difference in crystallization temperature between the resin (A) and resin (B) is within a specific range.
Opening claim text (preview).
The invention claimed is: 1. A method for producing a polypropylene-based resin foamed molded article, comprising extruding a foamable molten resin, obtained by kneading a base resin and a physical blowing agent, through a die to form a foamed parison, and blow molding the foamed parison, wherein said base resin comprises a branched polypropylene-based resin (A), a linear polypropylene-based resin (B) and a recovered raw material (C) that is recovered in the course of production of the polypropylene-based resin foamed molded article, wherein the branched polypropylene-based resin (A) has a melt tension (230° C.) of greater than 100 mN and a melt flow rate (230° C., load of 2.16 kg) of 0.1 to 15 g/10 min, the linear polypropylene-based resin (B) has a melt tension (230° C.) of less than 30 mN (not inclusive of 0) and a melt flow rate (230° C., load of 2.16 kg) of 5 to 25 g/10 min, the recovered raw material (C) has a melt tension (230° C.) of 5 to 50 mN and a melt flow rate (230° C., load of 2.16 kg) of 2 to 50 g/10 min, and wherein a difference (T m A−T m B) between a melting point T m A of the branched polypropylene-based resin (A) and a melting point T m B of the linear polypropylene-based resin (B) is −5° C. to 5° C., a difference (T c A−T c B) between a crystallization temperature T c A of the branched polypropylene-based resin (A) and a crystallization temperature T c B of the linear polypropylene-based resin (B) is 0 to 10° C., a mixing amount of the branched polypropylene-based resin (A) in the base resin is 5% by weight or more and less than 20% by weight based on 100% by weight of the base resin and a mixing amount of the recovered raw material (C) in the base resin is more than 65% by weight and 90% by weight or less based on 100% by weight of the base resin, and a weight ratio (A:B) of the mixing amount of the branched polypropylene-based resin (A) to a mixing amount of the linear polypropylene-based resin (B) in the base resin is 80:20 to 40:60. 2. The method for producing a polypropylene-based resin foamed molded article according to claim 1 , wherein the melt flow rate (230° C., load of 2.16 kg) of the linear polypropylene-based resin (B) is 10 to 25 g/10 min. 3. The method for producing a polypropylene-based resin foamed molded article according to claim 1 , wherein the melt tension (230° C.) of the recovered raw material (C) is 5 mN or more and less than 30 mN. 4. The method for producing a polypropylene-based resin foamed molded article according to claim 1 , wherein the physical blowing agent is an inorganic physical blowing agent. 5. The method for producing a polypropylene-based resin foamed molded article according to claim 1 , wherein the foamed molded article has an apparent density of 0.10 to 0.35 g/cm 3 .
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