Composition for odor suppression

Patent metadata

Field	Value
Publication number	US-11965081-B2
Application number	US-202017434198-A
Country	US
Kind code	B2
Filing date	Feb 18, 2020
Priority date	Feb 27, 2019
Publication date	Apr 23, 2024
Grant date	Apr 23, 2024

Abstract

The present disclosure provides a composition. In an embodiment, the composition includes an olefin-based polymer and from 0.15 wt % to 15 wt % of an odor suppressant. The odor suppressant includes (i) from 0.05 wt % to 2 wt % of a metal oxide having a band gap greater than 5.0 electron volts (eV), and (ii) from 0.1 wt % to 13 wt % of an acid copolymer. The ratio of metal oxide to acid copolymer is from 1:20 to 1:1. Weight percents are based on the total weight of the composition.

First claim

The invention claimed is:

1. A composition comprising:
(A) an ethylene-based polymer consisting of (i) ethylene and (ii) an optional C 3 -C 20 α-olefin comonomer;
(B) from 0.15 wt % to 15 wt % of an odor suppressant based on total weight of the composition, the odor suppressant consisting of
(Bi) from 0.05 wt % to 2 wt % based on the total weight of the composition of a metal oxide having a band gap greater than 5.0 electron volts (eV); and
(Bii) from 0.1 wt % to 13 wt % based on the total weight of the composition of an acid copolymer composed of (i) ethylene monomer and (ii) a carboxylic acid comonomer or ester derivative thereof; and
(C) optional antioxidant;
wherein (A), (Bi), (Bii), and (C) amount to 100 wt. % of the composition; and
wherein the ratio of metal oxide to acid copolymer is from 1:20 to 1:1.

2. The composition of claim 1 wherein the composition exhibits at least a 20% reduction in a volatile hetero-carbonyl species compared to the ethylene-based polymer without the odor suppressant, as measured by normalized gas chromatography.

3. The composition of claim 1 wherein the metal oxide is selected from the group consisting of calcium oxide and magnesium oxide.

4. The composition of claim 1 wherein the acid copolymer is selected from the group consisting of ethylene ethyl acrylate copolymer copolymer, ethylene butyl acrylate copolymer, ethylene acrylic acid copolymer, ethylene/(meth)acrylic acid copolymer, and combinations thereof.

5. The composition of claim 1 wherein the odor suppressant is a blend of the metal oxide particles dispersed in the acid copolymer.

6. The composition of claim 1 wherein the composition comprises
the ethylene-based polymer;
from 0.55 wt % to 5 wt % of the odor suppressant based on total weight of the composition, the odor suppressant comprising
(i) from 0.05 wt % to 1 wt % based on total weight of the composition of the metal oxide having a band gap greater than 5.0 electron volts (eV); and
(ii) from 0.5 wt % to 4 wt % based on total weight of the composition of the acid copolymer; and
the ratio of metal oxide to acid copolymer is from 1:4 to 1:1.

7. The composition of claim 1 wherein the metal oxide is particles of calcium oxide.

8. The composition of claim 1 wherein the acid copolymer is ethylene acrylic acid.

9. The composition of claim 1 wherein the ethylene-based polymer has
(i) a density from 0.910 g/cc to 0.920 g/cc;
(ii) a melt temperature (Tm) from 105° C. to 110° C.; and
(iii) a melt index from 5.0 g/10 min to 10.0 g/10 min.

10. The composition of claim 8 wherein the ethylene acrylic acid has from 5 wt % to 30 wt % acrylic acid comonomer.

11. The composition of claim 7 wherein the particles of calcium oxide have a D50 particle size from 100 nm to 3000 nm.

12. A process comprising:
(1) providing a composition, the composition comprising
(A) an ethylene-based polymer, the ethylene-based polymer consisting of (i) ethylene and (ii) an optional C 3 -C 20 α-olefin comonomer and having an amount of at least one volatile carbonyl-containing species;
(B) from 0.15 wt % to 15 wt %, based on total weight of the composition, of an odor suppressant consisting of
(Bi) from 0.05 wt % to 2 wt %, based on total weight of the composition, of a metal oxide having a band gap greater than 5.0 electron volts (eV); and
(Bii) from 0.1 wt % to 13 wt %, based on total weight of the composition, of an acid copolymer composed of (i) ethylene monomer and (ii) a carboxylic acid comonomer or ester derivative thereof, and
(C) optional antioxidant,
wherein (A), (B), (Bi), (Bii), and (C) amount to 100 wt% of the composition; and
wherein the ratio of metal oxide to acid copolymer is from 1:20 to 1:1; and
(2) neutralizing, with the odor suppressant, at least some of the volatile hetero-carbonyl species to form an odor-reduced composition.

13. The process of claim 12 comprising
forming an odor-reduced composition exhibiting at least a 20% reduction in the amount of a volatile hetero-carbonyl species compared to the ethylene-based polymer without the odor suppressant, as measured by normalized gas chromatography.

14. The process of claim 12 comprising dispersing, before the adding, particles of the metal oxide in the acid copolymer to form an odor suppressant pre-blend;
adding the odor suppressant pre-blend to the ethylene-based polymer; and
forming the odor-reduced composition.

Assignees

• Dow Global Technologies Llc

Inventors

• Mcalpin Casey R
• Krasovskiy Arkady L
• Sun Kefu
• Matteucci Scott T

Classifications

• C08L23/04 Primary

  Homopolymers or copolymers of ethene · CPC title

• C08K2003/2206

  of calcium, strontium or barium · CPC title

• C08K2003/2217

  of magnesium · CPC title

• C08L2203/16

  used for films · CPC title