Reversible bifunctional air electrode catalyst for rechargeable metal air battery and regenerative fuel cell
US-2016308220-A1 · Oct 20, 2016 · US
US11961960B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11961960-B2 |
| Application number | US-201917055890-A |
| Country | US |
| Kind code | B2 |
| Filing date | May 16, 2019 |
| Priority date | May 18, 2018 |
| Publication date | Apr 16, 2024 |
| Grant date | Apr 16, 2024 |
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Provided is a lithium secondary battery having a higher capacity and a longer life. The lithium secondary battery includes: a positive electrode including a material capable of intercalation and deintercalation of a lithium ion; a lithium ion-conductive electrolyte including a salen-based metal complex; and a negative electrode including a material capable of occlusion and release of a lithium metal or a lithium ion. The salen-based metal complex is selected from (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminotitanium chloride (TiSl), VSl, CrSl, MnSl, FeSl, CoSl, and RuSl.
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The invention claimed is: 1. A lithium secondary battery comprising: a positive electrode comprising a material capable of intercalation and deintercalation of a lithium ion; a lithium ion-conductive electrolyte comprising a salen-based metal complex, wherein the salen-based metal complex is selected from (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminotitanium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminovanadium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoiron chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt; or (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoruthenium chloride; and a negative electrode comprising a material capable of occlusion and release of a lithium metal or a lithium ion. 2. The lithium secondary battery according to claim 1 , wherein the salen-based metal complex includes at least two of the: (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminotitanium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminovanadium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminochromium chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminomanganese chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoiron chloride; (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminocobalt; or (R,R)-(−)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediaminoruthenium chloride. 3. The lithium secondary battery according to claim 2 , wherein the electrolyte comprises a lithium ion-conductive organic electrolyte solution. 4. The lithium secondary battery according to claim 2 , wherein the electrolyte comprises a lithium ion-conductive gel polymer electrolyte. 5. The lithium secondary battery according to claim 2 , wherein the electrolyte comprises a lithium ion-conductive solid electrolyte. 6. The lithium secondary battery according to claim 1 , wherein the electrolyte comprises a lithium ion-conductive organic electrolyte solution. 7. The lithium secondary battery according to claim 1 , wherein the electrolyte comprises a lithium ion-conductive gel polymer electrolyte. 8. The lithium secondary battery according to claim 1 , wherein the electrolyte comprises a lithium ion-conductive solid electrolyte.
Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title
characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes · CPC title
Organic electrolyte · CPC title
inorganic · CPC title
Polymeric materials, e.g. gel-type or solid-type · CPC title
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