Methods for extracting and encapsulating phenolics from food waste

Patent metadata

Field	Value
Publication number	US-11958672-B2
Application number	US-202217957018-A
Country	US
Kind code	B2
Filing date	Sep 30, 2022
Priority date	Feb 22, 2019
Publication date	Apr 16, 2024
Grant date	Apr 16, 2024

Abstract

The disclosed articles, apparatus, methods, and compositions provide for the integration of different and environmentally-friendly processes for extraction, stabilization, and formulation of active compounds with health and/or other benefits from lignocellulosic by-products of food processes. The active compounds can include one or more of polyphenols, flavonoids, o-diphenols, anthocyanins, and phenolic acids. A high-pressure, high-temperature extraction process provides a means to recover a substantial portion of the active compounds from a biomass feedstock. The corresponding extract can be encapsulated, which provides a convenient form for stabilization and delivery of the active compounds into a final product, for example an active packaging material or corresponding actively packaged food item.

First claim

What is claimed is:

1. A method for extracting active compounds from a food process waste, the method comprising:
(a) providing a feed slurry comprising (i) a liquid medium comprising water and (ii) a solid food process waste dispersed in the liquid medium, the solid food process waste comprising an active compound selected from the group consisting of polyphenols, flavonoids, o-diphenols, anthocyanins, phenolic acids, and combinations thereof;
(b) subjecting the feed slurry to a temperature above 100° C. at a pressure sufficiently high to prevent boiling of the liquid medium for a time sufficient to extract the active compound from the solid food process waste and into the liquid medium; and
(c) separating solid food process waste from the liquid medium containing the active compound, thereby forming an extract comprising the liquid medium and the active compound dissolved therein, wherein the extract has a total polyphenolic recovery in a range of 0.2 wt. % to 8 wt. %, expressed on a basis of gallic acid equivalents (GAE) per dry weight of original solid food process waste.

2. The method of claim 1 , wherein the liquid medium further comprises a water-miscible organic solvent.

3. The method of claim 1 , wherein the solid food process waste comprises at least one of pomace and pits from a fruit selected from the group consisting of cherries, apples, apricots, peaches, grapes, olives, avocados, mangos, tomatoes, carrots, citrus fruits, bananas, agave, and combinations thereof.

4. The method of claim 1 , wherein the solid food process waste is in powder form having a size less than 420 μm.

5. The method of claim 1 , wherein the solid food process waste is present in the feed slurry in an amount in a range from 5 wt. % to 50 wt. %.

6. The method of claim 2 , wherein:
the solid food process waste comprises cherry pits in powder form;
the water is present in the liquid medium in an amount ranging from 30 wt. % to 70 wt. % relative to total liquid content of the liquid medium;
the water-miscible organic solvent comprises ethanol and is present in the liquid medium in an amount ranging from 30 wt. % to 70 wt. % relative to total liquid content of the liquid medium; and
the temperature in part (b) is in a range of 120° C. to 200° C.

7. A method for processing a plurality of different food process waste feedstocks, the method comprising:
providing (i) a first solid food process waste comprising a first active compound selected from the group consisting of polyphenols, flavonoids, o-diphenols, anthocyanins, phenolic acids, and combinations thereof, and (ii) a second solid food process waste different from the first solid food process waste and comprising a second active compound selected from the group consisting of polyphenols, flavonoids, o-diphenols, anthocyanins, phenolic acids, and combinations thereof, wherein the first solid food process waste and the second solid food process waste are independently selected to be different members from the group consisting of cherry pits, cherry pomace, and cherry tar;
performing a first extraction method to extract the first solid food process waste, the first extraction method comprising:
(a1) providing a first feed slurry comprising (i) a first liquid medium comprising water and (ii) the first solid food process waste dispersed in the first liquid medium,
(b1) subjecting the first feed slurry to a temperature above 100° C. at a pressure sufficiently high to prevent boiling of the first liquid medium for a time sufficient to extract the first active compound from the first solid food process waste and into the first liquid medium,
(c1) separating the first solid food process waste from the first liquid medium containing the first active compound, thereby forming (i) a first extract comprising the first liquid medium and the first active compound dissolved therein, and (ii) a first exhausted solid comprising remaining first solid food process waste after extraction;

performing a second extraction method to extract the second solid food process waste, the second extraction method comprising:
(a2) providing a second feed slurry comprising (i) a second liquid medium comprising water and (ii) the second solid food process waste dispersed in the second liquid medium,
(b2) subjecting the second feed slurry to a temperature above 100° C. at a pressure sufficiently high to prevent boiling of the second liquid medium for a time sufficient to extract the second active compound from the second solid food process waste and into the second liquid medium,
(c2) separating the second solid food process waste from the second liquid medium containing the second active compound, thereby forming (i) Op a second extract comprising the second liquid medium and the second active compound dissolved therein, and al {iv) a second exhausted solid comprising remaining second solid food process waste after extraction; and

drying and encapsulating independently each of the first extract and the second extract, thereby forming (i) a first encapsulated powder comprising a first encapsulating matrix and the first active compound within and distributed throughout the first encapsulating matrix, and (ii) a second encapsulated powder comprising a second encapsulating matrix and the second active compound within and distributed throughout the second encapsulating matrix.

8. The method of claim 7 , further comprising:
incorporating at least one of the first encapsulated powder and the second encapsulated powder into a product selected from the group consisting of an active food packaging, an antibacterial coating, a cosmetic formulation, and a functional food product.

9. The method of claim 7 , further comprising:
performing pyrolysis on at least one of the first exhausted solid and the second exhausted solid, thereby forming a biofuel.

10. The method of claim 7 , wherein:
the first liquid medium and the second liquid medium each further comprise a water-miscible organic solvent;
the first solid food process waste is present in the first feed slurry in an amount in a range from 5 wt. % to 50 wt. %;
the second solid food process waste is present in the second feed slurry in an amount in a range from 5 wt. % to 50 wt. %;
the first encapsulating matrix and the second encapsulating matrix each independently comprise an oligosaccharide selected from fructooligosaccharides (FOS), galactooligosaccharides (GOS), and combinations thereof;
the temperature in part (b1) and part (b2) is in a range of 120° C. to 250° C.;
the water is present in each of the first liquid medium and the second liquid medium in an amount independently ranging from 10 wt. % to 90 wt. % relative to total liquid content of the first liquid medium or the second liquid medium, respectively; and
the water-miscible organic solvent is present in each of the first liquid medium and the second liquid medium in an amount independently ranging from 10 wt. % to 90 wt. % relative to total liquid content of the first liquid medium or the second liquid medium, respectively.

11. A method for extracting active compounds from a food process waste, the method comprising:
(a) providing a feed slurry comprising (i) a liquid medium comprising water and ethanol and (ii) a solid food process waste dispersed in the liquid medium, wherein:
the water is present in the liquid medium in an amount ranging from 30 wt. % to 70 wt. % relative to total liquid content of the liquid medium,
the ethanol is present in the liquid medium in an amount ranging from 30 wt. % to 70 wt. % relative to total liquid content of the liquid medium,
the solid food process waste comprises (A) cherry pits in powder form, and (B) an active compound selected

Assignees

• Univ Michigan State

Inventors

• Aliakbarian Bahar
• Nejad Mojgan

Classifications

• Y02E50/10

  Biofuels, e.g. bio-diesel · CPC title

• B01D11/0211

  in combination with an electric or magnetic field · CPC title

• C09K15/08

  containing a phenol or quinone moiety · CPC title

• Y02P60/87

  Re-use of by-products of food processing for fodder production · CPC title

• B65D65/466 Primary

  Bio- or photodegradable packaging materials · CPC title