Laminate containing a metal layer and a layer of a polyamide and EVA

Patent metadata

Field	Value
Publication number	US-11958267-B2
Application number	US-201917274214-A
Country	US
Kind code	B2
Filing date	Sep 11, 2019
Priority date	Sep 14, 2018
Publication date	Apr 16, 2024
Grant date	Apr 16, 2024

Abstract

Described herein is a laminate including at least one first layer of at least one first metal and at least one further layer of a polymer composition (PC). Also described herein is a process for producing the laminate.

First claim

The invention claimed is:

1. A laminate comprising at least one first layer of at least one first metal and at least one further layer of a polymer composition (PC), wherein the polymer composition (PC) comprises the following components:
(A) at least one polyamide, and
(B) at least one copolymer obtainable by polymerizing at least the following components:
(B1) at least one C 2 -C 20 -alkene and
(B2) at least one C 2 -C 18 -alkenyl ester,

wherein component (A) is obtainable by polymerizing caprolactam and optionally at least one of the components selected from the group consisting of:
(A2) at least one C 4 -C 40 diacid, and
(A3) at least one C 4 -C 20 diamine

wherein the caprolactam is present in an amount of at least 35 wt % relative to component (A); and
wherein component (B) is not a graft polymer, wherein the polymer composition (PC) comprises in the range from 2% to 30% by weight of component (B), based on the sum total of the percentages by weight of components (A) and (B).

2. The laminate according to claim 1 , wherein the laminate further comprises at least one second layer of at least one second metal and wherein the at least one first layer is joined to the at least one second layer via the at least one further layer.

3. The laminate according to claim 1 , wherein component (B1) is selected from the group consisting of ethene, propene, 1-butene and 2-butene.

4. The laminate according to claim 1 , wherein component (B2) is selected from the group consisting of vinyl acetate, vinyl propionate and vinyl butyrate.

5. The laminate according to claim 1 , wherein component (B) is selected from the group consisting of polyethylene-vinyl acetate, polyethylene-vinyl alcohol and ethylene-vinyl acetate-vinyl alcohol copolymers.

6. The laminate according to claim 1 , wherein the polymer composition (PC) additionally comprises in the range from 1% to 30% by weight of a component (C), at least one rubber, based on the sum total of the percentages by weight of components (A), (B) and (C).

7. The laminate according to claim 1 , wherein the polymer composition (PC) further comprises at least one filler selected from the group consisting of inorganic fillers, organic fillers and natural fillers.

8. The laminate according to claim 1 , wherein the at least one first metal is selected from the group consisting of iron, aluminum, copper, nickel and magnesium and also alloys thereof.

9. The laminate according to claim 1 , wherein the at least one first layer has a thickness in the range from 0.1 mm to 0.6 mm and/or wherein the at least one further layer has a thickness in the range from 0.02 mm to 1.5 mm.

10. A process for producing a laminate according to claim 1 , comprising the steps of
a) providing a film of a polymer composition (PC) comprising the following components:
(A) at least one polyamide, and
(B) at least one copolymer prepared by polymerizing at least the following components:
(B1) at least one C 2 -C 20 -alkene and
(B2) at least one C 1 -C 18 -alkenyl ester,

b) heating a first sheet of at least one first metal,
c) pressing the heated first sheet from step b) with the film provided in step a) to obtain the laminate.

11. The process according to claim 10 , wherein step b) comprises heating the first sheet to a temperature in the range from 150° C. to 350° C.

12. The process according to claim 10 , wherein the heating of the first sheet in step b) is effected by inductive means.

13. The process according to claim 10 , wherein step a) comprises providing the film by an extrusion process.

Assignees

• Basf Se

Inventors

• Desbois Philippe
• De Oliveira Rui
• Spies Patrick
• Simon Jasmina
• Weimer Julia

Classifications

• B32B15/088 Primary

  comprising polyamides · CPC title

• B32B27/20

  using fillers, pigments, thixotroping agents · CPC title

• B32B27/34

  comprising polyamides · CPC title

• B32B37/06

  characterised by the heating method · CPC title

• B32B37/153

  at least one layer is extruded and immediately laminated while in semi-molten state · CPC title