Multicomponent plasmonic photocatalysts consisting of a plasmonic antenna and a reactive catalytic surface: the antenna-reactor effect

Patent metadata

Field	Value
Publication number	US-11958043-B2
Application number	US-201816612660-A
Country	US
Kind code	B2
Filing date	May 11, 2018
Priority date	May 12, 2017
Publication date	Apr 16, 2024
Grant date	Apr 16, 2024

Abstract

A method of making a multicomponent photocatalyst, includes inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles; collecting the co-precipitated particles; and annealing the co-precipitated particles to form the multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

First claim

What is claimed:

1. A method of making an alloyed multicomponent photocatalyst, comprising:
inducing precipitation from a pre-cursor solution comprising a pre-cursor of a plasmonic material and a pre-cursor of a reactive component to form co-precipitated particles;
collecting the co-precipitated particles; and
annealing the co-precipitated particles to form the alloyed multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material.

2. The method of claim 1 , wherein the pre-cursor solution further comprises a pre-cursor of a support material.

3. The method of claim 2 , wherein the co-precipitated particles are between 99.9% and 20% support material.

4. The method of claim 1 , wherein precipitation is induced by contacting the pre-cursor solution with a basic solution.

5. The method of claim 4 , wherein the basic solution comprises at least one of alkali metal carbonate, alkali metal bicarbonate, and alkali metal hydroxide dissolved in an aqueous solution.

6. The method of claim 1 , wherein the pre-cursor of the plasmonic material and the pre-cursor of the reactive component are transition metal salts.

7. The method of claim 1 , wherein a molar ratio of the pre-cursor of the plasmonic material to the pre-cursor of the reactive component is between 1000:1 to 10:1.

8. The method of claim 1 , wherein the annealing is performed at least partially in a reducing atmosphere.

9. The method of claim 1 , wherein the annealing is performed at a temperature between 200° C. and 1000° C.

10. A method of catalyzing a reaction, comprising:
forming an alloyed multicomponent photocatalyst pre-cursor, by a method comprising:
inducing precipitation from a pre-cursor solution comprising a pre-cursor of a support material, a pre-cursor of a plasmonic material, and a pre-cursor of a reactive component to form co-precipitated particles of the alloyed multicomponent photocatalyst pre-cursor; and
collecting the alloyed multicomponent photocatalyst pre-cursor;

loading the alloyed multicomponent photocatalyst pre-cursor into a high-temperature reaction chamber;
annealing the loaded alloyed multicomponent photocatalyst to form an alloyed multicomponent photocatalyst comprising a reactive component optically, thermally, or electronically coupled to a plasmonic material;
feeding reactants into the reaction chamber; and
illuminating the alloyed multicomponent photocatalyst in the reaction chamber with a light source having a wavelength overlapping a plasmon resonance of the plasmonic material.

11. The method of claim 10 , wherein the alloyed multicomponent photocatalyst pre-cursor is processed into a pellet or film prior to loading into the high-temperature reaction chamber.

12. The method of claim 10 , wherein the pre-cursor of the plasmonic material and the pre-cursor of the reactive component are transition metal salts.

13. The method of claim 10 , wherein the molar ratio of the pre-cursor of the plasmonic material to the pre-cursor of the reactive component is between 1000:1 to 10:1.

14. The method of claim 10 , wherein the annealing is performed at least partially in a reducing atmosphere.

15. The method of claim 10 , wherein the annealing is performed at a temperature between 200° C. and 1000° C.

16. The method of claim 10 , wherein the plasmonic material is selected from gold (Au), silver (Ag), copper (Cu), aluminum (Al), and alloys including said elements.

17. The method of claim 10 , wherein the reactive component is selected from palladium (Pd), platinum (Pt), ruthenium (Ru), rhodium (Rh), nickel (Ni), iron (Fe), cobalt (Co), iridium (Jr), osmium (Os), titanium (Ti), vanadium (V), indium (In).

18. The method of claim 10 , wherein the alloyed multicomponent photocatalyst has the reactive component alloyed at the surface of the plasmonic material.

19. The method of claim 10 , wherein the reaction is one of methane steam reforming, methane dry reforming, ammonia decomposition, nitrous oxide decomposition, reverse water gas shift, water gas shift, reduction of acetylene, ammonia synthesis, and Fisher-Tropsch synthesis.

Assignees

• Univ Rice William M

Inventors

• Halas Nancy Jean
• Nordlander Peter
• Robatjazi Hossein
• Swearer Dayne Francis
• Zhang Chao
• Zhao Hangqi
• Zhou Linan

Classifications

• B01J2235/15

  X-ray diffraction · CPC title

• B01J35/505

  with a non-spherical or unspecified core-shell structure · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J35/45

  Nanoparticles · CPC title