Viscosity modified formaldehyde-free binder compositions and methods

Patent metadata

Field	Value
Publication number	US-11952689-B2
Application number	US-202017012471-A
Country	US
Kind code	B2
Filing date	Sep 4, 2020
Priority date	Nov 13, 2012
Publication date	Apr 9, 2024
Grant date	Apr 9, 2024

Abstract

Processes of making a non-woven glass fiber mat are described. The process may include forming an aqueous dispersion of fibers. The process may also include passing the dispersion through a mat forming screen to form a wet mat. The process may further include applying a carbohydrate binder composition to the wet mat to form a binder-containing wet mat. The binder compositions may include a carbohydrate, a nitrogen-containing compound, and a thickening agent. The binder compositions may have a Brookfield viscosity of 7 to 50 centipoise at 20° C. The thickening agents may include modified celluloses such as hydroxyethyl cellulose (HEC) and carboxymethyl cellulose (CMC), and polysaccharides such as xanthan gum, guar gum, and starches. The process may include curing the binder-containing wet mat to form the non-woven glass fiber mat.

First claim

What is claimed is:

1. A process of making a non-woven glass fiber mat, the process comprising the steps of:
forming an aqueous dispersion of fibers;
passing the aqueous dispersion through a mat forming screen to form a wet mat;
applying a carbohydrate binder composition to the wet mat to form a binder-containing wet mat; and
curing the binder-containing wet mat to form the non-woven glass fiber mat,
wherein the carbohydrate binder composition comprises a carbohydrate, a nitrogen-containing compound, and a thickening agent, and wherein the carbohydrate binder composition has a Brookfield viscosity of 7 to 50 centipoise at 20° C. as measured with a Brookfield viscometer using spindle 18 at 60 rpm.

2. The process of claim 1 , wherein the step of applying the carbohydrate binder composition to the wet mat comprises curtain coating the carbohydrate binder composition on the wet mat.

3. The process of claim 1 , wherein the carbohydrate comprises a reducing sugar, and the nitrogen-containing compound is chosen from a diamine and a reaction product of a urea compound and an aldehyde-containing compound.

4. The process of claim 3 , wherein the reducing sugar is chosen from dextrose, fructose, allose, galactose, xylose, ribose, maltose, cellobiose, and lactose.

5. The process of claim 3 , wherein the diamine is chosen from ethylene diamine, 1,3-propanediamine, 1,4-butanediamine, 1,5-pentanediamine, 1,6-hexanediamine, α, α′-diaminoxylene, diethylenetriamine, triethylenetetramine, tetraethylenepentamine, and diamino benzene.

6. The process of claim 3 , wherein the reaction product of a urea compound and an aldehyde-containing compound is 4,5-dihydroxyimidazolidin-2-one.

7. The process of claim 1 , wherein the thickening agent is chosen from a modified cellulose and a polysaccharide.

8. The process of claim 7 , wherein the modified cellulose is chosen from carboxymethyl cellulose (CMC), and hydroxyethyl cellulose (HEC).

9. The process of claim 7 , wherein the polysaccharide is chosen from xanthan gum, guar gum, and starch.

10. The process of claim 1 , wherein the thickening agent has a concentration of 0.03 wt. % to 0.3 wt. % of the carbohydrate binder composition.

11. The process of claim 1 , wherein:
the carbohydrate binder composition comprises a reducing sugar, and
the nitrogen-containing compound is a reaction product of urea (H 2 N—CO—NH 2 ) and glyoxal.

12. The process of claim 11 , wherein the carbohydrate binder composition is formaldehyde-free and forms a polymerization product.

13. The process of claim 1 , wherein:
the carbohydrate comprises dextrose, and
the nitrogen-containing compound is 4,5-dihydroxyimidazolidin-2-one.

14. The process of claim 1 , wherein the carbohydrate binder composition is an aqueous solution.

15. The process of claim 1 , wherein the aqueous dispersion of fibers has a fiber concentration of 0.2 to 1.0 wt. %.

16. The process of claim 1 , wherein the aqueous dispersion of fibers has a viscosity in a range of 4 to 5 cPs.

Assignees

• Johns Manville

Inventors

• Guo Zhihua
• Lester Uranchimeg
• Asrar Jawed
• Alavi Kiarash
• Zhang Mingfu

Classifications

• D04H13/008 Primary

  Glass fibre products; Complete installations for making them · CPC title

• C08K7/14

  Glass · CPC title

• C08L3/02 Primary

  Starch; Degradation products thereof, e.g. dextrin · CPC title

• C08L61/20

  Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen (with aminophenols C08L61/04) · CPC title

• C08L61/24

  with urea or thiourea · CPC title