Polyolefin and polyvinylpyrrolidone formulation

Patent metadata

Field	Value
Publication number	US-11952503-B2
Application number	US-201916968440-A
Country	US
Kind code	B2
Filing date	Mar 11, 2019
Priority date	Mar 20, 2018
Publication date	Apr 9, 2024
Grant date	Apr 9, 2024

Abstract

A polyolefin and polyvinylpyrrolidone formulation including (A) an olefin-based (co)polymer, (B) a polyvinylpyrrolidone (co)polymer, and (C) an antioxidant. Also a method of making the composition; a crosslinked polyolefin product made by curing the composition; manufactured articles including a shaped form of the inventive formulation or product; and methods of using the inventive formulation, product, or articles.

First claim

The invention claimed is:

1. A polyolefin and polyvinylpyrrolidone formulation comprising from 79.99 to 99.94 weight percent (wt %) of (A) an olefin-based (co)polymer based on a total weight of the formulation; from 0.05 to 1.0 wt % of (B) a polyvinylpyrrolidone (co)polymer based on a total weight of the formulation; and from 0.01 to 1.5 wt % of (C) an antioxidant based on a total weight of the formulation; with the proviso that the formulation is free of an anti-static agent and a carbon black.

2. The polyolefin and polyvinylpyrrolidone formulation of claim 1 wherein the (A) olefin-based (co)polymer is (i) an ethylene-based (co)polymer, a propylene-based (co)polymer, or a combination of any two or more thereof; or (ii) a polyethylene homopolymer, an ethylene/alpha-olefin copolymer, an ethylene/unsaturated carboxylic ester copolymer, an ethylene/olefin-functional hydrolyzable silane copolymer, or a combination of any two or more thereof.

3. The polyolefin and polyvinylpyrrolidone formulation of claim 1 wherein the (B) polyvinylpyrrolidone (co)polymer is a polyvinylpyrrolidone homopolymer or a polyvinylpyrrolidone/olefin comonomer copolymer.

4. The polyolefin and polyvinylpyrrolidone formulation of claim 1 wherein the (C) antioxidant is a hindered phenol, a phosphite, a phosphonite, a thio compound, an antioxidizing amine, or a combination of any two or more thereof.

5. The polyolefin and polyvinylpyrrolidone formulation of claim 1 wherein the anti-static agent is an ethoxylated alkylamine, an ethoxylated dialkylamine, a fatty acid ester, a poly(ethylene glycol ester), a polyglycerol ester, a glycidyl ester, an alkyl sulfonate, a pentaerythritol ester, a sorbitan ester, or a diethanol amide of a carboxylic acid.

6. The polyolefin and polyvinylpyrrolidone formulation of claim 1 , further comprising at least one additive chosen from optional additives (E) to (K): (E) a stabilizer (e.g., a compound that inhibits ultraviolet (UV) light-associated degradation); (F) a scorch retardant; (G) an alkenyl-functional coagent; (H) a nucleating agent; (I) a processing aid; (J) an extender oil; and (K) nanoparticles.

7. The polyolefin and polyvinylpyrrolidone formulation of claim 1 , characterized by (i) an increase in water-tree length (WTL) of less than 10% when measured according to the Water-Tree Growth Test Method using ASTM D6097; (ii) a dissipation factor of less than 0.30%, when measured according to the Dissipation Factor Test Method; or both (i) and (ii).

8. The polyolefin and polyvinylpyrrolidone formulation of claim 1 comprising constituents (A) to (C), a (D) organic peroxide, and a (E) stabilizer, wherein the (A) olefin-based (co)polymer is a low density polyethylene containing comonomeric units derived from 1-butene, 1-hexene, or 1-octene; the (B) polyvinylpyrrolidone (co)polymer is a polyvinylpyrrolidone homopolymer having a weight-average molecular weight (Mw) from 10,000 to 40,000 grams per mole, a vinylpyrrolidone/vinyl acetate copolymer, or a polyvinylpyrrolidone-graft-(1-triacontene) copolymer; the (C) antioxidant is a hindered phenol, a thio compound, or a combination of a hindered phenol and a thio compound; and the (D) organic peroxide is dicumyl peroxide.

9. A method of making the polyolefin and polyvinylpyrrolidone formulation of claim 1 , the method comprising mixing the (B) polyvinylpyrrolidone (co)polymer and (C) antioxidant into a melt of the (A) olefin-based (co)polymer to give a melt blend comprising constituents (A), (B), and (C); optionally extruding the melt blend to give an extrudate comprising constituents (A), (B), and (C); optionally pelletizing the extrudate to give pellets comprising constituents (A), (B), and (C); and optionally adding (D) organic peroxide to the melt blend, extrudate, or pellets to give the polyolefin and polyvinylpyrrolidone formulation.

10. A crosslinked polyolefin product that is a product of curing the polyolefin and polyvinylpyrrolidone formulation of claim 1 .

11. An insulated electrical conductor comprising a conductive core and an insulation layer at least partially covering the conductive core, wherein at least a portion of the insulation layer comprises the crosslinked polyolefin product of claim 10 .

12. A method of conducting electricity, the method comprising applying a voltage across the conductive core of the insulated electrical conductor of claim 11 so as to generate a flow of electricity through the conductive core.

13. A manufactured article comprising a shaped form of the crosslinked polyolefin product of claim 10 .

Assignees

• Dow Global Technologies Llc

Inventors

• He Chao
• Sun Yabin
• Cogen Jeffrey M
• Person Timothy J
• Chen Hongyu

Classifications

• C09D123/06 Primary

  Polyethylene · CPC title

• C08L23/06

  Polyethylene · CPC title

• H01B3/44

  vinyl resins; acrylic resins (silicones H01B3/46) · CPC title

• H01B3/448

  from other vinyl compounds · CPC title

• C08L2201/08

  Stabilised against heat, light or radiation or oxydation · CPC title