Cathode active material used for lithium ion secondary battery and lithium ion secondary battery

US11949100B2 · US · B2

Patent metadata
FieldValue
Publication numberUS-11949100-B2
Application numberUS-201916978271-A
CountryUS
Kind codeB2
Filing dateMar 4, 2019
Priority dateMar 7, 2018
Publication dateApr 2, 2024
Grant dateApr 2, 2024

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  1. Title

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  2. Abstract

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  3. Assignees and inventors

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  4. Key dates

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  5. First independent claim

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  6. CPC / IPC classifications

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  7. Citations and related patents

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Abstract

Official abstract text for this publication.

The present invention is to provide a cathode active material used for a lithium ion secondary battery which has a large charge-discharge capacity, and excels in charge-discharge cycle properties, output properties and productivity, and, a lithium ion secondary battery using the same. The cathode active material used for a lithium ion secondary battery comprises a lithium transition metal composite oxide represented by the following Formula (1); Li 1+a Ni b Co c Mn d M e O 2+α , where, in the formula (1), M is at least one metal element other than Li, Ni, Co, and Mn; and a, b, c, d, e, and α satisfy the following conditions: −0.04≤a≤0.04, 0.80≤b<1.00, 0≤c≤0.04, 0<d<0.20, b+c+d+e=1, −0.2<α<0.2, and c and d in the Formula (1) satisfy c/d≤0.75.

First claim

Opening claim text (preview).

The invention claimed is: 1. A cathode active material used for a lithium ion secondary battery comprising: a lithium transition metal composite oxide represented by the following Formula (1): Li 1+a Ni b Co c Mn d MeO 2+α   (1) where M contains at least one kind of metal elements selected from a group consisting of Al, Ti, Zn, Ga, Zr, Mo, Nb, V, Sn, Mg, Ta, Ba, W and Y; a, b, c, d, e, and a are respectively numbers satisfying the following conditions: −0.04≤a≤0.04, 0.80≤b<1.00, 0.01≤c≤0.04, 0<d<0.20, b+c+d+e=1, −0.2<α<0.2, wherein c and d in the Formula (1) satisfy 0<c/d≤0.75. 2. The cathode active material used for a lithium ion secondary battery according to the claim 1 , wherein the lithium transition metal composite oxide represented by the Formula (1) has an α-NaFeO 2 type crystal structure, and a site occupancy of nickel at a 3a site in a crystal structure belonging to a space group R-3m is less than 4%. 3. The cathode active material used for a lithium ion secondary battery according to the claim 1 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein I (003) and I (104) are defined as an integrated intensity of a diffraction peak assigned to planes (003) and (104) respectively, and a value of I (003) /I (104) is 1.2 or more. 4. The cathode active material used for a lithium ion secondary battery according to the claim 1 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein a full width at half maximum of a diffraction peak assigned to a plane (003) is 0.130° or smaller. 5. The cathode active material used for a lithium ion secondary battery according to the claim 1 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 6. The cathode active material used for a lithium ion secondary battery according to the claim 1 having a specific surface area of 0.2 m 2 /g or more and 1.5 m 2 /g or less. 7. A lithium ion secondary battery comprising a cathode comprising the cathode active material used for a lithium ion secondary battery according to the claim 1 . 8. The cathode active material used for a lithium ion secondary battery according to the claim 2 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein I (003) and I (104) are defined as an integrated intensity of a diffraction peak assigned to planes (003) and (104) respectively, and a value of I (003) /I (104) is 1.2 or more. 9. The cathode active material used for a lithium ion secondary battery according to the claim 2 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein a full width at half maximum of a diffraction peak assigned to a plane (003) is 0.130° or smaller. 10. The cathode active material used for a lithium ion secondary battery according to the claim 3 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein a full width at half maximum of a diffraction peak assigned to a plane (003) is 0.130° or smaller. 11. The cathode active material used for a lithium ion secondary battery according to the claim 8 , having an X-ray powder diffraction spectrum obtained using a CuKα radiation, wherein a full width at half maximum of a diffraction peak assigned to a plane (003) is 0.130° or smaller. 12. The cathode active material used for a lithium ion secondary battery according to the claim 2 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 13. The cathode active material used for a lithium ion secondary battery according to the claim 3 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 14. The cathode active material used for a lithium ion secondary battery according to the claim 8 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 15. The cathode active material used for a lithium ion secondary battery according to the claim 9 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 16. The cathode active material used for a lithium ion secondary battery according to the claim 10 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 17. The cathode active material used for a lithium ion secondary battery according to the claim 11 , wherein an a-axis lattice constant of a unit lattice is 2.878×10 −10 m or more. 18. The cathode active material used for a lithium ion secondary battery according to the claim 1 , wherein M is Ti.

Assignees

Inventors

Classifications

  • H01M4/505Primary

    of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy · CPC title

  • C01G53/50Primary

    of the type (MnO2)n-, e.g. Li(NixMn1-x)O2 or Li(MyNixMn1-x-y)O2 · CPC title

  • H01M4/525Primary

    of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy · CPC title

  • Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries · CPC title

  • containing elements as dopants · CPC title

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What does patent US11949100B2 cover?
The present invention is to provide a cathode active material used for a lithium ion secondary battery which has a large charge-discharge capacity, and excels in charge-discharge cycle properties, output properties and productivity, and, a lithium ion secondary battery using the same. The cathode active material used for a lithium ion secondary battery comprises a lithium transition metal compo…
Who is the assignee on this patent?
Proterial Ltd
What technology area does this patent fall under?
Primary CPC classification H01M4/505. Mapped technology areas include Electricity.
When was this patent published?
Publication date Tue Apr 02 2024 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
What related patents are in patentsdb?
We list 7 related publications on this page (citations in our corpus or others sharing the same primary CPC).