Energy-storing temperature control material and preparation method and application thereof

Patent metadata

Field	Value
Publication number	US-11946246-B2
Application number	US-202217883856-A
Country	US
Kind code	B2
Filing date	Aug 9, 2022
Priority date	Sep 25, 2020
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

The present invention provides an energy-storing temperature control material, and belongs to the technical field of temperature control materials. In the energy-storing temperature control material provided in the present invention, the organic synthetic fiber based phase-change material has a three-dimensional dispersion effect, and can form a network constraint for remaining phase-change materials to reinforce mechanical properties of the materials, thereby fixing shapes of the materials and avoiding a liquid-crystal phase separation phenomenon in the phase-change process. The phase-change energy storage agent can absorb and release the heat by means of solid-liquid phase conversion of the material, to achieve the temperature control effect; and the phase-change temperature regulator can regulate a phase-change temperature range of the phase-change material, to make the energy-storing temperature control material suitable for climatic features of northern China.

First claim

What is claimed is:

1. An energy-storing temperature control material, comprising the following components by mass percentage:
2-10% of organic synthetic fiber based phase-change material,
20-70% of phase-change energy storage agent,
3-10% of phase-change temperature regulator,
3-7% of nucleating agent,
1-5% of thickening stabilizer,
0.1-1% of preservative, and
the balance being water, wherein
the organic synthetic fiber based phase-change material comprises one or more of a bacterial cellulose fiber, a rayon fiber, a carboxymethyl cellulose fiber, a cellulose acetate fiber, a polypropylene fiber, a polyacrylate fiber, a polyacrylamide fiber and a polyol ester fiber; and the organic synthetic fiber based phase-change material has a diameter of 10-25 μm and a length of 5 mm, a particle size of the nucleating agent is from 10 nm to 800 nm; the organic synthetic fiber based phase-change material is composed of porous fibers to load the nucleating agent so that the nucleating agent is uniformly distributed in the organic synthetic fiber based phase-change material;
the nucleating agent is one or more of nano-calcium carbonate, nano-carbon particles, nano-magnesium silicate, nano-calcium oxide, nano-magnesium oxide, nano-cellulose and nano-lignin; and
the energy-storing temperature control material has a phase-change point of 18-40° C., a thermal conductivity of 0.1-0.9 W·m −1 ·K −1 , and a specific heat capacity of 1000-3000 J·kg −1 ·K −1.

2. The energy-storing temperature control material according to claim 1 , comprising the following components by mass percentage:
3-6% of organic synthetic fiber based phase-change material,
35-55% of phase-change energy storage agent,
4-7% of phase-change temperature regulator,
4-6% of nucleating agent,
1-2% of thickening stabilizer,
0.3-0.8% of preservative, and
the balance being water.

3. The energy-storing temperature control material according to claim 1 , wherein the phase-change energy storage agent comprises one or more of borax, sodium silicate decahydrate, ferrous sulfate heptahydrate, potassium aluminum sulfate dodecahydrate, magnesium chloride hexahydrate, zinc sulfate heptahydrate, copper sulfate pentahydrate, barium hydroxide octahydrate, calcium sulfate dihydrate and calcium disulfate monohydrate;
the phase-change temperature regulator is one or more of ammonium chloride, sodium chloride, potassium chloride and calcium chloride;
the thickening stabilizer is one or more of starch, dextrin, a polysaccharide derivative, carboxymethyl cellulose, polyvinylpyrrolidone, polyvinyl alcohol and a polyethylene oxide-polypropylene oxide block copolymer; and
the preservative is one or more of calcium hypochlorite, sodium benzoate, potassium sorbate, calcium sorbate, paraben, chloramine, copper sulfate, methylene dithiocyanate, isothiazolinone and a phenol compound.

4. A preparation method of the energy-storing temperature control material according to claim 1 , comprising the following steps:
(1) providing a thickening stabilizer aqueous solution; and
(2) mixing the thickening stabilizer aqueous solution with an organic synthetic fiber based phase-change material, a phase-change energy storage agent, a phase-change temperature regulator, a preservative and a nucleating agent, and performing heating and stirring to obtain the energy-storing temperature control material.

5. The preparation method according to claim 4 , wherein a mass concentration of the thickening stabilizer aqueous solution is 1-8%.

6. The preparation method according to claim 4 , wherein a temperature for the heating and stirring is 20-60° C., a rate is 100-800 rpm and time is 2-12 h.

7. A metal foil wrapped energy-storing temperature control board, comprising:
gypsum boards;
energy-storing temperature control material packaged and adhered between two layers of the gypsum boards to form an energy-storing temperature control board, and the energy-storing temperature control board is wrapped with metal foil; wherein when used as a building insulation layer, the wrapped energy-storing temperature control board is embedded between a brick layer and a gypsum layer of a wall of a building;
wherein the energy-storing temperature control material comprising:
2-10% of organic synthetic fiber based phase-change material,
20-70% of phase-change energy storage agent,
3-10% of phase-change temperature regulator,
3-7% of nucleating agent,
1-5% of thickening stabilizer,
0.1-1% of preservative, and
the balance being water, wherein
the organic synthetic fiber based phase-change material comprises one or more of a bacterial cellulose fiber, a rayon fiber, a carboxymethyl cellulose fiber, a cellulose acetate fiber, a polypropylene fiber, a polyacrylate fiber, a polyacrylamide fiber and a polyol ester fiber; and the organic synthetic fiber based phase-change material has a diameter of 10-25 μm and a length of 5 mm, a particle size of the nucleating agent is from 10 nm to 800 nm; the organic synthetic fiber based phase-change material is composed of porous fibers to load the nucleating agent so that the nucleating agent is uniformly distributed in the organic synthetic fiber based phase-change material; and
the nucleating agent is one or more of nano-calcium carbonate, nano-carbon particles, nano-magnesium silicate, nano-calcium oxide, nano-magnesium oxide, nano-cellulose and nano-lignin; and
the energy-storing temperature control material has a phase-change point of 18-40° C., a thermal conductivity of 0.1-0.9 W·m −1 ·K −1 , and a specific heat capacity of 1000-3000 J·kg −1 ·K −1.

Assignees

• Univ Qilu Technology

Inventors

• Qi Letian
• Wang Shoujuan
• Meng Xia
• Kong Fangong
• Zhao Ruhe
• Han Chen
• Li Debao

Classifications

• E04B1/80 Primary

  slab-shaped · CPC title

• C09K5/063 Primary

  Materials absorbing or liberating heat during crystallisation; Heat storage materials · CPC title

• E04B1/76 Primary

  specifically with respect to heat only (heat insulation in general F16L59/00) · CPC title

• E04B1/7608

  comprising a prefabricated insulating layer, disposed between two other layers or panels · CPC title

• E04C2/288

  composed of insulating material and concrete, stone or stone-like material · CPC title