System and method for producing needle coke

Patent metadata

Field	Value
Publication number	US-11946003-B2
Application number	US-202017758262-A
Country	US
Kind code	B2
Filing date	Dec 3, 2020
Priority date	Dec 31, 2019
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

A system for producing needle coke and a method for producing needle coke using the system are provided. The system includes a coke tower, a pressure stabilization tower, a buffer tank and a coking fractionation tower. A pressure controller is provided at the top of the pressure stabilization tower for adjusting the pressure at the top thereof. An oil gas outlet of the coke tower is in communication with an oil gas inlet of the pressure stabilization tower through a pipeline. No pressure controller for adjusting the pressure at the top of the coke tower is provided in the coke tower or on the oil gas pipeline connecting the coke tower to the pressure stabilization tower.

First claim

The invention claimed is:

1. A system for producing needle coke, comprising:
a coke tower provided with a feedstock inlet and an oil gas outlet, wherein a hydrocarbon-containing feedstock is reacted to produce the needle coke and an oil gas in the coke tower;
a pressure stabilization tower provided with an oil gas inlet, an overhead light fraction outlet, a bottom oil outlet and a cycle oil inlet, wherein the oil gas from the coke tower is received and separated into an overhead light fraction and a bottom oil, and a pressure controller is provided at a top of the pressure stabilization tower for adjusting the pressure at the top of the pressure stabilization tower;
a buffer tank provided with an inlet, a first bottom oil outlet, and a second bottom oil outlet, for receiving the bottom oil from the pressure stabilization tower; and
a coking fractionation tower provided with an inlet, a light oil outlet and a heavy oil outlet, wherein a bottom oil from the buffer tank is received and separated into a light oil and a heavy oil;
wherein the oil gas outlet of the coke tower is in communication with the oil gas inlet of the pressure stabilization tower through a pipeline, and no pressure controller for adjusting the pressure at the top of the coke tower is provided in the coke tower or on the oil gas pipeline connecting the coke tower to the pressure stabilization tower,
the inlet of the buffer tank is in communication with the bottom oil outlet of the pressure stabilization tower, the first bottom oil outlet of the buffer tank is in communication with the cycle oil inlet of the pressure stabilization tower through a pipeline with a temperature adjuster provided thereon, and the second bottom oil outlet of the buffer tank is in communication with the inlet of the coking fractionation tower, and
optionally, the heavy oil outlet of the coking fractionation tower is in communication with the feedstock inlet of the coke tower.

2. The system for producing needle coke according to claim 1 , wherein the pressure controller at the top of the pressure stabilization tower can be used to adjust the pressure at the top of the pressure stabilization tower by regulating the flow rate of the light fraction discharged at the top of the pressure stabilization tower, and in turn maintain the pressure at the top of the coke tower at a set value.

3. The system for producing needle coke according to claim 1 , further comprising at least one additional coke towers, wherein at least one coke tower in the system is in a reaction stage and at least one coke tower in the system is in a decoking stage.

4. The system for producing needle coke according to claim 1 , further comprising a furnace for heating the hydrocarbon-containing feedstock to be fed to the coke tower.

5. The system for producing needle coke according to claim 1 , further comprising a hydrogenation reactor for hydrotreating a hydrocarbon-containing initial feedstock to obtain the hydrocarbon-containing feedstock to be fed to the coke tower.

6. A method for producing needle coke using the system according to claim 1 , comprising the steps of:
(1) reacting a heated hydrocarbon-containing feedstock in the coke tower to obtain the needle coke and the oil gas;
(2) separating the oil gas from the coke tower in the pressure stabilization tower to obtain the overhead light fraction and the bottom oil;
(3) sending the bottom oil from the pressure stabilization tower to the buffer tank, and withdrawing a first stream of bottom oil and a second stream of bottom oil from the buffer tank;
(4) returning the first stream of bottom oil from the buffer tank to the pressure stabilization tower after a temperature adjustment;
(5) sending the second stream of bottom oil from the buffer tank to the coking fractionation tower, separating the stream into the light oil and the heavy oil therein, and optionally returning the heavy oil to the coke tower for further reaction,
wherein the pressure at the top of the pressure stabilization tower is adjusted by the pressure controller at the top of the pressure stabilization tower, so that the pressure at the top of the coke tower is maintained at a set value.

7. The method according to claim 6 , further comprising, prior to step (1), performing a solid removal treatment on a hydrocarbon-containing initial feedstock, wherein the solid removal treatment is selected from filtration, centrifugal sedimentation, vacuum distillation, solvent extraction, and combinations thereof; and
a step of hydrotreating the hydrocarbon-containing initial feedstock to obtain the hydrocarbon-containing feedstock,
wherein the hydrocarbon-containing initial feedstock is selected from the group consisting of catalytic cracking slurry oils, catalytic cracking decant oils, ethylene tars, thermal cracking residues, coal tars, coal tar pitches, and combinations thereof.

8. The method according to claim 7 , wherein the hydrotreating step has a reaction temperature of about 300-480° C., a reaction pressure of about 3-20 MPa, a hydrogen-to-oil volume ratio of about 100-2500, and a liquid hourly space velocity of about 0.1-2.0 h −1 .

9. The method according to claim 7 , wherein the reaction conditions of the hydrotreating step include: a reaction temperature of about 330-400° C., a reaction pressure of about 5-10 MPa, a hydrogen-to-oil volume ratio of about 500-1500, and a liquid hourly space velocity of about 0.5-1.0 h −1 .

10. The method according to claim 6 , wherein the heated hydrocarbon-containing feedstock of step (1) has a temperature of about 400-550° C., and the hydrocarbon-containing feedstock is heated at a rate of about 1-50° C./h, the pressure at the top of the coke tower is about 0.01-2.5 MPa, and the reaction duration is about 10-50 h.

11. The method according to claim 6 , wherein the heated hydrocarbon-containing feedstock of step (1) has a temperature of about 440-520° C., and the hydrocarbon-containing feedstock is heated at a rate of about 2-10° C./h; the pressure at the top of the coke tower is about 0.2-1.5 MPa, and the reaction duration is about 30-50 h.

12. The method according to claim 6 , wherein the overhead light fraction of step (2) comprises a non-condensable gas and a distillate oil, the 95% distillate temperature of the distillate oil is controlled to be about 150-430° C.,
a liquid level of the pressure stabilization tower is controlled to be about 10-80% of the total height of the tower in step (2).

13. The method according to claim 12 , wherein the 95% distillate temperature of the distillate oil is controlled to be about 230-370° C.

14. The method according to claim 12 , wherein the 95% distillate temperature of the distillate oil is controlled to be about 230-330° C.

15. The method according to claim 12 , wherein:
when the liquid level of the pressure stabilization tower is increased to 60% or more of the total height of the tower and the 95% distillate temperature of the distillate oil is increased to 310° C. or higher, the temperature at which the first stream of bottom oil is returned to the pressure stabilization tower is lowered and the discharge rate of the bottom oil from the pressure stabilization tower is raised;
when the liquid level at the bottom of the pressure stabilization tower is increased to 60% or more of the total height of the tower and the 95% distillate temperature of the distillate oil is decreased to 240° C. or lower, both the temperature at which the first stream of bottom oil is returned to the pressure stabilization tower and the discharge rate of the bottom oil from the pressure stabilization tower are raised;
when the l

Assignees

• China Petroleum & Chem Corp
• Sinopec Dalian Res Inst Petroleum & Petrochemicals Co Ltd

Inventors

• Guo Dan
• Fang Xiangchen
• Qiao Kai
• Chu Renqing
• Gou Lianzhong
• Chen Tianzuo

Classifications

• C10G69/06 Primary

  including at least one step of thermal cracking in the absence of hydrogen · CPC title

• C10B41/00

  Safety devices, e.g. signalling or controlling devices for use in the discharge of coke · CPC title

• C10B55/00

  Coking mineral oils, bitumen, tar, and the like or mixtures thereof with solid carbonaceous material (cracking oils C10G) · CPC title

• C10G9/005 Primary

  Coking (in order to produce liquid products mainly) · CPC title

• C10G2300/4012

  Pressure · CPC title