Aqueous composition and a method of producing durable and extremely efficient water repelling superhydrophobic materials at ambient condition thereof

Patent metadata

Field	Value
Publication number	US-11945957-B2
Application number	US-202217667196-A
Country	US
Kind code	B2
Filing date	Feb 8, 2022
Priority date	Oct 17, 2017
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

The present invention relates to a durable and multifunctional superhydrophobic coating composition and water based fabrication method of producing the durable and multifunctional superhydrophobic coating composition via chemical modification and functionalization of hydrophilic material by silanes under room temperature without any organic solvents. Synthesis of chemically modified cellulose nanofibers or clay in water forms excellent water repelling thin films upon coating over various substrates. The super hydrophobic materials are used as additive for paints, pigments, paper, varnish and, textile and used for various industrial applications such as construction of buildings and other super structures.

First claim

We claim:

1. A water based fabrication method of forming an amino silane functionalized superhydrophobic coating composition wherein said method includes chemical modification and functionalization of cellulose nanofiber by a wet chemical process in an aqueous medium free of any organic solvent, said method comprising the steps of:
a. dispersing a hydrophilic cellulose nanofiber in an aqueous medium to obtain a dispersed hydrophilic cellulose nanofiber in an aqueous medium,
b. mixing the dispersed hydrophilic cellulose nanofiber in an aqueous medium with 1H,1H,2H,2H-perfluorooctyltriethoxysilane and 3-(2-aminoethylamino)propyltrimethoxysilane, and
c. Vigorous stirring for 6-7 hours,
wherein the steps are performed under room temperature and ambient conditions.

2. The method as claimed in claim 1 , wherein the amino silane functionalized superhydrophobic coating composition adsorbs moisture and CO, from air at room temperature.

3. The method as claimed in claim 1 , wherein the superhydrophobic coating composition provides water repelling properties such that water is forced to sit as a droplets having contact angle greater than 160° and roll-off angle less than 10°.

4. The method as claimed in claim 1 , whereby the superhydrophobic coating composition may be coated on a substrate by multiple methods including spray coating, doctor blading, dip coating, and spin coating.

5. The method as claimed in claim 1 , wherein the superhydrophobic coating composition can be coated over flat and different curved surfaces.

6. The method as claimed in claim 1 , wherein the superhydrophobic coating composition can be coated over a range of soft substrates and hard substrates.

7. The method as claimed in claim 1 , wherein the superhydrophobic coating composition is used as an additives for paint, pigments, paper, varnish and, textiles and used in construction.

8. The method as claimed in claim 1 , wherein the superhydrophobic coating composition is inert to organic solvents and oils.

9. The method as claimed in claim 6 , wherein the superhydrophobic coating composition does not change the flexibility of the substrate.

10. The method as claimed in claim 6 wherein the soft substrates include paper and cotton substrates and the hard substrates include metal, wood and plastic substrates.

Assignees

• Indian Institute Of Tech Madras
• Indian Inst Tech Madras

Inventors

• Thalappil Pradeep
• Baidya Avijit
• Ganayee Mohd Azhardin
• Ravindran Swathy Jakka

Classifications

• C09D101/02 Primary

  Cellulose; Modified cellulose · CPC title

• C08B15/05 Primary

  Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur (esters or phosphorous acids C08B5/00) · CPC title

• C08B15/06

  containing nitrogen {, e.g. carbamates} · CPC title

• C09D5/1681

  Antifouling coatings characterised by surface structure, e.g. for roughness effect giving superhydrophobic coatings or Lotus effect · CPC title

• C09D7/61

  inorganic · CPC title