Algae cultivation systems and methods related thereto

Patent metadata

Field	Value
Publication number	US-11945736-B2
Application number	US-202117168112-A
Country	US
Kind code	B2
Filing date	Feb 4, 2021
Priority date	May 1, 2020
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

The present disclosure relates to methods and systems for algae cultivation including the integration of electrochemical carbonate production for enhancing algae growth. More particularly, the present disclosure relates to methods and systems for producing a sodium hydroxide from brine using an electrochemical cell, contacting the sodium hydroxide stream with a CO 2 gas sweep and producing a carbonate stream, and cultivating an algae slurry in a cultivation vessel comprising at least a portion of the carbonate stream.

First claim

What is claimed is:

1. An integrated system comprising:
an electrochemical cell to produce a sodium hydroxide stream from a brine stream that is recycled brine wastewater from a cultivation vessel, wherein the recycled brine wastewater includes sodium hydroxide;
a first conduit to convey at least a portion of the sodium hydroxide stream from the electrochemical cell;
a CO 2 gas sweep in fluid communication with the first conduit to receive the sodium hydroxide stream and contact the sodium hydroxide stream with CO 2 gas to produce a carbonate stream;
a second conduit to convey at least a portion of the carbonate stream from the CO 2 gas sweep; and
the cultivation vessel in fluid communication with the second conduit to receive the carbonate stream and to contain an algae slurry for cultivation.

2. The system of claim 1 , further comprising a brine conduit in fluid communication with the cultivation vessel and the electrochemical cell to convey the brine wastewater from the cultivation vessel to the electrochemical cell.

3. The system of claim 1 , wherein the carbonate stream comprises one or more of a carbonate ion, a carbonate salt, a bicarbonate ion, and a bicarbonate salt.

4. The system of claim 1 , wherein the carbonate stream comprises sodium bicarbonate.

5. The system of claim 1 , wherein the cultivation vessel is a closed cultivation vessel or an open cultivation vessel.

6. An integrated system comprising:
an electrochemical cell to produce a sodium hydroxide stream from a brine stream that is recycled brine wastewater from a cultivation vessel, wherein the recycled brine wastewater includes sodium hydroxide;
a first conduit to convey at least a portion of the sodium hydroxide stream from the electrochemical cell;
a second conduit to convey at least a portion of the recycled brine wastewater to the cultivation vessel;
a closed cultivation vessel in fluid communication with the first conduit to receive the sodium hydroxide stream, the second conduit to receive the at least a portion of the recycled brine wastewater, and to contain an algae slurry for cultivation; and
a CO 2 gas sweep to contact the sodium hydroxide stream received by the cultivation vessel to produce a carbonate stream.

7. The system of claim 6 , further comprising a brine conduit in fluid communication with the cultivation vessel and the electrochemical cell to convey the brine wastewater from the cultivation vessel to the electrochemical cell.

8. The system of claim 6 , wherein the carbonate stream comprises one or more of a carbonate ion, a carbonate salt, a bicarbonate ion, and a bicarbonate salt.

9. The system of claim 6 , wherein the carbonate stream comprises sodium bicarbonate.

10. The system of claim 6 , wherein the cultivation vessel is a closed cultivation vessel or an open cultivation vessel.

11. A method comprising:
producing a sodium hydroxide from brine using an electrochemical cell;
contacting the sodium hydroxide stream with a CO 2 gas sweep and producing a carbonate stream; and

cultivating an algae slurry in a cultivation vessel comprising at least a portion of the carbonate stream.

12. The method of claim 11 , wherein the brine stream is brine wastewater from the cultivation vessel, and further comprising conveying the brine wastewater to the electrochemical cell from the cultivation vessel.

13. The method of claim 11 , wherein the carbonate stream comprises one or more of a carbonate ion, a carbonate salt, a bicarbonate ion, and a bicarbonate salt.

14. The method of claim 11 , wherein the carbonate stream comprises sodium bicarbonate.

15. The method of claim 11 , wherein the cultivation vessel is a closed cultivation vessel or an open cultivation vessel.

16. The method of claim 11 , further comprising harvesting algae from the algae slurry.

17. The method of claim 16 , further comprising processing the harvested algae to produce biofuel.

18. The method of claim 11 , wherein a chlorine byproduct stream and a molecular hydrogen byproduct stream is produced from the producing the sodium hydroxide from brine using an electrochemical cell, and further comprising producing hydrochloric acid from the chlorine byproduct stream and the molecular hydrogen byproduct stream.

19. The method of claim 18 , further comprising introducing the hydrochloric acid to the algae slurry in the cultivation vessel comprising at least a portion of the carbonate stream to control pH.

Assignees

• Exxonmobil Technology & Engineering Company

Inventors

• Johnson Gregory R
• O'Neal Everett J
• Feicht Sarah E

Classifications

• B01D61/423

  comprising multiple electrodialysis steps · CPC title

• B01D61/461

  comprising only a single cell, only one anion or cation exchange membrane or one pair of anion and cation membranes · CPC title

• C02F1/46109 Primary

  Electrodes · CPC title

• B01D53/326

  in electrochemical cells · CPC title

• B01D2257/504

  Carbon dioxide · CPC title