Method for producing foamed flat moldings and mold for carrying out said method

Patent metadata

Field	Value
Publication number	US-11945141-B2
Application number	US-202117608233-A
Country	US
Kind code	B2
Filing date	Jan 11, 2021
Priority date	Jan 17, 2020
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

The invention relates to a method for the production of foamed areal polyurethane(PUR)/polyisocyanurate(PIR) moldings, where a polyurethane/polyisocyanurate reaction mixture is injected into a mold that is under elevated pressure and then a depressurization takes place, and the foaming process is thus induced, and after the reaction the molding is demolded, and to a mold for carrying out the method.

First claim

What is claimed is:

1. A method for producing a production of foamed areal polyurethane/polyisocyanurate molding with a thickness (LF2) in a mold ( 10 ), comprising an inlet region, a cavity ( 100 ) and a depressurization unit ( 300 ), the method comprising:
i) injecting a polyurethane/polyisocyanurate reaction mixture through at least one inlet aperture ( 110 , 210 ) in the inlet region and into the cavity ( 100 ) of the mold ( 10 ), said cavity being under an initial pressure of 5 bar to 40 bar,
ii) after the injection of the polyurethane/polyisocyanurate reaction mixture, carrying out a depressurization in the cavity ( 100 ) for 0.1 to 10 seconds by means of at least one valve ( 310 ) in the depressurization unit ( 300 ), to atmospheric pressure or to a pressure which is lower than the initial pressure and which is 1 bar to 5 bar, wherein the polyurethane/polyisocyanurate reaction mixture foams along a main flow direction from the inlet region through the cavity ( 100 ) to the depressurization unit ( 300 ), and
iii) hardening, cooling and demolding the foamed areal polyurethane/polyisocyanurate molding, wherein
the cavity has two long dimensions (LF1 and LF3) and one dimension (LF2) that is short in comparison therewith, and one of the long dimensions (LF3) represents the main flow direction of the foam,
the cavity ( 100 ) has at least one wall (A3) in the plane which contains the dimensions (LF1) and (LF2), or has at least one portion (K2) of a wall (A2) in a plane which contains the dimensions (LF1) and (LF3), where the at least one portion (K2) of the wall (A2) corresponds to the area which extends in the dimension (LF3) across that one-tenth part of the wall (A2) that is opposite to the inlet region, and where the at least one wall (A3) or at least one portion (K2) of a wall (A2) has at least one aperture ( 340 ) which connects the cavity ( 100 ) and the depressurization unit ( 300 ),
the ratio of the sum of the areas of the at least one aperture ( 340 ) to the area of the wall (A3) comprising said aperture or of the at least one portion (K2) of the wall (A2), where said at least one portion (K2) comprises said aperture, is 1:20 to 1:100,
the at least one aperture ( 340 ) has a length (LS1) in the direction of the long dimension (LF1) of the cavity ( 100 ), and
the ratio of the length (LS1) or, respectively, of the sum of the length (LS1) of the at least one aperture ( 340 ) to the long dimension (LF1) of the cavity ( 100 ) is greater than 1:4.

2. The method as claimed in claim 1 , where the ratio of the long dimension (LF1) of the cavity ( 100 ) to the short dimension (LF2), and also the ratio of the long dimension (LF3) of the cavity ( 100 ) to the short dimension (LF2) is respectively mutually independently greater than 3:1.

3. The method as claimed in claim 1 , where the at least one aperture ( 340 ) connecting the cavity ( 100 ) to the depressurization unit ( 300 ) has an aspect ratio of at least 2.

4. A mold for the production of foamed areal polyurethane/polyisocyanurate moldings with a thickness (LF2), comprising:
(i) an inlet region with at least one inlet aperture ( 110 , 210 ),
(ii) a cavity ( 100 ) adjacent to the inlet region, and
(iii) a depressurization unit ( 300 ) with at least one valve ( 130 , 310 ), wherein
the cavity ( 100 ) has two long dimensions (LF1) and (LF3) and one dimension (LF2) that is short in comparison thereto,
the cavity ( 100 ) has at least one wall (A3) in a plane which contains the dimensions (LF1) and (LF2), or has at least one portion (K2) of a wall (A2) in the plane which contains the dimensions (LF1) and (LF3), where the at least one portion (K2) of the wall (A2) corresponds to the area which extends in the dimension (LF3) across that one-tenth part of the wall (A2) that is opposite to the inlet region, and where the at least one wall (A3) or at least one portion (K2) of a wall (A2) has at least one aperture ( 340 ) which connects the cavity ( 100 ) and the depressurization unit ( 300 ),
the ratio of the sum of the areas of the at least one aperture ( 340 ) to the area of the wall (A3) comprising said aperture or of the at least one portion (K2) of the wall (A2), where said at least one portion (K2) comprises said aperture, is 1:20 to 1:100,
the at least one aperture ( 340 ) has a length (LS1) in the direction of the long dimension (LF1) of the cavity ( 100 ), and
the ratio of the length (LS1) or, respectively, of the sum of the length (LS1) of the at least one aperture ( 340 ) to the long dimension (LF1) of the cavity ( 100 ) is greater than 1:4.

5. The mold as claimed in claim 4 , where the ratio of the long dimension (LF1) of the cavity to the short dimension (LF2), and also the ratio of the long dimension (LF3) of the cavity to the short dimension (LF2) is respectively mutually independently greater than 3:1.

6. The mold as claimed in claim 4 , wherein the at least one aperture ( 340 ) connecting the cavity ( 100 ) to the depressurization unit ( 300 ) has an aspect ratio of at least 2.

Assignees

• Covestro Deutschland Ag

Inventors

• Hopf Stefan
• Moers Stephan
• Wick Achim
• Windeck Christian

Classifications

• B29C44/428 Primary

  Mould constructions; Mould supporting equipment · CPC title

• B29C44/04

  consisting of at least two parts of chemically or physically different materials, e.g. having different densities · CPC title

• B29C44/588 Primary

  with means for venting, e.g. releasing foaming gas · CPC title

• B29K2075/00

  Use of {PU, i.e.} polyureas or polyurethanes {or derivatives thereof}, as moulding material · CPC title

• B29C44/58 Primary

  Moulds · CPC title