Tunable, rapid uptake, aminopolymer aerogel sorbent for direct air capture of co2
US-2021370226-A1 · Dec 2, 2021 · US
US11944933B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11944933-B2 |
| Application number | US-202218069549-A |
| Country | US |
| Kind code | B2 |
| Filing date | Dec 21, 2022 |
| Priority date | May 28, 2020 |
| Publication date | Apr 2, 2024 |
| Grant date | Apr 2, 2024 |
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A primary amine polymer aerogel comprising greater than 5 wt. % of primary amine monomers covalently bound to cross-linking monomers, wherein the primary amine monomers are selected from vinyl amine. A secondary amine polymer aerogel comprising secondary amine monomers covalently bound to cross-linking monomers, the secondary amine monomers being a result of substituting a hydrogen atom from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers. A tertiary amine polymer aerogel comprising tertiary amine monomers covalently bound to cross-linking monomers, the tertiary amine monomers being a result of substituting hydrogen atoms from a primary amine polymer aerogel, the primary amine polymer aerogel comprising vinyl amine monomers covalently bound to the cross-linking monomers.
Opening claim text (preview).
What is claimed is: 1. A primary amine polymer aerogel comprising greater than 5 wt. % of primary amine monomers covalently bound to cross-linking monomers, wherein the primary amine monomers are selected from vinyl amine. 2. The primary amine polymer aerogel of claim 1 , wherein the cross-linking monomers are selected from divinylbenzene. 3. The primary amine polymer aerogel of claim 1 , wherein the cross-linking monomers are selected from the group consisting of: trimethylolpropane triacrylate, trimethylolpropane ethoxylate triacrylate, di(trimethylolpropane) tetraacrylate, dipentaerythritol penta-/hexa-acrylatetrimethacryl adamantane, dipentaerithritol, trimethylolpropane trimethacrylate, phenylene dimethacrylate, phenylene diacrylate, and 1,6-hexanediol diacrylate. 4. The primary amine polymer aerogel of claim 1 , wherein the primary amine polymer aerogel adsorbs greater than 1 millimole carbon dioxide per gram of primary amine polymer aerogel at temperatures greater than 0° C. and carbon dioxide concentrations less than 1000 parts per million. 5. The primary amine polymer aerogel of claim 1 , wherein the primary amine polymer aerogel adsorbs greater than 1 millimole carbon dioxide per gram of primary amine polymer aerogel at temperatures greater than 20° C. and carbon dioxide concentrations less than 500 parts per million. 6. The primary amine polymer aerogel of claim 1 , the primary amine polymer aerogel having a porosity greater than 10%. 7. The primary amine polymer aerogel of claim 1 , the primary amine polymer aerogel comprising greater than 10 wt. % of primary amine monomers. 8. The primary amine polymer aerogel of claim 1 , the primary amine polymer aerogel further comprising carbon dioxide adsorbed to the vinyl amine monomers.
by absorption · CPC title
containing an organic phase · CPC title
Preparation of aerogels, e.g. xerogels · CPC title
derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers · CPC title
Crosslinking, e.g. vulcanising, of macromolecules (mechanical aspects B29C35/00; crosslinking agents C08K) · CPC title
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