Spreading agent for agrochemicals, and agrochemical spray solution

Patent metadata

Field	Value
Publication number	US-11944093-B2
Application number	US-201916978509-A
Country	US
Kind code	B2
Filing date	Mar 7, 2019
Priority date	Mar 8, 2018
Publication date	Apr 2, 2024
Grant date	Apr 2, 2024

Abstract

The present invention provides a spreading agent for agrochemicals having superior adhesion particularly for plant surface. The present invention also provides an agrochemical spray solution having a reduced risk of leaving the spreading agent for agrochemicals on a plant surface. The present invention relates to a spreading agent for agrochemicals comprising a carboxy-modified vinyl alcohol polymer (A) having a carboxy-containing monomer unit content of 0.1 mol % to 10 mol %, a viscosity-average degree of polymerization of 200 to 5,000, and a degree of saponification of 65 mol % to 99.9 mol %.

First claim

The invention claimed is:

1. An agrochemical spray solution, comprising
a spreading agent comprising a carboxy-modified vinyl alcohol polymer (A) having a carboxy-containing monomer unit content of 0.1 mol % to 10 mol %, a viscosity-average degree of polymerization of 200 to 5,000, and a degree of saponification of 65 mol % to 99.9 mol %;
a water-soluble active agrichemical component having a saturation solubility of 50 ppm or more in water at a temperature of 21° C.; and
water,
wherein the agrochemical spray solution comprises 0.1 parts by mass to 1,000 parts by mass of the active agrichemical component relative to 100 parts by mass of the carboxy-modified vinyl alcohol polymer (A).

2. The agrochemical spray solution according to claim 1 , wherein the spreading agent further comprises 0.001 parts by mass to 25 parts by mass of a polyvalent metal ionizable compound (B) relative to 100 parts by mass of the carboxy-modified vinyl alcohol polymer (A).

3. The agrochemical spray solution according to claim 2 , wherein the polyvalent metal ionizable compound (B) is an organic salt or an inorganic salt.

4. The agrochemical spray solution according to claim 3 , wherein the organic salt or the inorganic salt comprises a cation that is at least one selected from the group consisting of an alkaline earth metal ion, a transition metal ion, an aluminum ion (Al 3+ ) and a zinc ion (Zn 2+ ).

5. The agrochemical spray solution according to claim 3 , wherein the organic salt or the inorganic salt comprises an anion that is at least one selected from the group consisting of an acetate ion (CH 3 COO 31 ), a carbonate ion (CO 3 2− ), hydroxide ion (OH − ), an iodide ion (I′), a chloride ion (Cl 31 ), a bromide ion (Br − ), a nitrate ion (NO 3 − ), a sulfate ion (SO 4 2− ), an orthosilicate ion (SiO 4 4− ), and a phosphate ion (PO 4 3− ).

6. The agrochemical spray solution according to claim 1 , wherein the carboxy-containing monomer is at least one selected from the group consisting of an ethylenic unsaturated monocarboxylic acid, an ethylenic unsaturated monocarboxylic acid derivative, an ethylenic unsaturated dicarboxylic acid, and an ethylenic unsaturated dicarboxylic acid derivative.

7. The agrochemical spray solution according to claim 6 , wherein the ethylenic unsaturated monocarboxylic acid or the ethylenic unsaturated monocarboxylic acid derivative are at least one selected from the group consisting of (meth)acrylic acid, a (meth)acrylic acid salt, methyl (meth)acrylate, ethyl (meth)acrylate, n-propyl (meth)acrylate, and isopropyl (meth)acrylate.

8. The agrochemical spray solution according to claim 6 , wherein the ethylenic unsaturated dicarboxylic acid or the ethylenic unsaturated dicarboxylic acid derivative are at least one selected from the group consisting of maleic acid, a maleic acid salt, a maleic acid ester, itaconic acid, an itaconic acid salt, an itaconic acid ester, fumaric acid, a fumaric acid salt, a fumaric acid ester, maleic anhydride, itaconic anhydride and itaconic anhydride.

9. The agrochemical spray solution according to claim 1 , wherein the carboxy-containing monomer is at least one selected from the group consisting of maleic acid, monomethyl maleate, dimethyl maleate, itaconic acid, monomethyl itaconate, dimethyl itaconate, (meth)acrylic acid, and methyl (meth)acrylate.

Assignees

• Kuraray Co

Inventors

• Kaharu Taeko
• Morikawa Keisuke

Classifications

• A01N25/24 Primary

  containing ingredients to enhance the sticking of the active ingredients · CPC title

• A01N37/36

  containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids · CPC title

• C08K3/105

  Compounds containing metals of Groups 1 to 3 or of Groups 11 to 13 of the Periodic Table · CPC title

• C08K3/28

  Nitrogen-containing compounds · CPC title

• A01N57/28

  containing acyclic or cycloaliphatic radicals · CPC title