Flexible multi-layered cover lens stacks for foldable displays

Patent metadata

Field	Value
Publication number	US-11940682-B2
Application number	US-202016902388-A
Country	US
Kind code	B2
Filing date	Jun 16, 2020
Priority date	Jun 26, 2019
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

Embodiments described and discussed herein generally relate to flexible or foldable display devices, and more specifically to flexible cover lens assemblies. In one or more embodiments, a flexible cover lens assembly contains a glass layer, an adhesion promotion layer on the glass layer, an anti-reflectance layer disposed on the adhesion promotion layer, a dry hardcoat layer having a nano-indentation hardness in a range from about 1 GPa to about 5 GPa and disposed on the anti-reflectance layer, and an anti-fingerprint coating layer disposed on the dry hardcoat layer.

First claim

What is claimed is:

1. A flexible cover lens assembly, comprising:
a glass layer;
a wet hardcoat layer disposed on the glass layer, wherein the wet hardcoat layer comprises an acrylate, and wherein the acrylate comprises a radiation curable acrylate, aliphatic urethane acrylate, a copolymer thereof, an elastomer thereof, or any combination thereof;
an adhesion promotion layer disposed directly on the wet hardcoat layer, wherein the adhesion promotion layer comprises a material selected from the group consisting of silicon oxide, silicon carbide, silicon oxycarbide, silicon nitride, silicon oxynitride, silicon oxycarbide nitride, a dopant thereof, and any combination thereof, and wherein the adhesion promotion layer has a refractive index in a range from about 1.40 to about 1.55;
an anti-reflectance layer disposed directly on the adhesion promotion layer;
a dry hardcoat layer disposed directly on the anti-reflectance layer, wherein the dry hardcoat layer comprises a material selected from the group consisting of silicon carbide, silicon oxycarbide, silicon oxycarbide nitride, a dopant thereof, and any combination thereof, and wherein the dry hardcoat layer has:
a refractive index of about 1.42 to about 1.55;
a nano-indentation hardness in a range from about 1 GPa to about 5 GPa; and
a porosity of about 1% to about 8%; and

an anti-fingerprint coating layer disposed directly on the dry hardcoat layer;
wherein the flexible cover lens assembly has a critical strain of greater than 1% to about 15%.

2. The flexible cover lens assembly of claim 1 , wherein the flexible cover lens assembly has a critical strain in a range from about 1.5% to about 10%.

3. The flexible cover lens assembly of claim 1 , wherein the glass layer is an ultra-thin glass layer and has thickness in a range from about 20 μm to about 100 μm.

4. The flexible cover lens assembly of claim 1 , wherein the wet hardcoat layer has a nano-indentation hardness in a range from about 0.5 GPa to about 1.2 GPa.

5. The flexible cover lens assembly of claim 1 , wherein the dry hardcoat layer is produced from a vapor deposition process and has a nano-indentation hardness in a range from about 1.5 GPa to about 4.5 GPa.

6. The flexible cover lens assembly of claim 1 , wherein the dry hardcoat layer has a porosity of about 3% to about 7%.

7. The flexible cover lens assembly of claim 1 , wherein the dry hardcoat layer has a refractive index of about 1.45 to about 1.52.

8. The flexible cover lens assembly of claim 1 , wherein the dry hardcoat layer has a thickness in a range from about 0.5 μm to about 40 μm.

9. The flexible cover lens assembly of claim 1 , wherein a substrate is disposed directly on the glass layer.

10. A flexible cover lens assembly, comprising:
a glass layer;
a substrate disposed directly on the glass layer;
a wet hardcoat layer disposed directly on the substrate, wherein the wet hardcoat layer comprises an acrylate, and wherein the acrylate comprises a radiation curable acrylate, aliphatic urethane acrylate, a copolymer thereof, an elastomer thereof, or any combination thereof;
an adhesion promotion layer disposed directly on the wet hardcoat layer, wherein the adhesion promotion layer comprises a material selected from the group consisting of silicon oxide, silicon carbide, silicon oxycarbide, silicon nitride, silicon oxynitride, silicon oxycarbide nitride, a dopant thereof, and any combination thereof;
an anti-reflectance layer disposed directly on the adhesion promotion layer;
a dry hardcoat layer disposed directly on the anti-reflectance layer, wherein the dry hardcoat layer comprises a material selected from the group consisting of silicon carbide, silicon oxycarbide, silicon oxycarbide nitride, a dopant thereof, and any combination thereof; and
an anti-fingerprint coating layer disposed directly on the dry hardcoat layer;
wherein the flexible cover lens assembly has a critical strain of greater than 1% to about 15%.

11. The flexible cover lens assembly of claim 10 , wherein the flexible cover lens assembly has a critical strain in a range from about 1.5% to about 10%.

12. A flexible cover lens assembly, comprising:
a glass layer;
a substrate disposed directly on the glass layer;
a wet hardcoat layer disposed directly on the substrate, wherein the wet hardcoat layer comprises an acrylate, and wherein the acrylate comprises a radiation curable acrylate, aliphatic urethane acrylate, a copolymer thereof, an elastomer thereof, or any combination thereof;
an adhesion promotion layer disposed directly on the wet hardcoat layer, wherein the adhesion promotion layer comprises a material selected from the group consisting of silicon oxide, silicon carbide, silicon oxycarbide, silicon nitride, silicon oxynitride, silicon oxycarbide nitride, a dopant thereof, and any combination thereof, and wherein the adhesion promotion layer has a refractive index in a range from about 1.40 to about 1.55;
an anti-reflectance layer disposed directly on the adhesion promotion layer;
a dry hardcoat layer disposed directly on the anti-reflectance layer, wherein the dry hardcoat layer comprises a material selected from the group consisting of silicon carbide, silicon oxycarbide, silicon oxycarbide nitride, a dopant thereof, and any combination thereof; and
an anti-fingerprint coating layer disposed on the dry hardcoat layer.

13. The flexible cover lens assembly of claim 12 , wherein the flexible cover lens assembly has a critical strain in a range from about 1.5% to about 15%.

14. The flexible cover lens assembly of claim 12 , wherein the dry hardcoat layer has a porosity of about 3% to about 7%.

15. The flexible cover lens assembly of claim 12 , wherein the dry hardcoat layer is produced from a vapor deposition process and has a nano-indentation hardness in a range from about 1.5 GPa to about 4.5 GPa.

16. The flexible cover lens assembly of claim 12 , wherein the wet hardcoat layer is produced from a gel, a spin-coating, a solution, a suspension, or any combination thereof.

17. The flexible cover lens assembly of claim 12 , wherein the wet hardcoat layer has a porosity of about 6% to about 10%.

18. The flexible cover lens assembly of claim 12 , wherein the wet hardcoat layer has a refractive index of about 1.40 to about 1.55.

19. The flexible cover lens assembly of claim 12 , wherein the wet hardcoat layer has a nano-indentation hardness in a range from about 0.5 GPa to about 1.2 GPa.

20. The flexible cover lens assembly of claim 12 , wherein the wet hardcoat layer has a thickness in a range from about 0.5 μm to about 40 μm.

Assignees

• Applied Materials Inc

Inventors

• Thothadri Manivannan
• You Harvey
• Nominanda Helinda
• Morrison Neil
• Forster Daniel Paul
• Chadha Arvinder

Classifications

• H05K5/03

  Covers · CPC title

• G09F9/301 Primary

  flexible foldable or roll-able electronic displays, e.g. thin LCD, OLED · CPC title

• Y02E10/549

  Organic PV cells · CPC title

• G02B1/116

  including electrically conducting layers · CPC title

• H10K59/879

  comprising refractive means, e.g. lenses · CPC title