Weft-knitted spacer fabric and a preparation method thereof, use of the fabric for the preparation of a composite material and a composite material comprising the same

Patent metadata

Field	Value
Publication number	US-11939708-B2
Application number	US-201917046587-A
Country	US
Kind code	B2
Filing date	Apr 8, 2019
Priority date	Apr 13, 2018
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

Described herein is a weft-knitted spacer fabric and a preparation method thereof, a polyurethane foam composite material including the fabric, a preparation method of the composite material and its use in shoe materials. The weft-knitted spacer fabric consists of an upper surface layer, intermediate spacer yarns, and a lower surface layer, and the upper surface and the lower surface layer are connected by the tuck of the spacer yarns in the upper surface and the lower surface layer to form a three-dimensional structure in an integrated manner. The different selected tuck needle changes the connecting distance and the number of connections of the tuck, and the thickness of the spacer fabric and the arrangement density of the spacer yarns are changed by the action of the upper and lower surface layers of elastic yarns.

First claim

The invention claimed is:

1. A weft-knitted spacer fabric consisting of an upper surface layer, intermediate spacer yarns, and a lower surface layer, wherein the upper surface layer and the lower surface layer use two yarns, non-elastic and elastic yarns, and there are tucks formed by the intermediate spacer yarns between the upper and lower surface layers, so that the upper surface is connected with the lower surface layer to form a three-dimensional structure in an integrated manner, characterized in that by selectively using a tuck with a different connecting distance in a local region than other regions and by an action of the elastic yarns in the upper and lower surface layers, a thickness of a local region is changed.

2. The weft-knitted spacer fabric according to claim 1 , characterized in that the thickness in a wale direction of the weft-knitted spacer fabric is changed by changing a connecting distance of the tuck in different courses and by the action of the elastic yarns in the upper and lower surface layers.

3. The weft-knitted spacer fabric according to claim 1 , characterized in that the thickness in a course direction of the weft-knitted spacer fabric is changed by changing the connecting distance of the tuck in different loops in the same course and by the action of the elastic yarns in the upper and lower surface layers.

4. The weft-knitted spacer fabric according to claim 1 , characterized in that distributed meshes are formed in the upper and lower surface layers by selectively loop transferring.

5. The weft-knitted spacer fabric according to claim 1 , characterized in that an arrangement density of the spacer intermediate yarns in a local region is changed by keeping the connecting distance of the tuck constant and selectively changing a number of intermediate spacer yarns in the local region.

6. The weft-knitted spacer fabric according to claim 1 , characterized in that the non-elastic yarns are selected from a 167 dtex/96F low-elasticity polyester yarn or a 110 dtex/48F low-elasticity polyester yarns; and the elastic yarns are selected from a 33 dtex nylon/22 dtex spandex covered yarn, a 77 dtex high-elasticity nylon yarn or a high-elasticity polyester yarn.

7. A method for preparing the weft-knitted spacer fabric according to claim 1 , the method comprising:
weaving on a double needle bar computerized flat knitting machine with an electronic needle selection device, wherein firstly weaving two courses of a single-side texture of the upper surface layer and the lower surface layer respectively on front and rear needle bars with non-elastic and elastic yarns in a form of plating, and
connecting the upper surface layer and the lower surface layer together by using the intermediate spacer yarns to weave through a needle selection tuck of the front and rear needle bars, characterized in that the connecting distance of the tuck is changed by changing a program design in the computerized flat knitting machine.

8. The method according to claim 7 , characterized in that with aid of an empty needle on the rear needle bar and a lateral movement of the rear needle bar, the front needle bar transfers a loop to an adjacent 1-5 needles on a same bed by using a selected needle, and the front needle bar is moved to the loop to form distributed meshes.

9. The method according to claim 7 , wherein the connecting distance of the tuck is kept constant and number of intermediate spacer yarns in a local region is selectively changed.

10. The method according to claim 7 , wherein the weft-knitted spacer fabric is heat set after the weft-knitted spacer fabric is removed from the computerized flat knitting machine.

11. A method for the preparation of a composite material, the method comprising:
using the weft-knitted spacer fabric according to claim 1 for the preparation of a composite material.

12. The method according to claim 11 , wherein the composite material is a shoe material.

13. A composite material comprising the weft-knitted spacer fabric according to claim 1 and a resin.

14. The composite material according to claim 13 , wherein the resin is an unsaturated polyester resin, an epoxy resin, or a polyurethane.

15. The composite material according to claim 14 , wherein the polyurethane is prepared by reacting:
(a) a di- or polyisocyanate,
(b) a polyether polyol or polyester polyol, and
(c) optionally a blowing agent.

16. The composite material according to claim 15 , wherein a functionality of the polyether polyol or the polyester polyol is from about 1.7 to about 2.5.

17. The composite material according to claim 15 , wherein a hydroxyl number of the polyether polyol or the polyester polyol is from about 50 to about 270 mg KOH/g.

18. The composite material according to claim 15 , wherein a molecular weight of the polyether polyol or the polyester polyol is from about 500 to about 6000.

19. The composite material according to claim 15 , wherein a polydispersion index of the polyether polyol or polyester polyol is from about 0.8 to about 1.3.

20. A method for preparing the composite material according to claim 13 , comprising infusing the resin into the weft-knitted spacer fabric.

21. The method according to claim 20 , wherein the resin is a polyurethane, the method further comprising:
adding the weft-knitted spacer fabric and starting materials for preparing a polyurethane foam into a mold, and
foaming.

22. The method according to claim 21 , the method further comprising:
mixing a reaction mixture for preparing the polyurethane foam,
infusing the reaction mixture for preparing the polyurethane foam into the weft-knitted spacer fabric which has already been put into the mold.

23. The method according to claim 22 , wherein the infusion is carried out by using vacuum-assisted resin transfer molding (VARTM) or by direct casting.

24. The method according to claim 22 , wherein the infusion is carried out in such a way that the reaction mixture for preparing the polyurethane foam flows through the weft-knitted spacer fabric in an intermediate spacer yarn direction.

25. A shoe material comprising the composite material according to claim 13 .

26. The shoe material according to claim 25 , wherein the shoe material is a shoe sole.

Assignees

• Basf Se

Inventors

• Sun xiao yu
• Wu Xiaojun
• Zhu li chao
• Zhang Ren Zheng
• Zhu Wenyan
• Hu Xueli
• Long Hairu

Classifications

• D04B1/22 Primary

  specially adapted for knitting goods of particular configuration · CPC title

• A43B13/12

  Soles with several layers of different materials · CPC title

• C08J9/125

  Water, e.g. hydrated salts · CPC title

• D04B1/16

  synthetic threads · CPC title

• D04B1/18 Primary

  elastic threads · CPC title