Water borne dry lamination bonding agent with heat resistance improvement

Patent metadata

Field	Value
Publication number	US-11939498-B2
Application number	US-201716604368-A
Country	US
Kind code	B2
Filing date	Apr 11, 2017
Priority date	Apr 11, 2017
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

The present disclosure is directed to a two-component bonding agent composition and a process for applying a layer of the bonding agent composition to substrate layers to make laminates.

First claim

What is claimed is:

1. A laminate comprising:
a first substrate that is a biaxially oriented polypropylene (BOPP) film;
a second substrate that is a vacuum metallized casted polyethylene terephthalate polyester film (VMPET);
a third substrate that is a polyethylene (PE) film;
a composition consisting of
(a) a first component that is an aqueous mixture with its solid portion consisting of
(i) 0.1% to 10% of a polyol containing at least two hydroxyl groups and being selected from the group consisting of water dispersible polyether polyols, polyester polyols, polyether polyester polyols and mixtures thereof,
(ii) 3% to 30% of a rosin resin, and
(iii) from 65% to 96% of a polymer having from 23-45% residues of at least one styrene monomer, from 50-80% residues of at least one acrylic monomer having a Tg less than 0° C., and from 1.5% to 2.5% residues of (meth)acrylic acid; and

(b) a second component consisting of a water dispersible polyisocyanate, wherein the second component is present relative to the first component at a NCO/NCO-reactive group molar ratio of 1:1 to 8:1; wherein the composition bonds the first substrate to the second substrate; and
the composition bonds the second substrate to the third substrate.

2. The laminate according to claim 1 , wherein the polymer has a weight average molecular weight of between 5,000 and 2,000,000.

3. The laminate according to claim 1 , wherein the polyol is polypropylene glycol.

4. The laminate according to claim 1 , wherein the polyol has a number average molecular weight from 100 to 7,500.

5. The laminate according to claim 1 , wherein the rosin resin is selected from modified rosins, hydrogenated rosins, disproportionated rosins and polymerized rosins obtained respectively by modifying, hydrogenating, disproportionating and polymerizing raw material rosins, and rosin esters obtained by esterifying raw material rosins with alcohols or an epoxy compound.

6. The laminate according to claim 5 , wherein the modified rosin resins are selected from unsaturated modified rosins obtained by modifying raw material rosins with unsaturated acid, and phenolic modified rosins obtained by modifying raw material rosins with phenols.

7. The laminate according to claim 6 , wherein the unsaturated acids are acrylic acid, methacrylic acid, fumaric acid, and maleic acid.

8. The laminate according to claim 6 , wherein the phenols are phenol and alkylphenol.

9. The laminate according to claim 5 , wherein the alcohol is glycerin.

10. The laminate according to claim 5 , wherein the alcohol is pentaerythritol.

11. The laminate according to claim 1 , wherein the rosin resin has a molecular weight of from 1,000 to 50,000.

12. The laminate according to claim 1 , wherein the rosin resin has an acid value of from 1 to 50 KOH mg/g.

13. The laminate according to claim 1 , wherein the rosin resin has a softening point of from 25° C. to 200° C.

14. The laminate according to claim 1 wherein the polyisocyanate is selected from polyisocyanates based on toluene diisocyanate, isophorone diisocyanate, hexamethylene diisocyanate, diphenyl methane diisocyanate, dicyclohexyl methane diisocyanate, isomers thereof, and mixtures thereof.

15. A process for making the laminate of claim 1 wherein at least two substrate layers are bonded together by a layer of the bonding agent composition, comprising bonding said at least two substrate layers with the bonding agent composition.

16. The laminate of claim 4 1 wherein the polymer consists of from 23-45% residues of a styrene monomer, from 50-80% residues of an acrylic monomer having a Tg less than 0° C. that is butyl acrylate, and from 1.5% to 2.5% residues of acrylic acid.

17. The laminate of claim 16 wherein the polymer consists of 38% styrene monomer, 60% butyl acrylate, and 2% acrylic acid.

18. The laminate of claim 16 wherein the composition consists of
(a)(i) from 1 % to 1.8% of a polyether diol,
(a)(ii) from 5% to 30% of the rosin resin,
(a)(iii) from 68.6% to 94% of the polymer; and
(b) 2% of the second component.

19. A laminate consisting of:
a first substrate that is a biaxially oriented polypropylene (BOPP) film;
a second substrate that is a vacuum metallized casted polyethylene terephthalate polyester film (VMPET);
a third substrate that is a polyethylene (PE) film;
a composition consisting of
(a) a first component that is an aqueous mixture with its solid portion consisting of
(i) 0.1% to 10% of a polyol containing at least two hydroxyl groups and being selected from the group consisting of water dispersible polyether polyols, polyester polyols, polyether polyester polyols and mixtures thereof,
(ii) 3% to 30% of a rosin resin, and
(iii) from 65% to 96% of a polymer having from 23-45% residues of at least one styrene monomer, from 50-80% residues of at least one acrylic monomer having a Tg less than 0° C., and from 1.5% to 2.5% residues of (meth)acrylic acid; and

(b) a second component consisting of a water dispersible polyisocyanate, wherein the second component is present relative to the first component at a NCO/NCO-reactive group molar ratio of 1:1 to 8:1; wherein the composition bonds the first substrate to the second substrate; and
the composition bonds the second substrate to the third substrate.

Assignees

• Dow Global Technologies Llc
• Rohm & Haas

Inventors

• Chen Mai
• Pan Yuanjia
• Wang Xinhong
• Chen Gaobing
• Liu Xinchun

Classifications

• C09J193/04 Primary

  Rosin · CPC title

• B32B7/12 Primary

  using interposed adhesives or interposed materials with bonding properties · CPC title

• C09J5/00

  Adhesive processes in general; Adhesive processes not provided for elsewhere, e.g. relating to primers · CPC title

• C09J133/062

  Copolymers with monomers not covered by C09J133/06 · CPC title

• C09J2433/00

  Presence of (meth)acrylic polymer · CPC title