Three-dimensional printing

Patent metadata

Field	Value
Publication number	US-11939484-B2
Application number	US-201917298927-A
Country	US
Kind code	B2
Filing date	Jun 10, 2019
Priority date	Jun 10, 2019
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

A multi-fluid kit for three-dimensional printing can include a fusing agent with water and a radiation absorber, and a detailing agent. The radiation absorber can absorb radiation energy and converts the radiation energy to heat. The detailing agent can include water and from about 0.1 wt % to about 20 wt % organosilanes based on a total weight of the detailing agent, wherein the organosilanes include an organosilane compound with a central silicon having both a water-solubilizing group and multiple hydrolyzable groups attached thereto.

First claim

What is claimed is:

1. A multi-fluid kit for three-dimensional printing, comprising:
a fusing agent comprising water and a radiation absorber, wherein the radiation absorber absorbs radiation energy and converts the radiation energy to heat; and
a detailing agent comprising water and from about 0.1 wt % to about 20 wt % of organosilanes based on a total weight of the detailing agent, wherein the organosilanes include an organosilane compound with a central silicon having both a water-solubilizing group and multiple hydrolyzable groups attached to the central silicon.

2. The multi-fluid kit of claim 1 , wherein the organosilane is a triethoxyorganosilane compound.

3. The multi-fluid kit of claim 1 , wherein the water-solubilizing group is selected from the group consisting of polyethylene oxide, amine, glycidyl, succinic anhydride, and a combination thereof.

4. The multi-fluid kit of claim 1 , wherein the water-solubilizing group is a polyethylene oxide urethane.

5. The multi-fluid kit of claim 1 , wherein the organosilanes further include a tetraalkoxyorganosilane compound in addition to the organosilane compound having the water-solubilizing group and multiple hydrolyzable groups attached thereto.

6. The multi-fluid kit of claim 1 , wherein the radiation absorber is selected from the group consisting of a metal dithiolene complex, carbon black, near-infrared absorbing dye, near-infrared absorbing pigment, metal nanoparticles, conjugated polymer, and a combination thereof.

7. The multi-fluid kit of claim 1 , wherein the water is present in the detailing agent in an amount ranging from about 50 wt % to about 99 wt %.

8. The multi-fluid kit of claim 1 , wherein:
the detailing agent includes from about 60 wt % to about 94 wt % of water, from about 5 wt % to about 35 wt % of an organic cosolvent, and from about 1 wt % to about 10 wt % of an organosilane, based on a total weight of the detailing agent; and
the fusing agent includes from about 60 wt % to about 94 wt % of water, from about 5 wt % to about 35 wt % of an organic cosolvent, and from about 1 wt % to about 20 wt % of a radiation absorber, based on a total weight of the fusing agent.

9. A three-dimensional printing kit, comprising:
a fusing agent comprising water and a radiation absorber, wherein the radiation absorber absorbs radiation energy and converts the radiation energy to heat;
a detailing agent comprising water and from about 0.1 wt % to about 20 wt % of organosilanes based on a total weight of the detailing agent, wherein the organosilanes include an organosilane compound with a central silicon having both a water-solubilizing group and multiple hydrolyzable moieties attached to the central silicon; and
a powder bed material including from about 60 wt % to 100 wt % of polymeric particles,
wherein the organosilanes are reactive with one another to form polysiloxanes that are chemically independent relative to the polymeric particles.

10. The three-dimensional printing kit of claim 9 , wherein the polymeric particles are selected from the group consisting of polyamide particles, polyethylene particles, thermoplastic polyurethane particles, polypropylene particles, polyester particles, polycarbonate particles, polyether ketone particles, polyacrylate particles, polystyrene particles, wax particles, and a combination thereof.

11. The three-dimensional printing kit of claim 9 , wherein the organosilanes are selected from the group consisting of dialkoxysilanes, trialkoxysilanes, and a combination thereof.

12. The three-dimensional printing kit of claim 9 , wherein the water-solubilizing group is a polyethylene oxide urethane.

13. A method of making a three-dimensional printed article, comprising:
iteratively applying individual build material layers of a powder bed material including polymer particles to a powder bed;
based on a three-dimensional object model, selectively jetting a fusing agent onto individual build material layers, wherein the fusing agent comprises water and a radiation absorber;
based on the three-dimensional object model, selectively jetting a detailing agent onto individual build material layers laterally at a border between a first area where the powder bed material is contacted by the fusing agent and a second area where the powder bed material is not contacted by the fusing agent, wherein the detailing agent comprises water and from about 0.1 wt % to about 20 wt % of organosilanes based on a total weight of the detailing agent, wherein the organosilanes include an organosilane compound with a central silicon having both a water-solubilizing group and multiple hydrolyzable moieties attached to the central silicon; and
exposing the powder bed material to energy to selectively fuse the polymer particles in contact with the radiation absorber to form a fused polymer matrix at individual build material layers.

14. The method of claim 13 , wherein the organosilanes forms polysiloxanes at the border that are chemically independent relative to the polymeric particles.

15. The method of claim 13 , wherein during the exposing, the energy and the radiation absorber together raise a temperature of the polymer particles in contact with the radiation absorber to a range of from about 100° C. to about 250° C. to fuse the polymer particles in contact with the radiation absorber.

Assignees

• Hewlett Packard Development Co

Inventors

• Negri Jimenez Graciela E
• Novick Michael A
• Chen Tienteh
• Wright Jacob

Classifications

• C09D11/54 Primary

  Inks based on two liquids, one liquid being the ink, the other liquid being a reaction solution, a fixer or a treatment solution for the ink · CPC title

• B29C64/165

  using a combination of solid and fluid materials, e.g. a powder selectively bound by a liquid binder, catalyst, inhibitor or energy absorber · CPC title

• B33Y10/00 Primary

  Processes of additive manufacturing · CPC title

• B33Y70/00

  Materials specially adapted for additive manufacturing · CPC title

• C08K5/5415

  containing at least one Si—O bond · CPC title