Low emission polyoxymethylene composition

Patent metadata

Field	Value
Publication number	US-11939464-B2
Application number	US-202217856500-A
Country	US
Kind code	B2
Filing date	Jul 1, 2022
Priority date	Apr 7, 2017
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

A polyoxymethylene polymer composition is disclosed containing a formaldehyde stabilizer package. The formaldehyde stabilizer package, which contains at least two emission control agents, dramatically and unexpectedly reduces formaldehyde emissions. The formaldehyde stabilizer package includes at least two emission control agents selected from the group of benzoguanamine compounds, a hydantoin, a substituted hydantoin, an amino acid, and an alkylene urea such as ethylene urea.

First claim

What is claimed:

1. A polymer composition comprising:
a polyoxymethylene polymer; and
a formaldehyde stabilizer package for reducing formaldehyde emissions, the formaldehyde stabilizer package comprising a blend of emission control agents, the blend including an ethylene urea, a guanamine compound, and allantoin.

2. A polymer composition as defined in claim 1 , wherein the formaldehyde stabilizer package further comprises a hydantoin.

3. A polymer composition as defined in claim 1 , wherein the formaldehyde stabilizer package further comprises an amino acid.

4. A polymer composition as defined in claim 3 , wherein the amino acid comprises arginine.

5. A polymer composition as defined in claim 1 , wherein the allantoin is present in an amount less than about 0.2% by weight and in an amount greater than about 0.001% by weight.

6. A polymer composition as defined in claim 1 , wherein the guanamine compound comprises benzoguanamine.

7. A polymer composition as defined in claim 6 , wherein the guanamine compound is present in the composition in an amount greater than about 0.2% by weight, and being present in an amount less than about 1% by weight.

8. A polymer composition as defined in claim 1 , wherein the ethylene urea is present in an amount from about 0.001% by weight to about 0.2% by weight.

9. A polymer composition as defined in claim 1 , wherein the polymer composition exhibits a formaldehyde emission of less than about 3 ppm when tested according to VDA Test 275.

10. A polymer composition as defined in claim 1 , wherein the polymer composition further comprises a nucleant in an amount from about 0.05% by weight to about 1% by weight, an antioxidant in an amount from about 0.05% to about 2% by weight, and a lubricant in an amount from about 0.05% to about 1.5% by weight.

11. A polymer composition as defined in claim 1 , wherein the polymer composition has a tensile modulus of at least 1200 MPa when tested according to ISO Test 527 at 23° C., has a tensile strain at yield of greater than about 7% when tested according to ISO Test 527 at 23° C. and has a notched Charpy impact strength of greater than about 3 kJ/m 2 when tested according to ISO Test 179-1 at 23° C.

12. A molded article made from a polymer composition of claim 1 .

13. A molded article as defined in claim 12 , wherein the molded article comprises a medical product.

14. A polymer composition comprising:
a polyoxymethylene polymer; and
a formaldehyde stabilizer package for reducing formaldehyde emissions, the formaldehyde stabilizer package comprising a blend of emission control agents, the blend including an ethylene urea and a hydantoin.

Assignees

• Ticona Llc

Inventors

• Kim Sung Hye
• Luo Rong
• Kindt Jared T

Classifications

• C08L59/02 Primary

  Polyacetals containing polyoxymethylene sequences only · CPC title

• C08G2/08

  Polymerisation of formaldehyde · CPC title

• C08K5/005

  Stabilisers against oxidation, heat, light, ozone · CPC title

• C08K5/0083

  Nucleating agents promoting the crystallisation of the polymer matrix · CPC title

• C08K5/16

  Nitrogen-containing compounds {(C08K5/0091 takes precedence)} · CPC title