Polyolefin formulation with poly(2-alkyl-2-oxazoline)

Patent metadata

Field	Value
Publication number	US-11939455-B2
Application number	US-201815733909-A
Country	US
Kind code	B2
Filing date	Jun 29, 2018
Priority date	Jun 29, 2018
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

A polyolefin-and-poly (2-alkyl-2-oxazoline) formulation comprising (A) an olefin-based (co) polymer, (B) a poly (2-alkyl-2-oxazoline) (co) polymer, and (C) an antioxidant. Also a method of making the composition; a crosslinked polyolefin product made by curing the composition; manufactured articles comprising a shaped form of the inventive formulation or product; and methods of using the inventive formulation, product, or articles.

First claim

The invention claimed is:

1. A polyolefin-and-poly(2-alkyl-2-oxazoline) formulation comprising from 80.50 to 99.70 weight percent (wt %) of (A) an olefin-based (co)polymer; from 0.1 to 15.0 wt % of (B) a poly(2-alkyl-2-oxazoline) (co)polymer; from 0.10 to 1.5 wt % of (C) an antioxidant; and from 0.1 to 3 wt % of (D) an organic peroxide; with the proviso that the wt % of (A)=100.00 wt %−wt % of (B)−wt % of (C)−wt % (D)−wt % of all other optional constituents, if any and with the proviso that the formulation is free of an anti-static agent and a carbon black.

2. The polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of claim 1 wherein the (A) olefin-based (co)polymer is (i) an ethylene-based (co)polymer, a propylene-based (co)polymer, or a combination of any two or more thereof; or (ii) a polyethylene homopolymer, an ethylene/alpha-olefin copolymer, an ethylene/unsaturated carboxylic ester copolymer, an ethylene/olefin-functional hydrolyzable silane copolymer, or a combination of any two or more thereof.

3. The polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of claim 1 wherein the (B) poly(2-alkyl-2-oxazoline) (co)polymer is a poly(2-alkyl-2-oxazoline) homopolymer, a poly(2-alkyl-2-oxazoline) copolymer, or a combination of any two or more thereof.

4. The polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of claim 1 wherein the (C) antioxidant is a hindered phenol, a phosphite, a phosphonite, a thio compound, an antioxidizing amine, or a combination of any two or more thereof.

5. The polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of claim 1 , characterized by (i) an increase in water-tree length (WTL) of less than 10% when measured according to the Water-Tree Growth Test Method using ASTM D6097; (ii) a dissipation factor of less than 0.30%, when measured according to the Dissipation Factor Test Method; or both (i) and (ii).

6. The polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of claim 1 comprising constituents (A) to (D) and a (E) stabilizer, wherein the (A) olefin-based (co)polymer is a low density polyethylene containing comonomeric units derived from 1-butene, 1-hexene, or 1-octene; the (B) poly(2-alkyl-2-oxazoline) (co)polymer is a poly(2-alkyl-2-oxazoline) homopolymer having a weight-average molecular weight (Mw) from 10,000 to 40,000 grams per mole; the (C) antioxidant is a hindered phenol, a thio compound, or a combination of a hindered phenol and a thio compound; and the (D) organic peroxide is dicumyl peroxide.

7. A crosslinked polyolefin product that is a product of curing a polyolefin-and-poly(2-alkyl-2-oxazoline) formulation comprising from 59.99 to 99.94 weight percent (wt %) of (A) an olefin-based (co)polymer; from 0.05 to 20.0 wt % of (B) a poly(2-alkyl-2-oxazoline) (co)polymer; from 0.01 to 1.5 wt % of (C) an antioxidant; and from 0.00 to 3.0 wt % of (D) an organic peroxide; with the proviso that the wt % of (A)=100.00 wt %−wt % of (B)−wt % of (C)−wt % (D)−wt % of all other optional constituents.

8. A manufactured article comprising a shaped form of the crosslinked polyolefin product of claim 7 .

9. An insulated electrical conductor comprising a conductive core and an insulation layer at least partially covering the conductive core, wherein at least a portion of the insulation layer comprises the polyolefin-and-poly(2-alkyl-2-oxazoline) formulation of the crosslinked polyolefin product of claim 7 .

10. A method of conducting electricity, the method comprising applying a voltage across the conductive core of the insulated electrical conductor of claim 9 so as to generate a flow of electricity through the conductive core.

Assignees

• Dow Global Technologies Llc

Inventors

• He Chao
• Sun Yabin
• Cogen Jeffrey M
• Person Timothy J
• Chen Hongyu

Classifications

• C08L23/06 Primary

  Polyethylene · CPC title

• C08G73/0233

  Polyamines derived from (poly)oxazolines, (poly)oxazines or having pendant acyl groups · CPC title

• C08K5/14

  Peroxides · CPC title

• H01B3/307

  Other macromolecular compounds · CPC title

• H01B3/441

  from alkenes · CPC title