Nanotextured metal powders for 3D printing of metals

Patent metadata

Field	Value
Publication number	US-11938536-B2
Application number	US-202217706259-A
Country	US
Kind code	B2
Filing date	Mar 28, 2022
Priority date	Mar 26, 2021
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

Metal powder particles for use in additive manufacturing are made by removing material from the surface of the particles using wet chemical etching to create a nanoscale texturing of the surface, increasing absorptivity by the metal powder particles of incident laser light and maintaining flowability. The nanoscale texturing has sub-wavelength features at laser wavelengths in the range 800-1100 nm. The particles are substantially spherical and have mean diameters in the range 10-70 μm.

First claim

The invention claimed is:

1. A method for processing metal powder particles for use in additive manufacturing, the method comprising:
performing maskless wet chemical etching of a metal surface of the metal powder particles to preferentially etch material at grain boundaries and dislocations from the metal surface and to create a nanoscale texturing of the metal surface, resulting in nanotextured metal powder particles, whereby absorptivity by the nanotextured metal powder particles of incident laser light of predetermined wavelength (λ) is increased and the flowability is maintained;
wherein the metal powder particles are composed substantially of copper, silver, gold, aluminum, platinum, tungsten, niobium, chromium, or zinc;
wherein the nanoscale texturing is characterized in that the root mean square roughness (σ) and correlation length (ξ 0 ) of surface features resulting from the nanoscale texturing of the metal surface is less than the predetermined wavelength (λ), wherein the predetermined wavelength (λ) is in the range 800-1100 nm.

2. The method of claim 1 wherein the metal powder particles have mean diameters in the range 10-70 μm.

3. The method of claim 1 wherein the metal powder particles are substantially spherical, defined to mean that for over 90% of the particles, 4π A/P 2 >0.8, where A is the particle cross-sectional area and P is the corresponding perimeter.

4. The method of claim 1 further comprising rinsing the wet chemical etched metal powder particles in a solution of ethanol to remove residual precipitates produced during the wet chemical etching.

5. The method of claim 1 further comprising passing the wet chemical etched metal powder particles through a 70 μm sieve.

6. The method of claim 1 wherein removing material from the surface of the metal powder particles using wet chemical etching comprises submerging the metal powder particles in a solution and stirring.

7. The method of claim 6 wherein the metal powder particles are composed substantially of copper and the solution is a solution of iron(III) chloride, ethanol, and hydrochloric acid.

8. The method of claim 7 wherein the wet chemical etching is performed for a minimum duration of 60 minutes at room temperature with an etchant ratio of 70 g:50 ml:150 ml for FeCl 3 :HCl:Ethanol.

Assignees

• Univ Leland Stanford Junior

Inventors

• Tertuliano Ottman A
• Depond Philip J
• Lee Andrew Curtis
• Gu Xun
• Cai Wei
• Lew Adrian J

Classifications

• B22F1/07 Primary

  Metallic powder characterised by particles having a nanoscale microstructure (nanosized particles B22F1/054) · CPC title

• B22F1/05

  Metallic powder characterised by the size or surface area of the particles · CPC title

• B22F1/065

  Spherical particles · CPC title

• B22F1/145

  Chemical treatment, e.g. passivation or decarburisation · CPC title

• B33Y70/00 Primary

  Materials specially adapted for additive manufacturing · CPC title