Red mud compositions and methods related thereto

Patent metadata

Field	Value
Publication number	US-11938470-B2
Application number	US-202217989444-A
Country	US
Kind code	B2
Filing date	Nov 17, 2022
Priority date	Apr 6, 2018
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

This disclosure relates to red mud compositions. This disclosure also relates to methods of making red mud compositions. This disclosure additionally relates to methods of using red mud compositions.

First claim

The invention claimed is:

1. A method of making a composition, the method comprising:
colloidally-dispersing red mud with alumina by mixing colloidal red mud with colloidal alumina to form a colloidal mixture of red mud and alumina;
drying the colloidal mixture at a first temperature to form a dried mixture; and
calcining the dried mixture at a second temperature higher than the first temperature to form dried and calcined catalytic particles comprising colloidally-dispersed red mud and alumina.

2. The method of claim 1 , wherein the second temperature is about 600° C. to about 800° C.

3. The method of claim 1 , further comprising reducing the dried and calcined catalytic particles in a reducing atmosphere.

4. The method of claim 3 , wherein the reducing atmosphere comprises 10% hydrogen and 90% nitrogen by volume and the particles are heated to about 450° C.

5. The method of claim 1 , further comprising mixing one or more colloidal additives with the colloidal red mud and the colloidal alumina in the colloidal mixture.

6. The method of claim 5 , wherein the one or more colloidal additives comprise colloidal silica.

7. The method of claim 5 , wherein the one or more colloidal additives comprise colloidal calcium oxide.

8. The method of claim 5 , wherein the one or more colloidal additives comprise colloidal zirconia.

9. The method of claim 5 , wherein the one or more colloidal additives comprise colloidal silica, colloidal calcium oxide, colloidal zirconia, or combinations thereof.

10. The method of claim 1 , further comprising mixing one or more non-colloidal additives with the colloidal mixture prior to drying the colloidal mixture.

11. The method of claim 10 , wherein the one or more non-colloidal additives comprise nickel.

12. The method of claim 11 , wherein the dried and calcined catalytic particles comprise 40% or less Nickel by weight.

13. The method of claim 1 , wherein the dried and calcined catalytic particles comprise at least 50% colloidally-dispersed red mud by weight.

14. The method of claim 1 , wherein the dried and calcined catalytic particles comprise at least 10% to 30% colloidally-dispersed alumina by weight.

15. The method of claim 1 , wherein the dried and calcined catalytic particles have a specific surface area greater than 30 m 2 /g.

16. The method of claim 1 , wherein the dried and calcined catalytic particles have a mean particle size of about 50 micron to about 250 micron.

17. The method of claim 1 , further comprising extruding the dried mixture prior to calcining the dried mixture.

18. The method of claim 17 , wherein the dried and calcined catalytic particles have a mean particle size of about 1 mm to about 5 mm.

19. The method of claim 1 , wherein drying the colloidal mixture comprises spray drying the colloidal mixture.

20. The method of claim 19 , wherein the dried and calcined catalytic particles have a mean particle size of about 250 micron to about 650 micron.

Assignees

• Univ Utah State

Inventors

• Agblevor Foster
• Jahromi Hossein
• Hietsoi Oleksandr
• Hassan Shereen

Classifications

• B01J2235/00

  Indexing scheme associated with group B01J35/00, related to the analysis techniques used to determine the catalysts form or properties · CPC title

• B01J2235/15

  X-ray diffraction · CPC title

• B01J2235/10

  Infrared [IR] · CPC title

• B01J2235/05

  Nuclear magnetic resonance [NMR] · CPC title

• B01J2235/30

  Scanning electron microscopy; Transmission electron microscopy · CPC title