Systems and methods for carbon sequestration using enhanced weathering

Patent metadata

Field	Value
Publication number	US-11938445-B2
Application number	US-202318298196-A
Country	US
Kind code	B2
Filing date	Apr 10, 2023
Priority date	Aug 31, 2021
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

The present disclosure relates, in part, to enhanced weathering systems and/or apparatuses and methods of use thereof. In one aspect, the present disclosure provides a method of at least partially sequestering CO 2 from an influent aqueous solution comprising aqueous and/or gaseous CO 2 . In another aspect, the present disclosure provides a method of at least partially sequestering CO 2 from a gaseous CO 2 source. In another aspect, the present disclosure provides systems and/or apparatuses suitable for use in the methods described herein. In another aspect, the present disclosure provides a method of optimizing the design and operation of a system for at least partial sequestration of CO 2 from a water source.

First claim

What is claimed is:

1. A method of at least partially sequestering CO 2 from a gaseous CO 2 source, the method comprising:
(a) providing an optionally compressed gas stream comprising CO 2 at a concentration ranging from about 1% (v/v) to about 100% (v/v);
(b) feeding the optionally compressed gas stream into an influent aqueous solution to provide a second influent aqueous solution comprising CO 2 ;
(c) measuring in the second influent aqueous solution at least two parameters selected from the group consisting of pH, alkalinity, dissolved CO 2 concentration, dissolved inorganic carbon (DIC) concentration, bicarbonate ion concentration, carbonate ion concentration, and partial pressure of CO 2 (g);
(d) feeding the second influent aqueous solution into at least one container comprising a mineral feedstock, wherein the mineral feedstock is selected from the group consisting of a metal silicate, a metal carbonate, and a metal oxide, and combinations thereof;
(e) contacting the second influent aqueous solution and the mineral feedstock in the container to form an effluent aqueous solution;
measuring in the effluent aqueous solution at least two parameters selected from the group consisting of pH, alkalinity, dissolved CO 2 concentration, dissolved inorganic carbon (DIC) concentration, bicarbonate ion concentration, carbonate ion concentration, and partial pressure of CO 2 (g); and
(g) comparing the at least two measured parameters of the second influent aqueous solution and the at least two measured parameters of the effluent aqueous solution to calculate a change in dissolved CO 2 concentration; and
(h) modifying at least one parameter of the influent aqueous solution or contacting step if the change comprises a decrease in dissolved CO 2 concentration of less than about 95%.

2. The method of claim 1 , wherein the optionally compressed gas stream comprising CO 2 is obtained from at least one source selected from the group consisting of a direct air capture (DAC) unit, CO 2 from organic component combustion, direct CO 2 sources (e.g., flue gas), CO 2 from an industrial source, CO 2 captured from high-purity oxygen activate sludge process, CO 2 from hydrogen production, CO 2 from syngas production, and CO 2 from biogas production.

3. The method of claim 2 , wherein the direct air capture (DAC) unit is a liquid based DAC system or a solid based DAC system.

4. The method of claim 1 , further comprising measuring in the second influent aqueous solution or effluent aqueous solution at least one parameter selected from the group consisting of temperature, conductivity, turbidity, salinity, dissolved oxygen concentration, total suspended solids concentration, total dissolved solids concentration, hardness, dissolved metal concentration, and dissolved non-metal or metalloid concentration.

5. The method of claim 1 , wherein the method is repeated beginning at step (c), by recirculation of the effluent aqueous solution, if at least one of the following occurs:
(a) the pH of the effluent aqueous solution is less than about 8.5;
(b) the change comprises a decrease in dissolved CO 2 concentration of less than about 95%; and
(c) the alkalinity in the effluent aqueous solution is less than 5% different than the alkalinity in the influent aqueous solution.

6. The method of claim 1 , wherein at least one of the following applies:
(a) if the pH of the second influent aqueous solution is greater than about 7.0, at least one acidifying agent is added in a quantity sufficient to achieve a pH of less than about 7.0 in the second influent aqueous solution; and
(b) if the pH of the effluent aqueous solution is greater than about 7.0, at least one acidifying agent is added in a quantity sufficient to achieve a pH of less than about 7.0 in the effluent aqueous solution, and wherein the method is repeated beginning at step (b) by recirculation of the effluent aqueous solution.

7. The method of claim 6 , wherein the acidifying agent is at least one selected from the group consisting of CO 2 (g), CO 2 (aq), one or more organic acids, and one or more inorganic acids.

8. The method of claim 1 , wherein the effluent aqueous solution is subjected to gas stripping if at least one of the following applies:
(a) the dissolved CO 2 concentration of the effluent aqueous solution is greater than the dissolved CO 2 concentration of the second influent aqueous solution; and
(b) the partial pressure of CO 2 of the effluent aqueous solution is greater than atmospheric partial pressure of CO 2 .

9. The method of claim 1 , further comprising treating the effluent aqueous solution to provide a second effluent aqueous solution, wherein the second effluent aqueous solution has at least one selected from the group consisting of a dissolved metal concentration and dissolved non-metal or metalloid concentration which is less than that of the influent aqueous solution or effluent aqueous solution.

10. The method of claim 9 , further comprising measuring in the second effluent aqueous solution at least two parameters selected from the group consisting of pH, alkalinity, dissolved CO 2 concentration, dissolved inorganic carbon (DIC) concentration, bicarbonate ion concentration, carbonate ion concentration, partial pressure of CO 2 (g), and optionally at least one selected from the group consisting of temperature, conductivity, turbidity, salinity, dissolved oxygen concentration, total suspended solids concentration, total dissolved solids concentration, hardness, dissolved metal concentration, and dissolved non-metal or metalloid concentration.

11. The method of claim 1 , wherein the at least one container comprises at least two containers arranged in series, parallel, or any combination thereof.

12. The method of claim 11 , wherein the metal silicate, metal carbonate, or metal oxide have a particle size which decreases in each subsequent container arranged in series, optionally wherein the particle size in an upstream container can be at least 2 times larger than the particle size in a downstream container.

13. The method of claim 1 , wherein the influent aqueous solution comprising CO 2 comprises at least one water source selected from the group consisting of municipal wastewater, industrial wastewater, rainwater, river water, lake water, freshwater, tap water, runoff, storm water, groundwater, and seawater.

14. The method of claim 1 , wherein the metal carbonate has a formula of:
(M 1 ) m (CO 3 ) n (OH) o (L 1 ) p ,
wherein:
M 1 comprises at least one element selected from the group consisting of a Group IA, Group IIA, Group IIIA, Group IVA, Group IB, Group IIB, Group IIIB, Group IVB, Group VB, Group VIB, and Group VIIIB element,
wherein each occurrence of M 1 can comprise one element, two identical elements, or two distinct elements;

L 1 is a neutral ligand, wherein the neutral ligand is optionally H 2 O; and
wherein m, n, o, and p are each independently numbers which are selected such that the metal carbonate has a net zero charge, and
wherein each number is independently optionally an integer.

15. The method of claim 1 , wherein the metal silicate has a formula of:
(M 2 ) q (SiO 4 ) r (OH) s (L 2 ) t ,
wherein:
M 2 comprises at least one element selected from the group consisting of a Group IA, Group IIA, Group IIIA, Group IVA, Group IB, Group IIB, Group TIM, Group IVB, Group VB, Group VIB, and Group VIIIB element,
wherein each occurrence of M 2 can comprise one element, two identical elements, or two distinct elements;

L 2 is a neutral ligand, wherein the neutral ligand is optionally H 2 O; and
where

Assignees

• Univ Yale

Inventors

• Katchinoff Joachim
• Planavsky Noah
• Jordan Jacob
• Takahashi Dean
• Crotty Sinead
• Freiberg Justin

Classifications

• B01D53/62 Primary

  Carbon oxides · CPC title

• B01D53/025

  with wetted adsorbents; Chromatography (analytical chromatography G01N30/00 - G01N30/96; for liquids B01D15/08) · CPC title

• B01D53/1406

  Multiple stage absorption · CPC title

• B01D53/1412

  Controlling the absorption process · CPC title

• B01D53/1475

  Removing carbon dioxide · CPC title