Hybrid post-combustion CO2 capture system and method

Patent metadata

Field	Value
Publication number	US-11938443-B2
Application number	US-202117174853-A
Country	US
Kind code	B2
Filing date	Feb 12, 2021
Priority date	Feb 12, 2020
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

A hybrid post-combustion carbon dioxide capture system for capturing carbon dioxide from a flue gas includes a compressor adapted to produce a compressed flue gas stream, a membrane-based carbon dioxide separation unit configured to receive a first portion of the compressed flue gas stream from the compressor, and an aqueous-based carbon dioxide capture unit configured to receive a second portion of the compressed flue gas stream from the compressor whereby the compressed flue gas stream is processed in parallel by the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit.

First claim

What is claimed is:

1. A hybrid post-combustion carbon dioxide capture system for capturing carbon dioxide from a flue gas, comprising:
a compressor adapted to produce a compressed flue gas stream at a compression rate determined by external electricity demand;
a membrane-based carbon dioxide separation unit configured to receive a first portion of the compressed flue gas stream from the compressor; and
an aqueous-based carbon dioxide capture unit configured to receive a second portion of the compressed flue gas stream from the compressor whereby the compressed flue gas stream is processed in parallel by the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit wherein the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit are configured to operate without recycling any recovered carbon dioxide removed from the compressed flue gas stream to the compressor, the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit.

2. The hybrid post-combustion carbon dioxide capture system, further including a flow control valve for directing the first portion of the compressed flue gas stream to the membrane-based carbon dioxide separation unit.

3. The hybrid post-combustion carbon dioxide capture system of claim 2 , wherein the membrane-based carbon dioxide separation unit includes a reactor and a membrane held in the reactor, wherein the membrane is adapted to allow the passage of carbon dioxide through the membrane.

4. The hybrid post-combustion carbon dioxide capture system of claim 3 , wherein the reactor includes (a) an inlet, adapted for receiving the first portion of the compressed flue gas stream from the compressor, and a first outlet, adapted to discharge a filtered flue gas stream from the reactor, on an upstream side of the membrane and (b) a second outlet on a downstream side of the membrane adapted to discharge a recovered carbon dioxide stream from the reactor.

5. The hybrid post-combustion carbon dioxide capture system of claim 4 , wherein the aqueous-based carbon dioxide capture unit, adapted for operation at a compression rate determined by external electricity demand, includes an absorber for capture of carbon dioxide by a carbon capture solvent in countercurrent flow to the second portion of the compressed flue gas stream moving though the absorber.

6. The hybrid post-combustion carbon dioxide capture system of claim 5 , wherein the aqueous-based carbon dioxide capture unit includes a stripper connected to the absorber and adapted to (a) receive a carbon dioxide-rich carbon capture solvent from the absorber and (b) return a carbon dioxide-lean carbon capture solvent to the absorber.

7. The hybrid post combustion carbon dioxide capture system of claim 6 , wherein the first portion of the compressed flue gas is between about 10 and about 30 percent of the compressed flue gas.

8. The hybrid post combustion carbon dioxide capture system of claim 6 , wherein the first portion of the compressed flue gas is about 20% of the compressed flue gas.

9. A method of capturing carbon dioxide from a flue gas, comprising:
compressing the flue gas into a compressed flue gas stream at a compression rate determined by external electricity demand;
delivering a first portion of the flue gas stream to a membrane-based carbon dioxide separation unit;
delivering a second portion of the compressed flue gas stream to aqueous-based carbon dioxide capture unit; and
processing the compressed flue gas stream in parallel in the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit without recycling any carbon dioxide removed from the compressed flue gas stream to the compressor, the membrane-based carbon dioxide separation unit and the aqueous-based carbon dioxide capture unit.

10. The method of claim 9 , further including recovering carbon dioxide from the first portion of the compressed flue gas stream on a downstream side of a membrane adapted to recover the carbon dioxide.

11. The method of claim 10 , further including recovering the carbon dioxide from the second portion of the compressed flue gas stream in an absorber using a countercurrent flow of a carbon dioxide-lean carbon capture solvent thereby generating a carbon dioxide-rich carbon capture solvent.

12. The method of claim 11 , further including regenerating the carbon dioxide-lean carbon capture solvent by releasing and recovering the captured carbon dioxide from the carbon dioxide-rich carbon capture solvent.

13. The method of claim 12 , including compressing the compressed flue gas to a pressure of between about 2 bar and about 4 bar.

14. The method of claim 13 , including providing between about 10 and about 30 percent of the compressed flue gas in the first portion.

15. The method of claim 13 , including providing about 20% of the compressed flue gas in the first portion.

Assignees

• Univ Kentucky Res Found

Inventors

• Liu Kunlei

Classifications

• B01D53/229 Primary

  Integrated processes (Diffusion and at least one other process, e.g. adsorption, absorption) · CPC title

• B01D53/1418

  Recovery of products · CPC title

• B01D53/1425

  Regeneration of liquid absorbents · CPC title

• B01D53/1475 Primary

  Removing carbon dioxide · CPC title

• B01D53/18

  Absorbing units; Liquid distributors therefor (B01D3/16, B01D3/26, B01D3/30 take precedence; packing elements B01J19/30, B01J19/32) · CPC title