Obtaining a volatile fraction from juices or alcoholic beverages

Patent metadata

Field	Value
Publication number	US-11937622-B2
Application number	US-201817268714-A
Country	US
Kind code	B2
Filing date	Aug 17, 2018
Priority date	Aug 17, 2018
Publication date	Mar 26, 2024
Grant date	Mar 26, 2024

Abstract

The present invention relates primarily to a method for obtaining a volatile fraction from a juice and/or an alcohol-containing beverage, comprising or consisting of the following steps: (a) distilling a mixture of substances from the juice and/or the alcohol-containing beverage, wherein the distillation is performed by a spinning cone column; (b) contacting the mixture of substances from step (a) with a sorbent to obtain a loaded sorbent; and (c) contacting the loaded sorbent from step (b) with a liquid desorbent to obtain the volatile fraction, wherein desired ingredients of the volatile fraction are concentrated as compared to the juice and/or alcohol-containing beverage such that an addition of 0.1% by mass or less of the volatile fraction to any food preparation produces a perceptible odor impression and/or taste impression in a test subject.

First claim

The invention claimed is:

1. A method for obtaining a volatile fraction of concentrated aroma, flavor, and/or fragrance compounds from an ethanol-containing juice or beverage comprising ethanol and the aroma, flavor, and/or fragrance compounds, the method comprising:
(a) obtaining a distillate from the ethanol-containing juice or beverage by subjecting the ethanol-containing juice or beverage to spinning cone column distillation, wherein the distillate comprises the aroma, flavor, and/or fragrance compounds;
(b) contacting the distillate of (a) with a sorbent to obtain a loaded sorbent; and
(c) recovering a volatile fraction containing the aroma, flavor, and/or fragrance compounds from the loaded sorbent of (b) by thermal desorption at a temperature of 90 to 200° C. using a desorbent of ethanol-free water vapor containing less than 5% by mass of organic compounds other than ethanol,
wherein the aroma, flavor, and/or fragrance compounds in the volatile fraction of (c) are concentrated compared to the ethanol-containing juice or beverage such that a ratio of ethanol in the volatile fraction to a sum of aroma, flavor, and/or fragrance compounds in the volatile fraction (V(E/A)) is 0.1 to 20, and
addition of 0.001 to 0.1% by mass of the volatile fraction to a food preparation produces a perceptible odor impression and/or taste impression.

2. The method according to claim 1 , wherein the spinning cone column distillation is carried out in the form of a countercurrent distillation at a pressure of 1 to 500 mbar.

3. The method according to claim 2 , wherein the countercurrent distillation is carried out with an inert gas.

4. The method according to claim 1 , wherein the spinning cone column distillation is carried out using a strip ratio in the range of 1:1 to 10:1.

5. The method according to claim 1 , wherein the ethanol-containing juice or beverage is maintained at a temperature of 28 to 70° C. for spinning cone column distillation.

6. The method according to claim 1 , wherein the sorbent is a porous solid, which is surface-modified with organic residues.

7. The method according to claim 1 , wherein the ethanol-containing juice or beverage is:
a juice selected from fruit juice, berry juice, vegetable juice, or mixture thereof; or
an alcoholic beverage selected from wine, wine-containing beverages, beer, beer-containing beverages, or mixtures thereof.

8. The method according to claim 3 , wherein the inert gas is nitrogen.

9. The method according to claim 1 , wherein the sorbent is a polystyrene.

10. The method according to claim 9 , wherein the ethanol-containing juice or beverage is a fruit juice, a berry juice, a vegetable juice, or mixture thereof, selected from lemon juice, orange juice, tangerine juice, clementine juice, grapefruit juice, lime juice, kumquat juice, tangor juice, tangelo juice, melon juice, kiwi juice, papaya juice, avocado juice, acerola juice, bearberry juice, blackberry juice, blueberry juice, boysenberry juice, cherry juice, virgin grape cherry juice, cloudberry juice, red currant juice, black currant juice, date juice, scratch berry ( Rubus caesius ) juice, elderberry juice, grape juice, gooseberry juice, huckleberry juice, loganberry juice, olallieberry juice, mulberry juice, raisin juice, plains berry juice, prairie berry juice, cranberry juice, raspberry juice, pear juice, splendid raspberry ( Rubus spectabilis ) juice, sea buckthorn fruit juice, sloe fruit juice, strawberry juice, white cinnamon raspberry ( Rubus parviflorus ) juice, buckthorn fruit juice, grape berry juice, blueberry juice, apple juice, rhubarb juice, passion fruit juice, plum juice, apricot juice, nectarine juice, quince juice, kiwi juice, star fruit juice, lychee juice, pineapple juice, guava juice, papaya juice, passion fruit juice, mango juice, peach juice, carrot juice, tomato juice, cucumber juice, radish juice, beet juice, sauerkraut juice, celery juice, and spinach juice, or a mixture thereof.

11. The method of claim 1 , wherein the ratio of the ethanol contained in the volatile fraction to the sum of the aroma, flavor, and/or fragrance compounds in the volatile fraction (V(E/A)) is 0.5 to 20.

12. The method of claim 1 , wherein the ratio of the ethanol contained in the volatile fraction to the sum of the aroma, flavor, and/or fragrance compounds in the volatile fraction (V(E/A)) is 1 to 15.

13. A method for obtaining a volatile fraction of concentrated aroma, flavor, and/or fragrance compounds from an ethanol-containing juice or beverage comprising ethanol and the aroma, flavor, and/or fragrance compounds, the method comprising:
(a) obtaining a distillate from the ethanol-containing juice or beverage by subjecting the ethanol-containing juice or beverage to spinning cone column distillation, wherein the distillate comprises the aroma, flavor, and/or fragrance compounds;
(b) contacting the distillate of (a) with a sorbent to obtain a loaded sorbent; and
(c) recovering a volatile fraction containing the aroma, flavor, and/or fragrance compounds from the loaded sorbent of (b) by thermal desorption at a temperature of 90 to 200° C. using an ethanol-free desorbent of water vapor containing less than 5% by mass of organic compounds other than ethanol,
wherein the aroma, flavor, and/or fragrance compounds in the volatile fraction of (c) are concentrated compared to the ethanol-containing juice or beverage such that a ratio of ethanol in the volatile fraction to a sum of the aroma, flavor, and/or fragrance compounds in the volatile fraction (V(E/A)) is 0.5 to 20, and
addition of 0.005 to 0.05% by mass of the volatile fraction to a food preparation produces a perceptible odor impression and/or taste impression.

14. The method according to claim 13 , wherein the spinning cone column distillation is carried out in the form of a countercurrent distillation at a pressure of 1 to 500 mbar.

15. The method according to claim 13 , wherein the countercurrent distillation is carried out with an inert gas.

16. The method according to claim 15 , wherein the inert gas is nitrogen.

17. The method according to claim 13 , wherein the spinning cone column distillation is carried out using a strip ratio in the range of 1:1 to 10:1.

18. The method according to claim 13 , wherein the ethanol-containing juice or beverage is maintained at a temperature of 28 to 70° C. for spinning cone column distillation.

19. The method according to claim 13 , wherein the sorbent is a porous solid, which is surface-modified with organic residues.

20. The method according to claim 13 , wherein the ethanol-containing juice or beverage is:
a juice selected from fruit juice, berry juice, and vegetable juice, or mixture thereof; or
an alcoholic beverage selected from wine, wine-containing beverages, beer, beer-containing beverages, or mixtures thereof.

21. The method according to claim 20 , wherein the ethanol-containing juice or beverage is a fruit juice, a berry juice, a vegetable juice, or mixture thereof, selected from lemon juice, orange juice, tangerine juice, clementine juice, grapefruit juice, lime juice, kumquat juice, tangor juice, tangelo juice, melon juice, kiwi juice, papaya juice, avocado juice, acerola juice, bearberry juice, blackberry juice, blueberry juice, boysenberry juice, cherry juice, virgin grape cherry juice, cloudberry juice, red currant juice, black currant juice, date juice, scratchberry ( Rubus caesius ) juice, elderberry juice, grape juice, gooseberry juice, huckleberry juice, loganberry juice, olallieberr

Assignees

• Symrise Ag

Inventors

• Kiefl Johannes
• Winkler Dominik
• Brennecke Stefan
• Hilmer Jens Michael
• Kindel Alexander

Classifications

• A23L2/80 Primary

  by adsorption · CPC title

• A23L2/02

  containing fruit or vegetable juices · CPC title

• A23L2/385

  Concentrates of non-alcoholic beverages · CPC title

• A23L2/56

  Flavouring or bittering agents (sweeteners A23L2/60) · CPC title

• A23L2/64

  Re-adding volatile aromatic ingredients · CPC title