Electrochemical cells and methods of manufacturing thereof

Patent metadata

Field	Value
Publication number	US-11936004-B2
Application number	US-202217587644-A
Country	US
Kind code	B2
Filing date	Jan 28, 2022
Priority date	Jan 28, 2022
Publication date	Mar 19, 2024
Grant date	Mar 19, 2024

Abstract

An electrochemical cell includes a housing, a positive electrode substrate disposed within a first electrode chamber of the housing, a negative electrode substrate disposed within a second electrode chamber of the housing, and a separator may be disposed within the housing between the first electrode chamber and the second electrode chamber. A method further includes pumping a manufacturing electrolyte through the positive electrode portion around the positive electrode substrate. The method further includes applying a first electrical signal to the positive electrode substrate so as to electrochemically fabricate one or both of an active material the negative electrode substrate to form a negative electrode and/or an active material on the positive electrode substrate, thereby forming a positive electrode.

First claim

What is claimed is:

1. A method, comprising;
providing an electrochemical cell comprising:
a housing,
a negative electrode substrate disposed within a first electrode chamber of the housing,
a positive electrode substrate disposed within a second electrode chamber of the housing, and
a separator disposed within the housing between the first electrode chamber and the second electrode chamber;

passing a first manufacturing electrolyte and a second manufacturing electrolyte through the electrochemical cell simultaneously by:
pumping the first manufacturing electrolyte through the first electrode chamber around the negative electrode substrate; and
pumping the second manufacturing electrolyte through the second electrode chamber around the positive electrode substrate;

applying a first electrical signal to the electrochemical cell; and
electrochemically fabricating a negative active material on the negative electrode substrate, thereby forming a negative electrode and electrochemically fabricating a positive active material on the positive electrode substrate, thereby forming a positive electrode.

2. The method of claim 1 , wherein the positive electrode substrate comprises one or more of lead, carbon, titanium, platinum, or silicon in a concentration in a range of 0.01% to 99.99%.

3. The method of claim 1 , further comprising, after formation of the negative electrode and the positive electrode, pumping a first charge operation electrolyte at a first charge operation concentration at a first charge operation flow rate through the first electrode chamber and pumping a second charge operation electrolyte at a second charge operation concentration at a second charge operation flow rate through the second electrode chamber.

4. The method of claim 3 , further comprising, after formation of the negative electrode and the positive electrode, pumping a first discharge operation electrolyte at a first discharge operation concentration at a first discharge operation flow rate through the first electrode chamber and pumping a second discharge operation electrolyte at a second discharge operation concentration at a second discharge operation flow rate through the second electrode chamber.

5. The method of claim 4 , further comprising pumping a first regeneration electrolyte through the first electrode chamber, wherein the first regeneration electrolyte is configured to remove spent active material from the negative electrode substrate.

6. The method of claim 5 , further comprising pumping a second regeneration electrolyte through the second electrode chamber, wherein the second regeneration electrolyte is configured to remove spent active material from the positive electrode substrate.

7. The method of claim 6 , wherein the first regeneration electrolyte and/or the second regeneration electrolyte that comprises one or more of sulfuric acid or acetic acid having a concentration in a range of 0.01% to 99.99%.

8. The method of claim 7 , further comprising:
subsequent to removal of the spent active material from the negative electrode substrate, pumping the first manufacturing electrolyte through the first electrode chamber around the negative electrode so as to refabricate the active material/electrode substrate on the negative electrode substrate; and
applying a second electrical signal to the positive electrode substrate.

9. The method of claim 8 , further comprising:
subsequent to removal of the spent active material from the positive electrode substrate, pumping the second manufacturing electrolyte through the second electrode chamber around the positive electrode so as to refabricate the active material/electrode substrate on the positive electrode substrate; and
applying a third electrical signal to the positive electrode substrate.

10. The method of claim 9 , wherein the first charge concentration and the first discharge concentration are in a range of 0.05 M to 10 M of sulfuric acid and the first charge concentration differs from the first discharge concentration.

11. The method of claim 10 , wherein the first charge flow rate and the first discharge flow rate are in a range of 0.001 to 100 liter/minute/cm 2 .

12. The method of claim 1 , wherein at least one of the first manufacturing electrolyte or the second manufacturing electrolyte comprises one or more of sulfuric acid, nitric acid, or methane sulfonic acid in a concentration in a range of 0.01% to 99.99%.

13. The method of claim 1 , wherein at least one of the first manufacturing electrolyte or the second manufacturing electrolyte comprises lead ions in a concentration in a range of 0.1 mM to 0.1 M.

14. An electrochemical cell assembly comprising:
an electrochemical cell, comprising:
a housing;
a negative electrode substrate disposed within a first electrode chamber of the housing;
a positive electrode substrate disposed within a second electrode chamber of the housing;
a pumping assembly; and
a plurality of electrolyte reservoirs, each of the plurality of electrolyte reservoirs having an electrolyte associated therewith, the pumping assembly configured to pump a plurality of electrolytes through the housing of the electrochemical cell,
wherein the plurality of electrolytes comprises:
a manufacturing electrolyte formulated to electrochemically fabricate an active material on one or both of the positive electrode substrate and the negative electrode substrate;
a first charge operation electrolyte having a first charge concentration; and
a first discharge operation electrolyte having a first discharge concentration different from the first charge concentration.

15. The electrochemical cell assembly of claim 14 , wherein the active material is Pb or PbO 2 .

16. The electrochemical cell assembly of claim 14 , wherein the manufacturing electrolyte comprises one or more of sulfuric acid, nitric acid, or methane sulfonic acid having a concentration in a range of 0.01% to 99.99%.

17. The electrochemical cell assembly of claim 14 , wherein the manufacturing electrolyte comprises lead ions having a concentration in a range of 0.1 mM to 1 M.

18. The electrochemical cell assembly of claim 14 , wherein the plurality of electrolytes further comprises a regeneration electrolyte configured to remove a spent active material.

19. The electrochemical cell assembly of claim 18 , wherein the regeneration electrolyte comprises water-based mixtures that comprise one or more of sulfuric acid or acetic acid having a concentration in a range of 0.01% to 99.99%.

20. The electrochemical cell assembly of claim 14 , wherein the first charge operation electrolyte and the first discharge operation electrolyte comprise sulfuric acid.

21. The electrochemical cell assembly of claim 20 , wherein the first charge concentration and the first discharge concentration are in a range of 0.05 M to 10 M of sulfuric acid.

Assignees

• Uchicago Argonne Llc

Inventors

• Lopes Pietro Papa
• Fister Timothy
• Babinec Susan J
• Stamenkovic Vojislav

Classifications

• H01M10/4242 Primary

  Regeneration of electrolyte or reactants · CPC title

• H01M10/128

  Processes for forming or storing electrodes in the battery container · CPC title

• H01M10/44 Primary

  Methods for charging or discharging (circuits for charging H02J7/00) · CPC title

• Y02E60/10

  Energy storage using batteries · CPC title

• H01M10/06

  Lead-acid accumulators (semi-lead accumulators H01M10/20) · CPC title