Solvent-based compostable cold seal release lacquer

Patent metadata

Field	Value
Publication number	US-11932776-B2
Application number	US-202118000316-A
Country	US
Kind code	B2
Filing date	Jun 30, 2021
Priority date	Jun 30, 2020
Publication date	Mar 19, 2024
Grant date	Mar 19, 2024

Abstract

The present invention provides solvent-based compostable cold seal release lacquers for use in packaging structures. The lacquers of the invention comprise resins, such as polyamide resins, comprising greater than 90% biobased carbon, generally prepared from renewable sources, e.g., plants such as rice. The present invention also provides the use of the inventive compostable lacquers as cold seal release lacquers in cold seal packaging, along with eco-friendly packaging film, etc., and has the potential to make the cold seal packaging fully compostable.

First claim

The invention claimed is:

1. A solvent-based cold seal release lacquer comprising:
a) one or more solvents;
b) from 20 wt % to 70 wt % of one or more polyamide resins comprising greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products; and
c) from 0.25 wt % to 5 wt % of one or more waxes, wherein the one or one or more waxes comprise greater than 70% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products;

wherein the cold seal release lacquer has a static coefficient of friction (CoF static ) of 0.35-0.50; a kinetic coefficient of friction (CoF kinetic ) of 0.20-0.35; wherein the cold seal release lacquer, when dried, comprises greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products and meets the ASTM D6400 standard for compostability, wherein equal to or greater than 90% of the biobased carbon converts to CO 2 within 180 days of composting; and wherein the cold seal release lacquer comprises from 0 to 1 wt % water.

2. The cold seal release lacquer according to claim 1 wherein the one or more solvents are chosen from the group consisting of alcohols, aliphatic solvents, glycol ethers and blends thereof.

3. The cold seal release lacquer according to claim 1 , wherein the one or more polyamide resins are derived from rice oil or rice bran and/or wherein the one or more polyamide resins are compostable.

4. A structure comprising a substrate, a cohesive and a solvent-based cold seal release lacquer comprising:
a) one or more solvents;
b) from 20 wt % to 70 wt % of one or more polyamide resins comprising greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products; and
c) from 0.25 wt % to 5 wt % of one or more waxes;

wherein the cold seal release lacquer has a static coefficient of friction (CoF static ) of 0.35-0.50; a kinetic coefficient of friction (CoF kinetic ) of 0.20-0.35; wherein the cold seal release lacquer, when dried, comprises greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products and meets the ASTM D6400 standard for compostability, wherein equal to or greater than 90% of the biobased carbon converts to CO 2 within 180 days of composting; and wherein the cold seal release lacquer comprises from 0 to 1 wt % water.

5. The structure according to claim 4 , wherein the substrate is printed with an ink, either directly onto a surface of the substrate or onto a primer layer adhering to a surface of the substrate.

6. The structure according to claim 4 , wherein the substrate is a film.

7. The structure according to claim 6 , wherein the substrate is a cellulosic film.

8. The structure according to claim 5 , wherein the substrate, the ink and the cohesive are also compostable.

9. The structure according to claim 5 , wherein a laminating substrate is positioned over the ink.

10. The structure according to claim 9 , wherein the cold seal release lacquer is positioned over the laminating substrate.

11. The structure according to claim 4 , wherein the cold seal release lacquer and the cohesive can form a bond sealing two portions of the substrate under ambient conditions, wherein the strength of the bond, after being aged for 4-weeks at 120° F., 80% RH and 50 PSI, is at least 80% of the value of the bond when formed, as measured by an air driven piston Block Tester.

12. The structure according to claim 9 , wherein the entire structure is compostable.

13. A method of providing a compostable cold seal structure comprising the steps of: applying a compostable adhesive to a surface of a compostable packaging substrate, and applying a solvent-based compostable cold seal release lacquer to a second surface of the same substrate or a surface of a second compostable packaging substrate, wherein the cohesive and compostable cold seal release lacquer form a seal under pressure, which seal is readily opened, wherein a solvent-based compostable cold seal release lacquer comprises:
a) one or more solvents;
b) from 20 wt % to 70 wt % of one or more polyamide resins comprising greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products; and
c) from 0.25 wt % to 5 wt % of one or more waxes;

wherein the cold seal release lacquer has a static coefficient of friction (CoF static ) of 0.35-0.50; a kinetic coefficient of friction (CoF kinetic ) of 0.20-0.35; wherein the cold seal release lacquer, when dried, comprises greater than 90% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products and meets the ASTM D6400 standard for compostability, wherein equal to or greater than 90% of the biobased carbon converts to CO 2 within 180 days of composting; and wherein the cold seal release lacquer comprises from 0 to 1 wt % water.

14. The structure according to 4 , wherein the one or more solvents are chosen from the group consisting of alcohols, aliphatic solvents, glycol ethers and blends thereof.

15. The structure according to 14 , wherein the one or more polyamide resins are derived from rice oil or rice bran and/or wherein the one or more polyamide resins are compostable.

16. The structure according to claim 14 , wherein the one or one or more waxes comprise greater than 70% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products.

17. The method of claim 13 , wherein the one or more solvents of the solvent-based compostable cold seal release lacquer are chosen from the group consisting of alcohols, aliphatic solvents, glycol ethers and blends thereof.

18. The method of claim 13 , wherein the one or more polyamide resins are derived from rice oil or rice bran and/or wherein the one or more polyamide resins are compostable.

19. The method of claim 13 , wherein the one or one or more waxes comprise greater than 70% biobased carbon, reported as a percentage of the total carbon that is carbon derived from plant or animal by-products.

20. The cold seal release lacquer according to claim 1 wherein the cold seal release lacquer comprises an adhesion promoter.

21. The cold seal release lacquer according to claim 20 , wherein the adhesion promoter is present in an amount of 0.2-0.85 wt %.

22. The cold seal release lacquer according to claim 20 , wherein the adhesion promoter comprises a phosphate modified isopropyl titanate.

Assignees

• Sun Chemical Corp

Inventors

• Boyd Craig
• Chavez Gina
• Fagan Mackensey

Classifications

• C09D193/00 Primary

  Coating compositions based on natural resins; Coating compositions based on derivatives thereof (based on polysaccharides C09D101/00 - C09D105/00; based on natural rubber C09D107/00; polishing compositions C09G) · CPC title

• C09D7/20

  Diluents or solvents · CPC title

• C09D7/65

  macromolecular (C09D7/41-C09D7/48 take precedence) · CPC title

• C09D17/00

  Pigment pastes, e.g. for mixing in paints (artists' paints C09D5/06) · CPC title

• C09J7/201 Primary

  characterised by the release coating composition on the carrier layer · CPC title