Absorbent Article Containing Nanoporous Superabsorbent Particles
US-2020188195-A1 · Jun 18, 2020 · US
US11931469B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11931469-B2 |
| Application number | US-201816631885-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 20, 2018 |
| Priority date | Jul 28, 2017 |
| Publication date | Mar 19, 2024 |
| Grant date | Mar 19, 2024 |
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An absorbent article comprising an absorbent member positioned between a topsheet and a backsheet is provided. The absorbent member contains at least one layer that comprises porous superabsorbent particles, wherein the particles exhibit a relative humidity microclimate of about 67% or less after being exposed to an atmosphere having a temperature of about 23° C. and relative humidity of 80% for a time period of 20 minutes.
Opening claim text (preview).
What is claimed is: 1. An absorbent article comprising an absorbent member positioned between a topsheet and a backsheet, wherein the absorbent member contains at least one layer that comprises porous superabsorbent particles, wherein the particles contain a porous network that includes a plurality of nanopores and wherein the nanopores have an average cross-sectional dimension of from 10 to 500 nanometers, wherein the percent porosity of the particles is greater than 5%, wherein the particles have a total pore area of greater than 2 m 2 /g, wherein the absorbent member comprises a fibrous material, wherein an average percent volume occupied by the nanopores within a given unit volume of the fibrous material is from 15% to 80% per cm3, wherein the particles exhibit a relative humidity microclimate of 67% or less after being exposed to an atmosphere having a temperature of 23° C. and relative humidity of 80% for a time period of 20 minutes. 2. The absorbent article of claim 1 , wherein the layer further contains a fibrous material. 3. The absorbent article of claim 2 , wherein the fibrous material includes absorbent fibers, synthetic polymer fibers, or a combination thereof. 4. The absorbent article of claim 3 , wherein the absorbent fibers contain pulp fibers. 5. The absorbent article of claim 3 , wherein the synthetic polymer fibers include meltblown fibers. 6. The absorbent article of claim 1 , wherein the superabsorbent particles are mixed into a matrix of the fibrous material. 7. The absorbent article of claim 1 , wherein the superabsorbent particles constitute from 20 wt. % to 90 wt. % of the layer of the absorbent member. 8. The absorbent article of claim 1 , wherein the superabsorbent particles exhibit an Absorption Rate of 300 g/g/ks or more after being placed into contact with an aqueous solution of 0.9 wt. % sodium chloride for 0.015 kiloseconds. 9. The absorbent article of claim 1 , wherein the superabsorbent particles exhibit a Vortex Time of 80 seconds or less. 10. The absorbent article of claim 1 , wherein the particles exhibit an Absorption Rate of 600 to 1,500 g/g/ks or more after being placed into contact with an aqueous solution of 0.9 wt. % sodium chloride for 0.015 kiloseconds. 11. The absorbent article of claim 1 , wherein the superabsorbent particles exhibit a total absorbent capacity of 10 g/g or more after being placed into contact with an aqueous solution of 0.9 wt. % sodium chloride for 3.6 kiloseconds. 12. The absorbent article of claim 1 , wherein the particles exhibit a Centrifuge Retention Capacity of 20 g/g or more. 13. The absorbent article of claim 1 , wherein the particles exhibit a relative humidity microclimate of 67% or less after being exposed to an atmosphere having a temperature of 23° C. and relative humidity of 80% for a time period of from 20 minutes to 150 minutes. 14. The absorbent article of claim 1 , wherein the porous network further comprises micropores. 15. The absorbent article of claim 1 , wherein at least 25 vol. % of the porous network is formed by the nanopores. 16. The absorbent article of claim 1 , wherein the particles are formed from a crosslinked polymer that contains repeating units derived from one or more ethylenically unsaturated monomeric compounds having at least one hydrophilic radical. 17. The absorbent article of claim 16 , wherein the monomeric compounds are monoethylenically unsaturated. 18. The absorbent article of claim 16 , wherein the hydrophilic radical includes a carboxyl, carboxylic acid anhydride, carboxylic acid salt, sulfonic acid, sulfonic acid salt, hydroxyl, ether, amide, amino, quaternary ammonium salt group, or a combination thereof. 19. The absorbent article of claim 16 wherein the polymer contains repeating units derived from a (meth)acrylic acid monomeric compound or a salt thereof. 20. The absorbent article of claim 16 , wherein the polymer contains an alkoxysilane functionality. 21. The absorbent article of claim 1 , wherein the particles have a median size of from 50 to 2,000 micrometers. 22. The absorbent article of claim 1 , wherein the particles have a specific surface area of 0.2 square meters per gram or more as determined in accordance with ISO 9277:2010. 23. The absorbent article of claim 1 , wherein the absorbent member contains an absorbent core that includes the superabsorbent particles. 24. The absorbent article of claim 23 , wherein the absorbent member further contains a surge layer positioned adjacent to the absorbent core. 25. The absorbent article of claim 24 , wherein a wrapsheet covers the absorbent core.
Porous materials, e.g. foams or sponges · CPC title
characterised by the absorbing medium (A61F13/20 takes precedence) · CPC title
the layer having a promotional function on liquid propagation in the vertical direction · CPC title
containing macromolecular materials · CPC title
containing organic materials · CPC title
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