Stable, non-corrosive electrolyte with high performance for rechargeable ion batteries

Patent metadata

Field	Value
Publication number	US-11929462-B2
Application number	US-202117153209-A
Country	US
Kind code	B2
Filing date	Jan 20, 2021
Priority date	Jan 21, 2020
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

Described herein are compounds and compositions for electrolytes based on bidentate and monodentate fluorinated alcohols. Also described are batteries that include the compounds and electrolytes described herein.

First claim

What is claimed is:

1. A salt of formula (Ia):

wherein:
each R 1 and R 2 are independently selected from the group consisting of H, F, a C 1 -C 10 alkyl, a C 1 -C 10 fluoroalkyl, and a phenyl that is optionally substituted with 1-5 substituents each independently selected from the group consisting of F, a C 1 -C 10 alkyl, and a C 1 -C 10 fluoroalkyl;
M is boron;
a is 1 or 2; and
X is magnesium.

2. An electrolyte comprising:
a solvent comprising an ether, an organic carbonate, a lactone, a ketone, a glyme, a nitrile, an aliphatic hydrocarbon solvent, an aromatic hydrocarbon solvent, an organic nitro solvent, an organosulfur compound, or combinations thereof; and
a salt of formula (Ia):

wherein:
each R 1 and R 2 are independently selected from the group consisting of H, F, a C 1 -C 10 alkyl, a C 1 -C 10 fluoroalkyl, and a phenyl that is optionally substituted with 1-5 substituents each independently selected from the group consisting of F, a C 1 -C 10 alkyl, and a C 1 -C 10 fluoroalkyl;
M is boron;
a is 1 or 2; and
X is magnesium, sodium, potassium, calcium, or zinc.

3. The electrolyte of claim 2 , wherein X is magnesium.

4. The electrolyte of claim 2 , wherein the solvent comprises tetrahydrofuran, 2-methyl tetrahydrofuran, dimethoxyethane, glyme, monoglyme, diglyme, triglyme, tetraglyme, diethoxyethane, diethylether, proglyme, ethyl diglyme, butyl diglyme, dimethylsulfoxide, dimethylsulfite, sulfolane, ethyl methyl sulfone, acetonitrile, hexane, toluene, nitromethane, 1-3 dioxalane, 1-4 dioxane, trimethyl phosphate, tri-ethyl phosphate, hexa-methyl-phosphoramide (HMPA), dimethyl glycol, ethylene glycol dimethyl ether, diethyl ether, or combinations thereof.

5. The electrolyte of claim 2 , wherein the solvent comprises at least one of dimethoxyethane, diglyme, ethyl diglyme, or butyl diglyme.

6. The electrolyte of claim 2 , wherein a concentration of the compound is from about 0.01 M to about 1 M.

7. The electrolyte of claim 6 , wherein the concentration of the compound is about 0.5 M.

8. The electrolyte of claim 2 , wherein the electrolyte has an anodic stability of greater than or equal to 2.0 Volts versus an alkali metal or alkaline earth metal which is the same as the alkali metal or alkaline earth metal of X in the compound of formula (Ia).

9. The electrolyte of claim 2 , wherein the solution has an anodic stability of greater than or equal to 4.0 Volts versus magnesium.

10. The electrolyte of claim 2 , wherein the electrolyte has a Coulombic efficiency greater than 70%.

11. The electrolyte of claim 2 , wherein the electrolyte has a Coulombic efficiency greater than 95%.

12. A battery comprising:
the electrolyte of claim 2 ;
a cathode; and
an anode comprising an anode active material comprising a metal selected from the group consisting of an alkali metal, an alkaline earth metal, and zinc;
where the metal is the same as X in the compound of formula (Ia).

13. The battery of claim 12 , wherein the cathode comprising an active material selected from the group consisting of sulfur, graphitic carbon, carbon fiber, glassy carbon, pyrolitic carbon, amorphous carbon, mesoporous carbon, carbon nanotubes, organic polymers, Mo 6 S 8 , MnO 2 , CuS, Cu 2 S, Ag 2 S, CrS 2 , VOPO 4 , TiS 2 , V 2 O 5 , MgVO 3 , MoS 2 , MgV 2 O 5 , MoO 3 , CuCr 2 S 4 , MgCr 2 S 4 , MgMn 2 O 4 , Mg 2 MnO 4 , MgFe 2 (PO 4 ) 3 , MgV 2 (PO 4 ) 3 , MgMnSiO 4 , MgFe 2 (PO 4 ) 2 , Mg 0.5 VPO 4 F, TiP 2 O 7 , VP 2 O 7 , and FeF 3 .

Assignees

• Liu Tianbiao
• Luo Jian
• Zhang Liping
• Univ Utah State

Inventors

• Liu Tianbiao
• Luo Jian
• Zhang Liping

Classifications

• H01M10/0568 Primary

  characterised by the solutes · CPC title

• H01M4/133

  Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx · CPC title

• H01M4/134

  Electrodes based on metals, Si or alloys · CPC title

• H01M4/136

  Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy · CPC title

• H01M10/054

  Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium · CPC title