Control Heat of Hydration by Characterizing Cementitious Components
US-2019330513-A1 · Oct 31, 2019 · US
US11926787B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11926787-B2 |
| Application number | US-202016854376-A |
| Country | US |
| Kind code | B2 |
| Filing date | Apr 21, 2020 |
| Priority date | Jun 24, 2019 |
| Publication date | Mar 12, 2024 |
| Grant date | Mar 12, 2024 |
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A well cementing method is described for improving cementing quality by controlling the hydration heat of cement slurry. By controlling the degree and/or rate of hydration heat release from cement slurry, the method improves the hydration heat release during formation of cement with curing of cement slurry, improves the binding quality between the cement and the interfaces, and in turn improves the cementing quality at the open hole section and/or the overlap section. The cementing method improves cementing quality of oil and gas wells and reduces the risk of annular pressure.
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The invention claimed is: 1. A well cementing method for improving cementing quality of a well, comprising: controlling the hydration heat of cement slurry to control the degree and rate of hydration heat release from the cement slurry, wherein the method improves the hydration heat release during formation of cement with curing of cement slurry, improves the binding quality between the cement and the interfaces, and in turn improves the cementing quality at an overlap section of a well; wherein when the controlling is achieved the cementing quality at the overlap section is improved; wherein lowering the degree of hydration heat release from cement slurry is achieved by reducing the addition amount of a material generating a high hydration heat; wherein lowering the rate of hydration heat release from cement slurry is achieved by adding a retarder; wherein the well cementing is performed on a short-overlap-section well having a length of the overlap section not greater than 150 m; wherein for well cementing with a separable setting cement slurry comprising a lead slurry and a tail slurry, wherein for the lead slurry, controlling of hydration heat is achieved by lowering the degree and rate of hydration heat release from the slurry, wherein the lead slurry is cement slurry with high strength and low elastic modulus, and its additional safety time for thickening is 60-300 minutes; and wherein for the tail slurry, controlling of hydration heat is achieved by increasing the degree and rate of hydration heat release from the slurry, wherein the tail slurry is cement slurry with high strength, and its additional safety time for thickening is 30-60 minutes; wherein the high strength occurs when the 7-day strength is greater than 28 MPa, and the low elastic modulus occurs when the elastic modulus is less than 10 GPa. 2. The well cementing method according to claim 1 , wherein increasing the degree of hydration heat release from cement slurry is achieved by adding a material generating a high hydration heat to cement slurry. 3. The well cementing method according the claim 2 , wherein the material generating a high hydration heat includes an accelerating early strength agent. 4. The well cementing method according to claim 3 , wherein the accelerating early strength agent includes one of, or a combination of two or more of: sodium chloride, sodium carbonate, sodium formate, sodium nitrite, calcium chloride, calcium formate, calcium sulfate, calcium metasilicate, sodium aluminate, metakaolin, magnesium trisilicate, magnesium oxide, strontium sulfate, strontium carbonate, strontium nitrate, lithium carbonate, gypsum, hemihydrate gypsum, dihydrate gypsum, magnesium oxide, calcium oxide, activated slag, and ultra-fine cement. 5. The well cementing method according to claim 1 , wherein increasing the rate of hydration heat release from cement slurry is achieved by shortening the additional safety time for thickening of cement slurry. 6. The well cementing method according to claim 1 , wherein the retarder includes an AMPS-based retarder. 7. The well cementing method according claim 1 , wherein the cement component in the cement slurry is one of or a combination of two or more of: class A oil well cement, class B oil well cement, class C oil well cement, class D oil well cement, class E oil well cement, class F oil well cement, class G oil well cement, class H oil well cement, and class J oil well cement. 8. The well cementing method according to claim 7 , wherein the cement slurry further contains one of or a combination of two or more of: a toughening agent, a fluid loss additive, a dispersant, a defoaming agent, a fleeing-proof agent, silica, and water. 9. The well cementing method according to claim 1 , wherein for well cementing with single setting cement slurry, controlling of hydration heat is achieved by lowering the degree and rate of hydration heat release from the cement slurry; wherein the cement slurry is cement slurry with high strength and low elastic modulus, and its additional safety time for thickening is 60-300 minutes; for well cementing with multi-setting cement slurry comprising a lead slurry, an intermediate slurry and a tail slurry, wherein for the lead slurry, controlling of hydration heat is achieved by lowering the degree and rate of hydration heat release from the slurry, wherein the lead slurry is cement slurry with high strength and low elastic modulus, and its additional safety time for thickening is 60-300 minutes; wherein for the intermediate slurry, controlling of hydration heat is achieved by increasing the degree and rate of hydration heat release from the slurry, wherein the intermediate slurry is cement slurry with high strength, and its additional safety time for thickening is 60-200 minutes; and wherein for the tail slurry, controlling of hydration heat is achieved by increasing the degree and rate of hydration heat release from the slurry, wherein the tail slurry is cement slurry with high strength, and its additional safety time for thickening is 30-60 minutes. 10. A well cementing method for improving cementing quality of a well, comprising: controlling the hydration heat of cement slurry to control the degree and rate of hydration heat release from the cement slurry, wherein the method improves the hydration heat release during formation of cement with curing of cement slurry, improves the binding quality between the cement and the interfaces, and in turn improves the cementing quality at an overlap section of a well; wherein for well cementing of a well of a pure overlap section, hydration heat is controlled by lowering the degree and rate of hydration heat release from cement slurry; wherein the cement slurry is cement slurry with high strength and low elastic modulus, the additional safety time is 60-300 minutes for thickening of the lead slurry and 30-200 minutes for thickening of the tail slurry; wherein the high strength occurs when the 7-day strength is greater than 28 MPa, and the low elastic modulus occurs when the elastic modulus is less than 10 GPa. 11. A well cementing method for improving cementing quality of a well, comprising: controlling the hydration heat of cement slurry to control the degree and rate of hydration heat release from the cement slurry; wherein the method improves the hydration heat release during formation of cement with curing of cement slurry, improves the binding quality between the cement and the interfaces, and in turn improves the cementing quality at an overlap section of a well; wherein when the controlling is achieved, the cementing quality at the overlap section is improved by lowering the degree and rate of hydration heat release from cement slurry; wherein lowering the degree of hydration heat release from cement slurry is achieved by reducing the addition amount of a material generating a high hydration heat; wherein lowering the rate of hydration heat release from cement slurry is achieved by adding a retarder; wherein the well cementing is performed on a long-overlap-section well having a length of overlap section greater than 150 m; wherein for well cementing with single setting cement slurry, controlling of hydration heat is achieved by lowering the degree and/or rate of hydration heat release from the cement slurry; wherein the cement slurry is cement slurry with high strength and low elastic modulus, and its additional safety time for thickening is 60-300 minutes; for well cementing with separable setting cement slurry comprising a lead slurry and a tail slurry, wherein for the lead slurry, controlling of hydration heat is achieved by lowering the degree and/or rate of hydration heat release from the slurry,
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