Water-based pressure sensitive adhesive compositions and methods of making same

Patent metadata

Field	Value
Publication number	US-11926770-B2
Application number	US-201616325085-A
Country	US
Kind code	B2
Filing date	Aug 12, 2016
Priority date	Aug 12, 2016
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

Disclosed is a composition comprising at least one interpolymer dispersed within an aqueous medium, the interpolymer comprising at least one unsaturated monomer and at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof, and, optionally, at least one surfactant configured to stabilize the interpolymer within the aqueous medium. The conjugated acid may be derived from a naturally-occurring oil, such as tung oil. There is also provided a method for preparing a composition, comprising forming an interpolymer comprising the at least one unsaturated monomer and the at least one selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof. There is still further provided a pressure sensitive adhesive comprising the composition prepared according to the disclosed method.

First claim

The invention claimed is:

1. A water-based adhesive composition, comprising:
at least one interpolymer dispersed within an aqueous medium, the interpolymer consisting of (i) at least one acrylate selected from the group consisting of butyl acrylate, ethylhexyl acrylate, ethyl acrylate, methyl acrylate, octyl acrylate, isooctyl acrylate, decyl acrylate, isodecyl acrylate, lauryl acrylate and cyclohexyl acrylate methacrylates such as methyl methacrylate, isobutyl methacrylate, octyl methacrylate, isooctyl methacrylate, decyl methacrylate, isodecyl methacrylate, lauryl methacrylate, pentadecyl methacrylate, stearyl methacrylate, C 12 to C 18 alkyl methacrylates and cyclohexyl methacrylate, and (ii) optionally acrylic acid, and at least one compound selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof;
wherein the at least one conjugated acid comprises an unsaturated fatty acid having at least three conjugated double bonds,
wherein the unsaturated fatty acid is an unsaturated fatty acid derivable from tung oil, wherein the at least one conjugated acid is present in the emulsified mixture from 0.01 to 2 weight percent; and
wherein the tung oil comprises a fatty acid including α-eleostearic acid.

2. The water-based adhesive composition of claim 1 , wherein the at least one acrylate is selected from the group consisting of 2-ethylhexyl acrylate, ethyl acrylate, butyl acrylate, methyl (meth)acrylate, (meth)acrylic acid, and mixtures of two or more thereof.

3. A method for preparing a water-based adhesive composition, comprising:
dispersing at least one unsaturated monomer consisting of (i) at least one acrylate selected from the group consisting of butyl acrylate, ethylhexyl acrylate, ethyl acrylate, methyl acrylate, octyl acrylate, isooctyl acrylate, decyl acrylate, isodecyl acrylate, lauryl acrylate and cyclohexyl acrylate methacrylates such as methyl methacrylate, isobutyl methacrylate, octyl methacrylate, isooctyl methacrylate, decyl methacrylate, isodecyl methacrylate, lauryl methacrylate, pentadecyl methacrylate, stearyl methacrylate, C 12 to C 18 alkyl methacrylates and cyclohexyl methacrylate, and (ii) optionally acrylic acid, and at least one surfactant in an aqueous medium to form an emulsified mixture;
introducing at least one initiator to the emulsified mixture, thereby polymerizing the at least one unsaturated monomer; and
introducing at least one compound selected from the group consisting of at least one conjugated acid, at least one mono-ester of a conjugated acid, and mixtures thereof to the emulsified mixture during polymerization of the at least one unsaturated monomer, thereby forming an interpolymer comprising the at least one unsaturated monomer and the at least one ester;
wherein the at least one conjugated acid comprises an unsaturated fatty acid having at least three conjugated double bonds,
wherein the unsaturated fatty acid is an unsaturated fatty acid derivable from tung oil, wherein the at least one conjugated acid is present in the emulsified mixture from 0.01 to 2 weight percent, wherein the at least one conjugated acid is introduced to the emulsified mixture after at least 90% of the at least one unsaturated monomer is introduced to the aqueous medium; and
wherein the tung oil comprises a fatty acid including α-eleostearic acid.

4. A water-based pressure sensitive adhesive comprising the adhesive composition prepared according to claim 3 .

Assignees

• Rohm & Haas
• Dow Global Technologies Llc

Inventors

• Zhang Jiguang
• Yang Miao
• Feng Shaoguang
• Qu Zhaohui

Classifications

• C09J7/385 Primary

  Acrylic polymers · CPC title

• C08F220/06

  Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof · CPC title

• C08F220/14

  Methyl esters {, e.g. methyl (meth)acrylate} · CPC title

• C08F220/1802

  C2-(meth)acrylate, e.g. ethyl (meth)acrylate · CPC title

• C08F220/1804

  C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate · CPC title