Chemical compounds with perfluoroaryl groups that can facilitate post-synthesis functionalization
US-2019177466-A1 · Jun 13, 2019 · US
Chemical compounds with perfluoroaryl groups that can facilitate post-synthesis functionalization
US11926693B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11926693-B2 |
| Application number | US-202117365321-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jul 1, 2021 |
| Priority date | Dec 12, 2017 |
| Publication date | Mar 12, 2024 |
| Grant date | Mar 12, 2024 |
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- Title
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Abstract
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Techniques regarding chemical compounds comprising perfluoroaryl groups that can facilitate post-synthesis functionalization are provided. For example, one or more embodiments described herein can comprise a chemical compound. The chemical compound can comprise a molecular backbone. The chemical compound can also comprise a pendent functional group bonded to the molecular backbone. The pendent functional group can comprise a perfluoroaryl group and a methylene group.
First claim
Opening claim text (preview).
What is claimed is: 1. A method comprising: functionalizing a chemical compound by covalently bonding a trimethylsilyl protected thiol to a pendent functional group of the chemical compound in presence of a catalyst, the pendent functional group comprising a perfluoroaryl group and a methylene group. 2. The method of claim 1 , further comprising: dissolving the chemical compound, the trimethylsilyl protected thiol, and the catalyst in a solvent to form a solution. 3. The method of claim 2 , further comprising: stirring the solution at a temperature greater than or equal to 10 degrees Celsius (° C.) and less than or equal to 150° C. for a period of time greater than or equal to 2 minutes and less than or equal to 48 hours. 4. The method of claim 1 , wherein the catalyst is a basic salt. 5. The method of claim 1 , wherein the chemical compound comprises a molecular backbone. 6. The method of claim 5 , wherein the molecular backbone comprises polycarbonate structure. 7. The method of claim 5 , wherein the molecular backbone comprises a polyurethane structure. 8. A method comprising: functionalizing a chemical compound by covalently bonding a trimethylsilyl protected thiol to a pendent functional group of the chemical compound in presence of a catalyst, the pendent functional group comprising a perfluorobenzyl group. 9. The method of claim 8 , further comprising: dissolving the chemical compound, the trimethylsilyl protected thiol, and the catalyst in a solvent to form a solution. 10. The method of claim 9 , further comprising: stirring the solution at a temperature greater than or equal to 10 degrees Celsius (° C.) and less than or equal to 150° C. for a period of time greater than or equal to 2 minutes and less than or equal to 48 hours. 11. The method of claim 8 , wherein the catalyst is a basic salt. 12. The method of claim 8 , wherein the chemical compound comprises a molecular backbone. 13. The method of claim 12 , wherein the molecular backbone comprises polycarbonate structure. 14. The method of claim 12 , wherein the molecular backbone comprises a polyurethane structure.
Assignees
Inventors
Classifications
- C08G18/329Primary
containing aromatic groups · CPC title
containing halogen atoms · CPC title
containing two hydroxy groups · CPC title
having fluorine atoms · CPC title
cycloaliphatic · CPC title
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- What does patent US11926693B2 cover?
- Techniques regarding chemical compounds comprising perfluoroaryl groups that can facilitate post-synthesis functionalization are provided. For example, one or more embodiments described herein can comprise a chemical compound. The chemical compound can comprise a molecular backbone. The chemical compound can also comprise a pendent functional group bonded to the molecular backbone. The pendent …
- Who is the assignee on this patent?
- IBM
- What technology area does this patent fall under?
- Primary CPC classification C08G18/329. Mapped technology areas include Chemistry & Metallurgy.
- When was this patent published?
- Publication date Tue Mar 12 2024 00:00:00 GMT+0000 (Coordinated Universal Time) (B2). Legal status and post-grant events are not shown on this page.
- What related patents are in patentsdb?
- We list 4 related publications on this page (citations in our corpus or others sharing the same primary CPC).