Compound, composition, film, laminate, and display device

Patent metadata

Field	Value
Publication number	US-11926575-B2
Application number	US-202017628980-A
Country	US
Kind code	B2
Filing date	Jun 22, 2020
Priority date	Jul 23, 2019
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

Provided is a compound represented by formula (1). In formula (1), Ar 1 , Ar 2 , and Ar 3 represent a 1,4-phenylene group or a divalent sulfur-containing aromatic heterocyclic group optionally having a substituent, and at least one of Ar 1 and Ar 2 has a fluorine atom as a substituent; n represents 1 or 2; R 1 represents a single bond or a group selected from the group consisting of —OC(═O)—, —C(═O)O—, —C≡C—, —CH═CH—, —CH═N—, and —N═CH—; R 2 represents an alkylamino group or an alkoxy group; R 3 represents a group selected from the group consisting of an alkanediyl group, an alkanediyloxy group, an alkanediyloxycarbonyl group, and an alkanediylcarbonyloxy group; and R 4 represents a polymerizable group or a hydrogen atom.

R 4 —R 3 —Ar 1 —(—R 1 —Ar 2 —) n -N═N-Ar 3 —R 2   (1)

First claim

The invention claimed is:

1. A compound represented by the following formula (1):
R 4 —R 3 —Ar 1 —(—R 1 —Ar 2 —) n -N═N-Ar 3 —R 2   (1)

wherein Ar 1 , Ar 2 , and Ar 3 each independently represent a 1,4-phenylene group optionally having a substituent or a divalent sulfur-containing aromatic heterocyclic group optionally having a substituent, and at least one of Ar 1 and Ar 2 has a fluorine atom as a substituent;
n is an integer of 1 or 2;
R 1 represents a single bond or at least one group selected from the group consisting of —OC(═O)—, —C(═O)O—, —C≡C—, —CH═CH—, —CH═N—, and —N═CH—;
R 2 represents an alkylamino group optionally having a polymerizable group;
R 3 represents at least one group selected from the group consisting of an alkanediyl group having 4 to 20 carbon atoms, an alkanediyloxy group having 2 to 20 carbon atoms, an alkanediyloxycarbonyl group having 2 to 20 carbon atoms, and an alkanediylcarbonyloxy group having 2 to 20 carbon atoms;
R 4 represents a polymerizable group or a hydrogen atom;
when n is 2, two R 1 s may be the same as or different from each other, and two Ar 2 s may be the same as or different from each other.

2. The compound according to claim 1 , wherein either one of Ar 1 and Ar 2 has one or two fluorine atoms as a substituent in the formula (1).

3. The compound according to claim 1 , wherein R 1 is a single bond in the formula (1).

4. The compound according to claim 1 , wherein n is an integer of 1 in the formula (1).

5. The compound according to claim 1 , wherein the polymerizable group is a radically polymerizable group.

6. A composition comprising the compound according to claim 1 .

7. A film comprising the compound according to claim 1 as a forming material.

8. A laminate comprising the film according to claim 7 .

9. A display device comprising the film according to claim 7 .

Assignees

• Sumitomo Chemical Co

Inventors

• Takahashi Keisuke

Classifications

• C07C245/08 Primary

  with the two nitrogen atoms of azo groups bound to carbon atoms of six-membered aromatic rings, e.g. azobenzene · CPC title

• C07D277/30 Primary

  Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals · CPC title

• C07D277/66

  with aromatic rings or ring systems directly attached in position 2 · CPC title

• C07D333/16

  by oxygen atoms · CPC title

• C07D333/60

  Radicals substituted by carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals · CPC title