Method for manufacturing crystallized glass member having curved shape
US-2021206684-A1 · Jul 8, 2021 · US
US11926554B2 · US · B2
| Field | Value |
|---|---|
| Publication number | US-11926554-B2 |
| Application number | US-202318154041-A |
| Country | US |
| Kind code | B2 |
| Filing date | Jan 13, 2023 |
| Priority date | Aug 9, 2018 |
| Publication date | Mar 12, 2024 |
| Grant date | Mar 12, 2024 |
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To provide a crystallized glass substrate including a surface with a compressive stress layer, where a stress depth DOL zero of the compressive stress layer, at which the compressive stress is 0 MPa, is 45 to 200 μm, a compressive stress CS on an outermost surface of the compressive stress layer is 400 to 1400 MPa, and a central stress CT determined by using curve analysis is 55 to 300 MPa.
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What is claimed is: 1. A crystallized glass substrate including a surface with a compressive stress layer, wherein a stress depth DOL zero of the compressive stress layer is 45 to 200 μm, the stress depth DOL zero being a depth at which the compressive stress is 0 MPa, a compressive stress CS on an outermost surface of the compressive stress layer is 400 to 1400 MPa, a central stress CT determined by using curve analysis is 55 to 300 MPa, and the crystallized glass substrate comprises, by wt % in terms of oxide: 5.0% or more of a Na 2 O component; and 2.0% or more of a TiO 2 component. 2. The crystallized glass substrate according to claim 1 , wherein a sum of the stress depths from both surfaces of the crystallized glass substrate, 2×DOL zero is 10 to 80% of a thickness T of the crystallized glass substrate. 3. The crystallized glass substrate according to claim 1 , comprising: by wt % in terms of oxide, 40.0% to 70.0% of a SiO 2 component; 11.0% to 25.0% of an Al 2 O 3 component; 5.0% to 19.0% of a Na 2 O component; 0% to 9.0% of a K 2 O component; 1.0% to 18.0% of one or more selected from a MgO component and a ZnO component; 0% to 3.0% of a CaO component; and 2.0% to 12.0% of a TiO 2 component. 4. The crystallized glass substrate according to claim 1 , wherein a thickness T of the crystallized glass substrate is 0.1 to 1.0 mm. 5. The crystallized glass substrate according to claim 1 , wherein E/ρ, which is a ratio of Young's modulus E(GPa) to a specific gravity ρ, is 31 or more. 6. The crystallized glass substrate according to claim 1 , wherein a sum of the compressive stress CS on the outermost surface and the central stress CT is 600 to 1400 MPa. 7. The crystallized glass substrate according to claim 1 , wherein the stress depth DOL zero is 70 to 110 μm, the compressive stress CS of the outermost surface is 550 to 890 MPa, the central stress CT is 100 to 250 MPa, and a sum of the compressive stress CS on the outermost surface and the central stress CT is 800 to 1200 MPa. 8. The crystallized glass substrate according to claim 1 , wherein the stress depth DOL zero is 65 to 85 μm, the compressive stress CS on the outermost surface is 700 to 860 MPa, the central stress CT is 120 to 240 MPa, and a thickness T of the crystallized glass substrate is 0.15 to 0.7 mm.
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