Two-step thermochemical reactor

Patent metadata

Field	Value
Publication number	US-11926526-B2
Application number	US-202017116669-A
Country	US
Kind code	B2
Filing date	Dec 9, 2020
Priority date	Dec 10, 2019
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

A two-step thermochemical reactor and method are disclosed. The reactor includes a housing and a reactor cavity formed within, and surrounded by, thermal insulation within the housing. The reactor cavity includes at least one unit cell, each cell having an electric heat source and a reactive material. The reactor also includes a feedstock inlet and a product outlet in fluid communication with the reactor cavity. The reactor also includes a reducing configuration, with the inlet being closed and the electric heat source of each unit cell being driven to thermally reduce the reactive material at a first temperature, releasing oxygen into the cavity. The reactor also has a splitting configuration where the reactive material is at a second temperature that is lower than the first, the feedstock inlet open and introducing feedstock gas into the cavity to reoxidize the reactive material and split into a product gas.

First claim

What is claimed is:

1. A thermochemical reactor, comprising:
a housing comprising a thermal insulation;
a reactor cavity formed within, and surrounded by, the thermal insulation such that there is no aperture through the thermal insulation to allow solar flux into the reactor cavity, the reactor cavity comprising at least one unit cell, each unit cell of the at least one unit cell comprising:
an electric heat source, and
a reactive material;

a feedstock inlet in fluid communication with the reactor cavity and coupled to a feedstock gas source supplying a feedstock gas; and
a product outlet in fluid communication with the reactor cavity;
wherein the thermochemical reactor also comprises a reducing configuration and a splitting configuration,
wherein the reducing configuration comprises the inlet being closed and the electric heat source of each of the at least one unit cell being driven to thermally reduce the reactive material at a first temperature, releasing oxygen from the reactive material into the reactor cavity, and
wherein the splitting configuration comprises the reactive material of each of the at least one unit cell being maintained at a second temperature by the electric heat source, the second temperature lower than the first temperature, the feedstock inlet being open and introducing feedstock gas into the reactor cavity to react with and reoxidize the reactive material, the feedstock gas splitting into a product gas received from the reactor cavity through the product outlet, the product outlet being open.

2. The thermochemical reactor of claim 1 , wherein the reactive material comprises a metal oxide.

3. The thermochemical reactor of claim 2 , wherein the metal oxide is cerium oxide.

4. The thermochemical reactor of claim 1 , wherein the feedstock gas comprises at least one of steam and carbon dioxide, and wherein the product gas comprises at least one of hydrogen and carbon monoxide.

5. The thermochemical reactor of claim 1 , wherein the electric heat source is an incandescent heat lamp.

6. The thermochemical reactor of claim 5 , wherein the first temperature is above 1600° C.

7. The thermochemical reactor of claim 1 wherein, for each unit cell of the at least one unit cell, the reactive material is stationary with respect to the electric heat source.

8. The thermochemical reactor of claim 1 , wherein at least one of the product gas and the oxygen is removed from the reactor cavity using a sweep gas.

9. The thermochemical reactor of claim 1 , wherein the reducing configuration further comprises the reactor cavity being evacuated and maintained at a pressure at most 1/100 th of atmospheric pressure to remove at least the oxygen released by the reactive material from the reactor cavity.

10. The thermochemical reactor of claim 1 wherein, for each unit cell in the at least one unit cell, the reactive material encircles the electric heat element.

11. A method for a thermochemical reactor cycle, comprising:
heating a reactive material to a first temperature with an electric heat source to thermally reduce the reactive material and release oxygen, the reactive material and the electric heat source enclosed within a reactor cavity formed within, and surrounded by, thermal insulation such that there is no aperture through the thermal insulation to allow solar flux into the reactor cavity;
removing the released oxygen from the reactor cavity;
cooling the reactive material to a second temperature maintained by the electric heat source, the second temperature lower than the first temperature;
reoxidizing the reactive material by introducing a feedstock gas into the reactor cavity, the feedstock gas reacting with the reactive material and splitting into a product gas; and
removing the product gas from the reactor cavity;
wherein the reactive material is stationary with respect to the electric heat source,
wherein the feedstock gas comprises at least one of steam and carbon dioxide, and
wherein the product gas comprises at least one of hydrogen and carbon monoxide.

12. The method of claim 11 , wherein the electric heat source is an incandescent heat lamp.

13. The method of claim 11 , wherein the first temperature is above 1600° C.

14. The method of claim 11 , further comprising removing at least one of the product gas and the oxygen from the reactor cavity using a sweep gas.

15. The method of claim 11 , wherein removing the released oxygen from the reactor cavity comprises evacuating the reactor cavity, removing the oxygen while maintaining the reactor cavity at a pressure at least two orders of magnitude below atmospheric pressure.

16. The method of claim 11 wherein the reactive material encircles the electric heat element.

Assignees

• Univ Arizona State

Inventors

• Ermanoski Ivan

Classifications

• C01B3/063 Primary

  Cyclic methods · CPC title

• B01J19/0013

  Controlling the temperature of the process · CPC title

• B01J19/2465

  externally, i.e. the mixture leaving the vessel and subsequently re-entering it · CPC title

• B01J2219/00135

  Electric resistance heaters · CPC title

• B01J2219/0015

  by thermal insulation means · CPC title