Reduced final grain size of unrecrystallized wrought material produced via the direct chill (DC) route

Patent metadata

Field	Value
Publication number	US-11925973-B2
Application number	US-202017757665-A
Country	US
Kind code	B2
Filing date	Dec 18, 2020
Priority date	Dec 20, 2019
Publication date	Mar 12, 2024
Grant date	Mar 12, 2024

Abstract

Grain size of a deliverable metal product can be improved by pre-setting recrystallization-suppressing dispersoids during casting. The outer regions of a direct chill cast embryonic ingot can undergo reheating before casting is complete. Through unique wiper placement and/or other reheating techniques, the temperature of the ingot can be permitted to reheat (e.g., up to approximately 410° C. to approximately 420° C.), allowing dispersoids to form. Stirring and/or agitation of the molten sump can facilitate formation of a deeper sump and desirably fine grain size as-cast. The formation of dispersoids during and/or immediately after casting can pin the grain boundaries at the desirably fine grain size, encouraging the same grain sizes even after a later recrystallization and/or solutionizing step.

First claim

What is claimed is:

1. A casting method, comprising:
supplying molten metal to a casting mold and forming an embryonic ingot comprising an external solid shell and an internal molten core, wherein the molten metal is a 7xxx series aluminum alloy;
advancing the embryonic ingot in a direction of advancement away from the casting mold while supplying additional molten metal to the casting mold;
extracting heat from the embryonic ingot between the casting mold and a transition location by directing a supply of liquid coolant to an outer surface of the external solid shell; and
reheating the embryonic ingot at the transition location to induce dispersoid precipitation, wherein at least a portion of the external solid shell of the embryonic ingot at the transition location reaches a temperature suitable for precipitating dispersoids and lower than a homogenizing temperature of the molten metal, wherein the transition location lies in a plane that is perpendicular to the direction of advancement and that intersects the internal molten core, wherein the temperature is between 400° C. and 420° C., and wherein the method further comprises maintaining the temperature at the portion of the external solid shell for at least 3 hours.

2. The method of claim 1 , wherein the temperature, in Celsius, is between 80% and 98% of the homogenizing temperature, in Celsius, of the molten metal.

3. The method of claim 1 , wherein the temperature, in Celsius, is between 85% and 90% of the homogenizing temperature, in Celsius, of the molten metal.

4. The method of claim 1 , further comprising maintaining the temperature at the portion of the external solid shell for 3 hours to 10 hours.

5. The method of claim 1 , wherein reheating the embryonic ingot comprises removing the liquid coolant from the outer surface of the external solid shell.

6. The method of claim 5 , wherein reheating the embryonic ingot further comprises applying heat to the outer surface of the external solid shell to supplement latent heating from the internal molten core.

7. The method of claim 1 , further comprising:
taking temperature measurements of the embryonic ingot; and
dynamically adjusting the transition location based on the temperature measurements.

8. The method of claim 1 , further comprising:
inducing stirring in the internal molten core adjacent an interface between the internal molten core and the external solid shell.

9. The method of claim 8 , further comprising taking temperature measurements of the embryonic ingot, wherein inducing stirring in the internal molten core comprises dynamically adjusting an intensity of stirring based on the temperature measurements.

10. The method of claim 1 , wherein the transition location is selected such that the plane intersects the embryonic ingot at a cross section where the external solid shell of the embryonic ingot occupies approximately one third of a line extending from the outer surface to a center of the embryonic ingot within the plane.

11. The method of claim 1 , wherein the transition location is selected such that the plane intersects the embryonic ingot at a cross section where the external solid shell of the embryonic ingot occupies no more than 50% of a line extending from the outer surface to a center of the embryonic ingot within the plane.

12. A method, comprising:
forming an embryonic ingot by supplying molten metal to a mold and extracting heat from the molten metal to form an external solid shell, wherein the molten metal is a 7xxx series aluminum alloy;
solidifying an internal molten core of the embryonic ingot as the embryonic ingot is advanced in a direction of advancement away from the mold and additional molten metal is supplied to the mold, wherein solidifying the internal molten core comprises extracting heat from the internal molten core through the external solid shell; and
continuously forming a high-strength zone within the external solid shell at a cross section of the embryonic ingot that is perpendicular to the direction of advancement and that intersects the internal molten core, wherein the high-strength zone is located between an outer surface of the external solid shell and the internal molten core, and wherein forming the high-strength zone includes reheating the external solid shell at the cross section to induce dispersoid precipitation in the external solid shell,
wherein reheating the external solid shell at the cross section comprises reheating a portion of the external solid shell to a temperature suitable for precipitating dispersoids, wherein the temperature is lower than a homogenizing temperature of the molten metal and is between 400° C. and 420° C., and wherein the method further comprises maintaining the temperature at the portion of the external solid shell for at least 3 hours.

13. The method of claim 12 , wherein the temperature, in Celsius, is between 80% and 98% of the homogenizing temperature, in Celsius, of the molten metal.

14. The method of claim 12 , wherein the temperature, in Celsius, is between 85% and 90% of the homogenizing temperature, in Celsius, of the molten metal.

15. The method of claim 12 , further comprising maintaining the temperature at the portion of the external solid shell for 3 hours to 10 hours.

16. The method of claim 12 , wherein extracting heat from the internal molten core through the external solid shell comprises supplying liquid coolant to the outer surface of the external shell, and wherein reheating the external solid shell comprises removing the liquid coolant from the outer surface of the external solid shell.

17. The method of claim 16 , wherein reheating the external solid shell further comprises applying heat to the outer surface of the external solid shell to supplement latent heating from the internal molten core.

18. The method of claim 12 , further comprising:
taking temperature measurements of the embryonic ingot; and
dynamically adjusting a distance between the mold and the cross section based on the temperature measurements.

19. The method of claim 12 , further comprising:
inducing stirring in the internal molten core adjacent an interface between the internal molten core and the external solid shell.

20. The method of claim 19 , further comprising taking temperature measurements of the embryonic ingot, wherein inducing stirring in the internal molten core comprises dynamically adjusting an intensity of stirring based on the temperature measurements.

21. The method of claim 12 , wherein, at the cross section, the external solid shell of the embryonic ingot occupies approximately one third of a line extending from the outer surface to a center of the embryonic ingot.

22. The method of claim 12 , wherein, at the cross section, the external solid shell of the embryonic ingot occupies no more than 50% of a line extending from the outer surface to a center of the embryonic ingot.

23. The method of claim 12 , wherein the high-strength zone includes a higher concentration of dispersoids than a remainder of the external solid shell.

Assignees

• Novelis Inc

Inventors

• Wagstaff Samuel Robert
• Wagstaff Robert Bruce

Classifications

• B22D11/003

  Aluminium alloys · CPC title

• B22D11/049 Primary

  for direct chill casting, e.g. electromagnetic casting · CPC title

• C22C21/10

  with zinc as the next major constituent · CPC title

• B22D11/112

  by accelerated cooling · CPC title

• B22D11/124

  for cooling · CPC title